Chemistry: An Introduction to General, Organic, and Biological Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (13th Edition)
13th Edition
ISBN: 9780134416793
Author: Karen C Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 5, Problem 5.58APP
Determine the number of protons and number of neutrons in the nucleus of each of the following: (5.1)
- boron-10
- zinc-72
- iron-59
- gold-198
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 5 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (13th Edition)
Ch. 5.1 - Prob. 5.1PPCh. 5.1 - Prob. 5.2PPCh. 5.1 - Naturally occurring potassium consists of three...Ch. 5.1 - Naturally occurring iodine is iodine-127....Ch. 5.1 - Identify each of the following: a. 10X b. 24X c....Ch. 5.1 - Identify each of the following: a. 11X b. 3581X c....Ch. 5.1 - Prob. 5.7PPCh. 5.1 - Prob. 5.8PPCh. 5.1 - Prob. 5.9PPCh. 5.1 - Prob. 5.10PP
Ch. 5.1 - Prob. 5.11PPCh. 5.1 - Prob. 5.12PPCh. 5.2 - Prob. 5.13PPCh. 5.2 - Prob. 5.14PPCh. 5.2 - Prob. 5.15PPCh. 5.2 - Prob. 5.16PPCh. 5.2 - Prob. 5.17PPCh. 5.2 - Prob. 5.18PPCh. 5.2 - Prob. 5.19PPCh. 5.2 - Prob. 5.20PPCh. 5.2 - Complete each of the following reactions: a....Ch. 5.2 - Prob. 5.22PPCh. 5.3 - Prob. 5.23PPCh. 5.3 - Prob. 5.24PPCh. 5.3 - Prob. 5.25PPCh. 5.3 - Prob. 5.26PPCh. 5.3 - Prob. 5.27PPCh. 5.3 - Prob. 5.28PPCh. 5.4 - Prob. 5.29PPCh. 5.4 - Prob. 5.30PPCh. 5.4 - Prob. 5.31PPCh. 5.4 - Prob. 5.32PPCh. 5.4 - Prob. 5.33PPCh. 5.4 - Prob. 5.34PPCh. 5.5 - Prob. 5.35PPCh. 5.5 - Prob. 5.36PPCh. 5.5 - Prob. 5.37PPCh. 5.5 - Prob. 5.38PPCh. 5.5 - Prob. 5.39PPCh. 5.5 - Prob. 5.40PPCh. 5.6 - Prob. 5.41PPCh. 5.6 - Prob. 5.42PPCh. 5.6 - Prob. 5.43PPCh. 5.6 - Prob. 5.44PPCh. 5.6 - Prob. 5.45PPCh. 5.6 - Prob. 5.46PPCh. 5.6 - Prob. 5.47PPCh. 5.6 - Prob. 5.48PPCh. 5.6 - Prob. 5.49PPCh. 5.6 - Prob. 5.50PPCh. 5 - Prob. 5.51UTCCh. 5 - Prob. 5.52UTCCh. 5 - 5.53 Draw the nucleus of the isotope that is...Ch. 5 - Prob. 5.54UTCCh. 5 - Prob. 5.55UTCCh. 5 - Prob. 5.56UTCCh. 5 - Determine the number of protons and number of...Ch. 5 - Determine the number of protons and number of...Ch. 5 - Prob. 5.59APPCh. 5 - Prob. 5.60APPCh. 5 - Prob. 5.61APPCh. 5 - Prob. 5.62APPCh. 5 - Prob. 5.63APPCh. 5 - Prob. 5.64APPCh. 5 - Prob. 5.65APPCh. 5 - Prob. 5.66APPCh. 5 - Prob. 5.67APPCh. 5 - Prob. 5.68APPCh. 5 - Prob. 5.69APPCh. 5 - Prob. 5.70APPCh. 5 - Where does fusion occur naturally? (5.6)Ch. 5 - Prob. 5.72APPCh. 5 - Prob. 5.73APPCh. 5 - Prob. 5.74APPCh. 5 - Prob. 5.75APPCh. 5 - Prob. 5.76APPCh. 5 - Prob. 5.77APPCh. 5 - Prob. 5.78APPCh. 5 - Prob. 5.79CPCh. 5 - Prob. 5.80CPCh. 5 - Prob. 5.81CPCh. 5 - Prob. 5.82CPCh. 5 - Prob. 5.83CPCh. 5 - Prob. 5.84CPCh. 5 - Prob. 5.85CPCh. 5 - Prob. 5.86CPCh. 5 - Prob. 5.87CPCh. 5 - Prob. 5.88CPCh. 5 - Prob. 5.89CPCh. 5 - Prob. 5.90CP
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