For the given set of molecules the optically active or optically inactive should be identified. Concept Introduction : Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another. Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms. Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

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Answer 1

Question

Chapter 5, Problem 59IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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Answer 2

Question

Chapter 5, Problem 59IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

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Answer 3

Question

Chapter 5, Problem 59IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

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Answer 4

Question

Chapter 5, Problem 59IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

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Answer 5

Chapter 5, Problem 59IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 6

Chapter 5, Problem 59IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 7

Chapter 5, Problem 59IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 8

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 9

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 10

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 11

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 5.1 - In the following compound, identify each unit...Ch. 5.1 - Prob. 2CC Ch. 5.1 - Prob. 3CC Ch. 5.2 - Prob. 1LTS Ch. 5.2 - Prob. 4PTS Ch. 5.2 - Prob. 5ATS Ch. 5.2 - Prob. 6ATS Ch. 5.2 - Prob. 2LTS Ch. 5.2 - Prob. 7PTS Ch. 5.2 - Prob. 8ATS

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