Atkins' Physical Chemistry
11th Edition
ISBN: 9780198769866
Author: ATKINS, P. W. (peter William), De Paula, Julio, Keeler, JAMES
Publisher: Oxford University Press
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Chapter 5, Problem 5B.12AE
(i)
Interpretation Introduction
Interpretation: Whether the given solution ideal or not has to be predicted.
Concept introduction: According to the Raoult’s law, the partial vapour pressure of the component is equal to the product of the mole fraction of the component in the liquid mixture and the vapour pressure of that component when present as pure liquid.
(ii)
Interpretation Introduction
Interpretation: The initial composition of vapour above the solution has to be calculated.
Concept introduction: According to the Raoult’s law, the partial vapour pressure of the component is equal to the product of the mole fraction of the component in the liquid mixture and the vapour pressure of that component when present as pure liquid.
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
metals, in sequence from the
Fable (Dr. R's slides) and
Calculate Volume and Density.
Aa
BCC
V
52 5
SFCC
None
Chapter 5 Solutions
Atkins' Physical Chemistry
Ch. 5 - Prob. 5A.1STCh. 5 - Prob. 5A.2STCh. 5 - Prob. 5A.3STCh. 5 - Prob. 5A.4STCh. 5 - Prob. 5B.2STCh. 5 - Prob. 5C.2STCh. 5 - Prob. 5F.1STCh. 5 - Prob. 5A.1DQCh. 5 - Prob. 5A.2DQCh. 5 - Prob. 5A.3DQ
Ch. 5 - Prob. 5A.4DQCh. 5 - Prob. 5A.5DQCh. 5 - Prob. 5A.1AECh. 5 - Prob. 5A.1BECh. 5 - Prob. 5A.2AECh. 5 - Prob. 5A.2BECh. 5 - Prob. 5A.3AECh. 5 - Prob. 5A.3BECh. 5 - Prob. 5A.4AECh. 5 - Prob. 5A.4BECh. 5 - Prob. 5A.5AECh. 5 - Prob. 5A.5BECh. 5 - Prob. 5A.6AECh. 5 - Prob. 5A.6BECh. 5 - Prob. 5A.7AECh. 5 - Prob. 5A.7BECh. 5 - Prob. 5A.8AECh. 5 - Prob. 5A.8BECh. 5 - Prob. 5A.9AECh. 5 - Prob. 5A.9BECh. 5 - Prob. 5A.10AECh. 5 - Prob. 5A.10BECh. 5 - Prob. 5A.11AECh. 5 - Prob. 5A.11BECh. 5 - Prob. 5A.1PCh. 5 - Prob. 5A.3PCh. 5 - Prob. 5A.4PCh. 5 - Prob. 5A.5PCh. 5 - Prob. 5A.6PCh. 5 - Prob. 5A.7PCh. 5 - Prob. 5B.1DQCh. 5 - Prob. 5B.2DQCh. 5 - Prob. 5B.3DQCh. 5 - Prob. 5B.4DQCh. 5 - Prob. 5B.5DQCh. 5 - Prob. 5B.6DQCh. 5 - Prob. 5B.7DQCh. 5 - Prob. 5B.1AECh. 5 - Prob. 5B.1BECh. 5 - Prob. 5B.2AECh. 5 - Prob. 5B.2BECh. 5 - Prob. 5B.3AECh. 5 - Prob. 5B.3BECh. 5 - Prob. 5B.4AECh. 5 - Prob. 5B.4BECh. 5 - Prob. 5B.5AECh. 5 - Prob. 