EBK CHEMISTRY FOR ENGINEERING STUDENTS,
4th Edition
ISBN: 9781337671439
Author: Holme
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Textbook Question
Chapter 5, Problem 5CO
- perform stoichiometric ca1cu1uions for reactions involving gases as reactants or products.
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Please help me find the 1/Time, Log [I^-] Log [S2O8^2-], Log(time) on the data table. With calculation steps. And the average for runs 1a-1b. Please help me thanks in advance. Will up vote!
Q1: Answer the questions for the reaction below:
..!! Br
OH
a) Predict the product(s) of the reaction.
b) Is the substrate optically active? Are the product(s) optically active as a mix?
c) Draw the curved arrow mechanism for the reaction.
d) What happens to the SN1 reaction rate in each of these instances:
1. Change the substrate to
Br
"CI
2. Change the substrate to
3. Change the solvent from 100% CH3CH2OH to 10% CH3CH2OH + 90% DMF
4. Increase the substrate concentration by 3-fold.
Experiment 27 hates & Mechanisms of Reations
Method I visual Clock Reaction
A. Concentration effects on reaction Rates
Iodine
Run [I] mol/L [S₂082] | Time
mo/L
(SCC)
0.04 54.7
Log
1/ Time Temp Log [ ] 13,20] (time)
/ [I] 199
20.06
23.0
30.04 0.04
0.04 80.0
22.8
45
40.02
0.04 79.0
21.6
50.08
0.03 51.0
22.4
60-080-02 95.0
23.4
7 0.08
0-01 1970
23.4
8 0.08 0.04 16.1
22.6
Chapter 5 Solutions
EBK CHEMISTRY FOR ENGINEERING STUDENTS,
Ch. 5 - Prob. 1COCh. 5 - Prob. 2COCh. 5 - Prob. 3COCh. 5 - Prob. 4COCh. 5 - perform stoichiometric ca1cu1uions for reactions...Ch. 5 - Prob. 6COCh. 5 - Prob. 7COCh. 5 - Prob. 8COCh. 5 - Prob. 9COCh. 5 - Prob. 10CO
Ch. 5 - Prob. 11COCh. 5 - Prob. 5.1PAECh. 5 - Prob. 5.2PAECh. 5 - What possible uses exist for the natural gas...Ch. 5 - How does hydraulic fracturing differ from...Ch. 5 - Prob. 5.5PAECh. 5 - Use the internet to determine what areas of the...Ch. 5 - Prob. 5.7PAECh. 5 - Prob. 5.8PAECh. 5 - Prob. 5.9PAECh. 5 - Prob. 5.10PAECh. 5 - Prob. 5.11PAECh. 5 - 5.12 Water has a density that is 13.6 times less...Ch. 5 - 5.13 Water has a density that is 13.6 times less...Ch. 5 - Prob. 5.14PAECh. 5 - 5.15 Gas pressure can be expressed in units of mm...Ch. 5 - 5.16 If the atmospheric pressure is 97.4 kPa, how...Ch. 5 - Prob. 5.17PAECh. 5 - 5.18 When helium escapes from a balloon, the...Ch. 5 - 5.19 A sample of CO2 gas has a pressure of 56.5 mm...Ch. 5 - Prob. 5.20PAECh. 5 - Prob. 5.21PAECh. 5 - Prob. 5.22PAECh. 5 - 5.23 A gas bubble forms inside a vat containing a...Ch. 5 - 5.24 A bicycle tire is inflated to a pressure of...Ch. 5 - 5.25 A balloon filled with helium has a volume of...Ch. 5 - 5.26 How many moles of an ideal gas are there if...Ch. 5 - 5.27 A newly discovered gas has a density of 2.39...Ch. 5 - 5.28 Calculate the mass of each of the following...Ch. 5 - 5.29 What are the densities of the following gases...Ch. 5 - Prob. 5.30PAECh. 5 - 5.31 A cylinder is filled with toxic COS gas to a...Ch. 5 - 5.32 Cylinders of compressed gases are often...Ch. 5 - Prob. 5.33PAECh. 5 - 5.34 Define the term mole fractionCh. 5 - Prob. 5.35PAECh. 