(a) Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated. Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R , S notations. Diastereomers are the stereoisomers that have the opposite R , S notations for at least one stereogenic center and the same R , S notations for at least one stereogenic center. Identical compounds have same R , S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R , S ). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

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Answer 1

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Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

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Q6: Using acetic acid as the acid, write the balanced chemical equation for the protonation of the two bases shown (on the -NH2). Include curved arrows to show the mechanism. O₂N- O₂N. -NH2 -NH2 a) Which of the two Bronsted bases above is the stronger base? Why? b) Identify the conjugate acids and conjugate bases for the reactants. c) Identify the Lewis acids and bases in the reactions.

Q5: For the two reactions below: a) Use curved electron-pushing arrows to show the mechanism for the reaction in the forward direction. Redraw the compounds to explicitly illustrate all bonds that are broken and all bonds that are formed. b) Label Bronsted acids and bases in the left side of the reactions. c) For reaction A, which anionic species is the weakest base? Which neutral compound is the stronger acid? Is the forward or reverse reaction favored? d) Label Lewis acids and bases, nucleophiles and electrophiles in the left side of the reactions. A. 용 CH3OH я хон CH3O OH B. HBr CH3ONa NaBr CH3OH

potential energy Br b) Translate the Newman projection below to its wedge-and-dash drawing. F H. OH CH3 CI c) Isopentane (2-methylbutane) is a compound containing a branched carbon chain. Draw a Newman projection of six conformations about the C2-C3 bond of isopentane. On the curve of potential energy versus angle of internal rotation for isopentane, label each energy maximum and minimum with one of the conformations. 0° 。 F A B D C angle of internal rotation E F 360° (=0°) JDownl

Answer 2

Question

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

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Answer 3

Question

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

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Answer 4

Question

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

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Answer 5

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 6

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 7

Chapter 5.11, Problem 30P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). However, the IUPAC name of identical isomers is completely same. Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 8

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 9

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 10

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 11

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 12

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 13

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds as enantiomers, diastereomers, constitutional isomers, or identical is to be stated.

Concept introduction: Enantiomers are the stereoisomers that have exactly opposite R,S notations. Diastereomers are the stereoisomers that have the opposite R,S notations for at least one stereogenic center and the same R,S notations for at least one stereogenic center. Identical compounds have same R,S notations at each stereogenic center. The IUPAC names of enantiomers and diastereomers are differ to each other, only in terms of prefixes (cis, trans, R,S). Constitutional isomers are the compounds that have same molecular formula, but possess different skeletal structures. They differ to each other in the connectivity of atoms. Therefore, their IUPAC names are entirely different.

Answer 14

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Answer 17

Ch. 5.1 - Prob. 1P Ch. 5.2 - Prob. 2P Ch. 5.3 - Draw the mirror image of each compound. Label each...Ch. 5.3 - Prob. 4P Ch. 5.3 - A molecule is achiral if it has a plane of...Ch. 5.6 - Prob. 17P Ch. 5.6 - Prob. 18P Ch. 5.7 - Prob. 19P Ch. 5.7 - Prob. 20P Ch. 5.7 - Problem 5.18 Compounds E and F are two isomers of...

Solution Summary: The author explains the relation between given pair of compounds as enantiomers, diastereomer, constitutional isomeric, or identical.

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