(a) Interpretation: The relation between given pair of compounds is to be determined. Concept introduction: The stereogenic centers with R , S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration. Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 1

Question

Chapter 5, Problem 5.63P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(e)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(f)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 2

Question

Chapter 5, Problem 5.63P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(e)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(f)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 3

Question

Chapter 5, Problem 5.63P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(e)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(f)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 4

Question

Chapter 5, Problem 5.63P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(e)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(f)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 5

Chapter 5, Problem 5.63P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(e)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(f)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 6

Chapter 5, Problem 5.63P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 7

Chapter 5, Problem 5.63P

Interpretation Introduction

(a)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 8

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 9

Interpretation Introduction

(b)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 10

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 11

Interpretation Introduction

(c)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 12

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 13

Interpretation Introduction

(d)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 14

Interpretation Introduction

(e)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 15

Interpretation Introduction

(e)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 16

Interpretation Introduction

(f)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 17

Interpretation Introduction

(f)

Interpretation: The relation between given pair of compounds is to be determined.

Concept introduction: The stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules. According to these rules, the substituents attached to stereogenic centers are given priority. On moving from higher priority to lower priority substituent in clockwise direction, the compound is assigned with R configuration. On moving from higher priority to lower priority substituent in anticlockwise direction, the compound is assigned with S configuration.

Enantiomer of a compound has opposite configuration at stereogenic centers. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Draw the mirror image of each compound. Label each...Ch. 5 - Prob. 5.4P Ch. 5 - A molecule is achiral if it has a plane of...Ch. 5 - Problem 5.6 Locate the stereogenic centers in each...Ch. 5 - The facts in section 5.4A can be used to locate...Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that the stereogenic centers with R,S configuration are assigned according to Cahn-Ingold-Prelog rules.

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