5 - 36 What is the total pressure exerted by a mixture...Ch. 5 - Prob. 5.37PAECh. 5 - 38 For a gas sample whose total pressure is 740...Ch. 5 - 39 A sample containing only NO2 and SO2, has a...Ch. 5 - Prob. 5.40PAECh. 5 - 41 A sample of a smokestack emission was collected...Ch. 5 - 42 Air is often dry air, ignoring the water mole...Ch. 5 - 43 In an experiment, a mixture of gases occupies a...Ch. 5 - Prob. 5.44PAECh. 5 - Prob. 5.45PAECh. 5 - Prob. 5.46PAECh. 5 - 47 HCl(g) reacts with ammonia gas, NH3(g), to form...Ch. 5 - 48 Hydrogen gas is generated when acids come into...Ch. 5 - Prob. 5.49PAECh. 5 - 50 The first step in processing zinc metal from...Ch. 5 - 51 What volume of oxygen at 24 C and 0.88 atm is...Ch. 5 - 52 If tetraborane, B4H10, is treated with pure...Ch. 5 - 53 N2O5is an unstable gas that decomposes...Ch. 5 - 54 One way to generate oxygen is to heat potassium...Ch. 5 - 55 Ammonia is not the only possible fertilizer....Ch. 5 - 56 Consider the following reaction:...Ch. 5 - 57 What volume of hydrogen gas, in liters, is...Ch. 5 - 58 Magnesium will burn in air to form both Mg3N2...Ch. 5 - 59 During a collision, automobile air bags are...Ch. 5 - 60 Automakers are always investigating reactions...Ch. 5 - 61 As one step in its purification, nickel metal...Ch. 5 - 62 Ammonium dinitramide (ADN), NH4N(NO2)2, was...Ch. 5 - Prob. 5.63PAECh. 5 - Prob. 5.64PAECh. 5 - Prob. 5.65PAECh. 5 - Prob. 5.66PAECh. 5 - Prob. 5.67PAECh. 5 - Prob. 5.68PAECh. 5 - Prob. 5.69PAECh. 5 - Prob. 5.70PAECh. 5 - Prob. 5.71PAECh. 5 - Prob. 5.72PAECh. 5 - Prob. 5.73PAECh. 5 - Prob. 5.74PAECh. 5 - Prob. 5.75PAECh. 5 - Prob. 5.76PAECh. 5 - Prob. 5.77PAECh. 5 - Prob. 5.78PAECh. 5 - Prob. 5.79PAECh. 5 - Prob. 5.80PAECh. 5 - Prob. 5.81PAECh. 5 - 82 Why do heavier gases move more slowly than...Ch. 5 - 83 Suppose that speed distribution for each of the...Ch. 5 - 84 Consider a sample of an ideal gas with n and T...Ch. 5 - Prob. 5.85PAECh. 5 - Prob. 5.86PAECh. 5 - Prob. 5.87PAECh. 5 - 88 Liquid oxygen for use as a rocket fuel can be...Ch. 5 - 89 A number of compounds containing the heavier...Ch. 5 - Prob. 5.90PAECh. 5 - 91 A 0.2500-g sample of an Al-Zn alloy reacts with...Ch. 5 - Prob. 5.92PAECh. 5 - 93 The complete combustion of octane can be used...Ch. 5 - 94 Mining engineers often have to deal with gases...Ch. 5 - 95 Some engineering designs call for the use of...Ch. 5 - Prob. 5.96PAECh. 5 - 97 Homes in rural areas where natural gas service...Ch. 5 - Prob. 5.98PAECh. 5 - 99 Pure gaseous nitrogen dioxide (NO2) cannot be...Ch. 5 - Prob. 5.100PAECh. 5 - Prob. 5.101PAECh. 5 - 102 A mixture of helium and neon gases has a...Ch. 5 - Prob. 5.103PAECh. 5 - 104 When a 0.817-g sample of a copper oxide is...Ch. 5 - 105 The decomposition of mercury(II) thiocyanate...Ch. 5 - Prob. 5.106PAECh. 5 - 107 A soft drink can’s label indicates that the...Ch. 5 - Prob. 5.108PAECh. 5 - 109 An ore sample with a mass of 670 kg contains...Ch. 5 - Prob. 5.110PAECh. 5 - 111 Consider a room that is 14ft20ft wih an 8-ft...Ch. 5 - Prob. 5.112PAECh. 5 - 113 A 0.0125-g sample of a gas with an empirical...Ch. 5 - Prob. 5.114PAE
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