Unit Operations Of Chemical Engineering
Unit Operations Of Chemical Engineering
7th Edition
ISBN: 9789339213237
Author: MCCABE, WARREN
Publisher: Tata McGraw-Hill Education India
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Chapter 5, Problem 5.5P
Interpretation Introduction

Interpretation: The rise in the temperature of the oil in the previous question is to be calculated due to viscous dissipation.

Concept introduction: The rise in temperature is generally calculated from the heat balance equation. The rise or increase in the temperature is generally due to the physical factors involved in the system or surroundings. The equation for the heat balance to calculate the rise in temperature is,

  Q=m˙ ×cp×ΔT.......(1)

The notations used in this equation are,

  Q =Amount of heat suppliedm˙=Mass flow rate of the oilcp=SpecificheatoftheoilΔT=Riseintemperature

The mass flow rate of the oil can be given as,

  m˙=ρ×q.......(2)ρ= Densityofoilq=Flow rate of the oil

On combining equation (1) and equation (2) and rearranging,

  ΔT=Qρ×q×cp.......(3)

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For each set of measurements below, calculate the Grubbs statistic, G, look up the appropriate critical value of G from Table 4.6, and determine whether the Grubbs test supports discarding the first value in the list at the 95% level of confidence. a) 106.0, 165.0, 167.5, 170.5, 163.5, 170.7 (Geale -2.028; Gerit 1.822; yes, the Grubbs test supports discarding 106.0) b) 214.8, 263.0, 229.9, 236.9, 221.8, 230.8, 241.1 c) 357.0, 309.3, 304.9, 314.8, 305.8, 295.3, 284.7, 299.5 TABLE 4-6 Critical values of G for rejection of outlier Number of observations otsulsve os Tenos nagsibarito G to buboxy (95% confidence) 456 1.463 1.672 1.822 7 1.938 8 upa 2.032 9 2.110 10 2.176 - 1 12 15 20 11 2.234 2.285 2.409 2.557
#1 A irreversible isothermal gas-phase isomerization reaction is given as: AB. This reaction is conducted in a 400L batch reactor and 100 mol of A (NAD = 100 mol) is charged into this reactor. The rate of reaction is determined as a function of the conversion of reactant A and the results are given below. The temperature was constant at 500K and the total pressure was constant at 830 kPa. The entering number of moles of species A is 100 mol. Calculate the time necessary to achieve 80% conversion. 0 0.1 0.2 0.4 -TA (mol/m³.s) 0.45 0.37 0.3 0.195 0.6 0.113 0.7 0.079 0.8 0.05
#3 A irreversible isothermal liquid-phase reaction is given as: A → B is conducted in continuous flow systems. The rate of reaction is determined as a function of the conversion of reactant A and the results are given below. The temperature was constant at 500K. The entering molar flow rate of A is 0.4 mol/min. a) If this reaction is conducted in two CSTRS in series. Calculate the required reactor volume of each CSTRS if conversion X₁ = 0.4 and conversion X2 = 0.8. b) If this reaction is conducted in two PFRS in series. Calculate the required reactor volume of each PFRS if conversion X₁ = 0.4 and conversion X2 = 0.8. c) If this reaction is conducted in a PFR followed by a CSTR. Calculate the required reactor volume of PFR if conversion X₁ = 0.4 and of CSTR if conversion X2 = 0.8. X -A (mol/L.min) 0 0.1 0.2 0.4 0.6 0.7 0.8 0.45 0.37 0.3 0.195 0.113 0.079 0.05
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