5B.5BECh. 5 - Prob. 5B.6AECh. 5 - Prob. 5B.6BECh. 5 - Prob. 5B.7AECh. 5 - Prob. 5B.7BECh. 5 - Prob. 5B.8AECh. 5 - Prob. 5B.8BECh. 5 - Prob. 5B.9AECh. 5 - Prob. 5B.9BECh. 5 - Prob. 5B.10AECh. 5 - Prob. 5B.10BECh. 5 - Prob. 5B.11AECh. 5 - Prob. 5B.11BECh. 5 - Prob. 5B.12AECh. 5 - Prob. 5B.12BECh. 5 - Prob. 5B.1PCh. 5 - Prob. 5B.2PCh. 5 - Prob. 5B.3PCh. 5 - Prob. 5B.4PCh. 5 - Prob. 5B.5PCh. 5 - Prob. 5B.6PCh. 5 - Prob. 5B.9PCh. 5 - Prob. 5B.11PCh. 5 - Prob. 5B.13PCh. 5 - Prob. 5C.1DQCh. 5 - Prob. 5C.2DQCh. 5 - Prob. 5C.3DQCh. 5 - Prob. 5C.1AECh. 5 - Prob. 5C.1BECh. 5 - Prob. 5C.2AECh. 5 - Prob. 5C.2BECh. 5 - Prob. 5C.3AECh. 5 - Prob. 5C.3BECh. 5 - Prob. 5C.4AECh. 5 - Prob. 5C.4BECh. 5 - Prob. 5C.1PCh. 5 - Prob. 5C.2PCh. 5 - Prob. 5C.3PCh. 5 - Prob. 5C.4PCh. 5 - Prob. 5C.5PCh. 5 - Prob. 5C.6PCh. 5 - Prob. 5C.7PCh. 5 - Prob. 5C.8PCh. 5 - Prob. 5C.9PCh. 5 - Prob. 5C.10PCh. 5 - Prob. 5D.1DQCh. 5 - Prob. 5D.2DQCh. 5 - Prob. 5D.1AECh. 5 - Prob. 5D.1BECh. 5 - Prob. 5D.2AECh. 5 - Prob. 5D.2BECh. 5 - Prob. 5D.3AECh. 5 - Prob. 5D.3BECh. 5 - Prob. 5D.4AECh. 5 - Prob. 5D.4BECh. 5 - Prob. 5D.5AECh. 5 - Prob. 5D.5BECh. 5 - Prob. 5D.6AECh. 5 - Prob. 5D.1PCh. 5 - Prob. 5D.2PCh. 5 - Prob. 5D.3PCh. 5 - Prob. 5D.4PCh. 5 - Prob. 5D.5PCh. 5 - Prob. 5D.6PCh. 5 - Prob. 5D.7PCh. 5 - Prob. 5E.1DQCh. 5 - Prob. 5E.2DQCh. 5 - Prob. 5E.3DQCh. 5 - Prob. 5E.4DQCh. 5 - Prob. 5E.1AECh. 5 - Prob. 5E.1BECh. 5 - Prob. 5E.2AECh. 5 - Prob. 5E.2BECh. 5 - Prob. 5E.3AECh. 5 - Prob. 5E.3BECh. 5 - Prob. 5E.4AECh. 5 - Prob. 5E.4BECh. 5 - Prob. 5E.5AECh. 5 - Prob. 5E.5BECh. 5 - Prob. 5E.1PCh. 5 - Prob. 5E.2PCh. 5 - Prob. 5E.3PCh. 5 - Prob. 5F.1DQCh. 5 - Prob. 5F.2DQCh. 5 - Prob. 5F.3DQCh. 5 - Prob. 5F.4DQCh. 5 - Prob. 5F.5DQCh. 5 - Prob. 5F.1AECh. 5 - Prob. 5F.1BECh. 5 - Prob. 5F.2AECh. 5 - Prob. 5F.2BECh. 5 - Prob. 5F.3AECh. 5 - Prob. 5F.3BECh. 5 - Prob. 5F.4AECh. 5 - Prob. 5F.4BECh. 5 - Prob. 5F.5AECh. 5 - Prob. 5F.5BECh. 5 - Prob. 5F.6AECh. 5 - Prob. 5F.6BECh. 5 - Prob. 5F.7AECh. 5 - Prob. 5F.7BECh. 5 - Prob. 5F.8AECh. 5 - Prob. 5F.8BECh. 5 - Prob. 5F.1PCh. 5 - Prob. 5F.2PCh. 5 - Prob. 5F.3PCh. 5 - Prob. 5F.4PCh. 5 - Prob. 5.1IACh. 5 - Prob. 5.2IACh. 5 - Prob. 5.3IACh. 5 - Prob. 5.4IACh. 5 - Prob. 5.5IACh. 5 - Prob. 5.6IACh. 5 - Prob. 5.8IACh. 5 - Prob. 5.9IACh. 5 - Prob. 5.10IA
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY