It should be determined that the number of alkenes used to prepare methylcyclopentane by hydrogenation process. Concept introduction: The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation ( Δ H 0 ) . The most stable alkene has the smallest heat of hydrogenation. The stability of an alkene increases as the number of alkyl substituents bonded to its s p 2 carbon increases. The stability of an alkene increases as the number of hydrogen bonded to its s p 2 carbon decreases. Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H − H bond. A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

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Answer 1

Question

Chapter 5, Problem 56P

(a)

Interpretation Introduction

Interpretation:

It should be determined that the number of alkenes used to prepare methylcyclopentane by hydrogenation process.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

(b)

Interpretation Introduction

Interpretation:

Most stable alkene should be identified that which was used to prepare methylcyclopentane.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation should be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

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1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.

3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗ

2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br O

Answer 2

Question

Chapter 5, Problem 56P

(a)

Interpretation Introduction

Interpretation:

It should be determined that the number of alkenes used to prepare methylcyclopentane by hydrogenation process.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

(b)

Interpretation Introduction

Interpretation:

Most stable alkene should be identified that which was used to prepare methylcyclopentane.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation should be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

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Answer 3

Question

Chapter 5, Problem 56P

(a)

Interpretation Introduction

Interpretation:

It should be determined that the number of alkenes used to prepare methylcyclopentane by hydrogenation process.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

(b)

Interpretation Introduction

Interpretation:

Most stable alkene should be identified that which was used to prepare methylcyclopentane.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation should be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

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Answer 4

Question

Chapter 5, Problem 56P

(a)

Interpretation Introduction

Interpretation:

It should be determined that the number of alkenes used to prepare methylcyclopentane by hydrogenation process.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

(b)

Interpretation Introduction

Interpretation:

Most stable alkene should be identified that which was used to prepare methylcyclopentane.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation should be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

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Answer 5

Chapter 5, Problem 56P

(a)

Interpretation Introduction

Interpretation:

It should be determined that the number of alkenes used to prepare methylcyclopentane by hydrogenation process.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

(b)

Interpretation Introduction

Interpretation:

Most stable alkene should be identified that which was used to prepare methylcyclopentane.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation should be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 6

Chapter 5, Problem 56P

(a)

Interpretation Introduction

Interpretation:

It should be determined that the number of alkenes used to prepare methylcyclopentane by hydrogenation process.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

Answer 7

Chapter 5, Problem 56P

(a)

Interpretation Introduction

Interpretation:

It should be determined that the number of alkenes used to prepare methylcyclopentane by hydrogenation process.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Catalytic hydrogenation is the process of addition of hydrogen to a compound in the presence of a catalyst. The most common metal catalyst is palladium, which is used as a powder absorbed on charcoal to maximize its surface area. The metal catalyst is required to weaken the very strong H−H bond.

A meso compound is a molecule with multiple stereocentres that is super imposable on its mirror image.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Most stable alkene should be identified that which was used to prepare methylcyclopentane.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Most stable alkene should be identified that which was used to prepare methylcyclopentane.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation should be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The alkene which has the smallest heat of hydrogenation should be identified.

Concept introduction:

The amount of heat released in a hydrogenation reaction is known as heat of hydrogenation(ΔH0).

The most stable alkene has the smallest heat of hydrogenation.

The stability of an alkene increases as the number of alkyl substituents bonded to its sp2 carbon increases.

The stability of an alkene increases as the number of hydrogen bonded to its sp2 carbon decreases.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 5.1 - What is the molecular formula for each of the...Ch. 5.1 - Prob. 4P Ch. 5.1 - Determine the degree of unsaturation and then draw...Ch. 5.1 - Prob. 6P Ch. 5.2 - What is each compounds systematic name?Ch. 5.2 - Prob. 8P Ch. 5.2 - Draw the structure for each of the following: a....Ch. 5.3 - How many carbons are in the planar double-bond...Ch. 5.3 - Prob. 12P Ch. 5.5 - Prob. 13P

Solution Summary: The author explains the number of alkenes used to prepare methylcyclopentane by hydrogenation process.

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