EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Textbook Question
Chapter 5.1, Problem 5.2P
Use the molecular art to identify the process as a
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
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64.0
65.0
74.0
40
75.0
76.0
20
20
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60
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140
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200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
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171.0
21.6
172.0
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181.0
1.3
183.0
197.0
100.0
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200.
784
Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
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ō (ppm)
LOD
D
4000
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HAVENUMBERI -11
Chapter 5 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 5.1 - Use the molecular art to identify the process as a...Ch. 5.1 - Use the molecular art to identify the process as a...Ch. 5.1 - Label the reactants and products, and indicate how...Ch. 5.1 - One term in a balanced chemical equation contained...Ch. 5.2 - Write a balanced equation for each reaction....Ch. 5.2 - Write a balanced equation for the following...Ch. 5.2 - Write a balanced equation for the reaction of...Ch. 5.2 - Balance each chemical equation. Al+H2SO4Al2(...Ch. 5.3 - Write a balanced equation for the reaction...Ch. 5.3 - Classify each reaction as a combination or...
Ch. 5.3 - Classify each reaction as a single replacement or...Ch. 5.3 - Classify each reaction as a combination,...Ch. 5.3 - Fill in the needed reactants or products for each...Ch. 5.4 - Identify the species that is oxidized and the...Ch. 5.4 - Identify the species that is oxidized and the...Ch. 5.4 - Prob. 5.16PCh. 5.5 - How many items are contained in one mole of (a)...Ch. 5.5 - How many carbon atoms are contained in each of the...Ch. 5.5 - How many molecules are contained in each of the...Ch. 5.5 - How many moles of water contain each of the...Ch. 5.6 - Calculate the formula weight of each ionic...Ch. 5.6 - The unmistakable odor of a freshly cut cucumber is...Ch. 5.6 - Prob. 5.23PCh. 5.6 - Calculate the number of grams contained in each of...Ch. 5.6 - How many moles are contained in each of the...Ch. 5.6 - How many molecules are contained in two 500.-mg...Ch. 5.7 - Use the balanced equation for the reaction of N2...Ch. 5.7 - Use the balanced equation in Sample Problem 5.15...Ch. 5.8 - Prob. 5.29PCh. 5.8 - Using the balanced equation for the combustion of...Ch. 5.8 - Prob. 5.31PCh. 5.8 - Use the balanced equation, N2+O22NO, to answer the...Ch. 5.9 - Prob. 5.33PCh. 5.9 - Prob. 5.34PCh. 5.9 - The synthetic antiviral drug Tamiflu, currently...Ch. 5.10 - Consider the reaction of hydrogen and nitrogen to...Ch. 5.10 - Using the balanced equation for the reaction of H2...Ch. 5.10 - Using the balanced equation, 3H2(g)+N2(g)2NH3(g),...Ch. 5.10 - Using the balanced equation, N2(g)+O2(g)2NO(g),...Ch. 5.10 - Prob. 5.41PCh. 5.10 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Prob. 5.44PCh. 5 - How many atoms of each element are drawn on each...Ch. 5 - How many atoms of each element are drawn on each...Ch. 5 - Use the molecular art to write a balanced equation...Ch. 5 - Prob. 5.48PCh. 5 - Balance each equation. a....Ch. 5 - Balance each equation. a....Ch. 5 - Prob. 5.51PCh. 5 - Prob. 5.52PCh. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - For the reaction depicted in the molecular art:...Ch. 5 - Prob. 5.56PCh. 5 - Prob. 5.57PCh. 5 - Prob. 5.58PCh. 5 - Classify the reaction depicted in the molecular...Ch. 5 - Classify the reaction depicted in the molecular...Ch. 5 - Classify each reaction as combination,...Ch. 5 - Classify each reaction as combination,...Ch. 5 - Fill in the needed reactant or product for each of...Ch. 5 - Fill in the needed reactant or product for each of...Ch. 5 - Identify the species that is oxidized and the...Ch. 5 - Identify the species that is oxidized and the...Ch. 5 - Prob. 5.67PCh. 5 - Rechargeablenickel-cadmium batteries are used in...Ch. 5 - The reaction of hydrogen (H2) with acetylene...Ch. 5 - Prob. 5.70PCh. 5 - Calculate the formula weight and molar mass of...Ch. 5 - Calculate the formula weight and molar mass of...Ch. 5 - L-Dopa is a drug used to treat Parkinson’s...Ch. 5 - Niacin, vitamin B3, is found in soybeans, which...Ch. 5 - Which quantity has the greater mass? 1 mol of Fe...Ch. 5 - Prob. 5.76PCh. 5 - Mescaline is a hallucinogen in peyote, a cactus...Ch. 5 - Prob. 5.78PCh. 5 - How many grams are contained in 5.00 mol of each...Ch. 5 - How many grams are contained in 0.50 mol of each...Ch. 5 - Prob. 5.81PCh. 5 - How many moles are contained in each number of...Ch. 5 - Prob. 5.83PCh. 5 - Prob. 5.84PCh. 5 - Prob. 5.85PCh. 5 - Prob. 5.86PCh. 5 - Using the balanced equation for the combustion of...Ch. 5 - Sodium metal (Na) reacts violently when added to...Ch. 5 - Prob. 5.89PCh. 5 - Prob. 5.90PCh. 5 - What is the percent yield of B in a reaction that...Ch. 5 - What is the percent yield of B in a reaction that...Ch. 5 - The reaction of methane (CH4) with Cl2forms...Ch. 5 - Methanol (CH4O), which is used as a fuel in...Ch. 5 - Consider the given reaction mixture that contains...Ch. 5 - Consider the reaction of A2 and B2 to form A2B,...Ch. 5 - Prob. 5.97PCh. 5 - Prob. 5.98PCh. 5 - Prob. 5.99PCh. 5 - Prob. 5.100PCh. 5 - The local anesthetic ethyl chloride ( C2H5Cl,...Ch. 5 - The solvent dichloromethane (, molar mass 84.93...Ch. 5 - Answer the following questions about the...Ch. 5 - Answer the following questions about diethyl ether...Ch. 5 - Prob. 5.105PCh. 5 - Prob. 5.106PCh. 5 - Prob. 5.107PCh. 5 - Prob. 5.108PCh. 5 - Prob. 5.109PCh. 5 - Prob. 5.110PCh. 5 - DDT, a pesticide that kills disease-carrying...Ch. 5 - Prob. 5.112PCh. 5 - TCDD, also called dioxin...Ch. 5 - Prob. 5.114CP
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- 16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してしarrow_forward3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forward
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