CHEMISTRY-TEXT
8th Edition
ISBN: 9780134856230
Author: Robinson
Publisher: PEARSON
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Textbook Question
Chapter 5, Problem 5.55SP
Cesium metal is frequently used in photoelectric cells because the amount of energy necessary to eject electrons from acesium surface is relatively small—only 206.5 kJ/mol. What
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 5 Solutions
CHEMISTRY-TEXT
Ch. 5 - What is the wavelength in meters of an FM radio...Ch. 5 - Conceptual APPLY 5.2 Two electromagnetic waves are...Ch. 5 - PRACTICE 5.3 The biological effects of a given...Ch. 5 - Prob. 5.4ACh. 5 - Prob. 5.5PCh. 5 - Conceptual APPLY 5.6 Compare the two elements Rb...Ch. 5 - PRACTICE 5.7 The Balmer equation can be extended...Ch. 5 - APPLY 5.8 (a) What is the longest-wavelength line...Ch. 5 - Prob. 5.9PCh. 5 - Prob. 5.10A
Ch. 5 - Give the or bital notation for an electron in an...Ch. 5 - APPLY 5.10 Extend Table 5.2 to show allowed...Ch. 5 - Conceptual PRACTICE 5.13 Give a possible...Ch. 5 - Conceptual APPLY 5.14 How many nodal planes...Ch. 5 - Give the expected ground state electron...Ch. 5 - Conceptual APPLY 5.16 Identify the atoms with the...Ch. 5 - Order the atoms from smallest to largest: Cs,...Ch. 5 - APPLY 5.18 Predict which bond length will be the...Ch. 5 - What percentage of electrical energy is converted...Ch. 5 - Prob. 5.20PCh. 5 - (a) How is the emission spectrum from the...Ch. 5 - PROBLEM 5.19 Mercury vapor is contained inside the...Ch. 5 - PROBLEM 5.20 When electricity is used to add...Ch. 5 - Atomic emission spectra arise from electron...Ch. 5 - PROBLEM 5.22 Three different wavelengths in the...Ch. 5 - Two electromagnetic waves are represented below....Ch. 5 - The following diagram shows the energy levels of...Ch. 5 - Identify each of the following orbitals, and give...Ch. 5 - Where on the blank outline of the periodic table...Ch. 5 - One of the elements shown on the following...Ch. 5 - What atom has the following orbital-filling...Ch. 5 - The following orbital-filling diagram represents...Ch. 5 - Prob. 5.33CPCh. 5 - Which has the higher frequency, red light or...Ch. 5 - Prob. 5.35SPCh. 5 - The Hubble Space Telescope detects electromagnetic...Ch. 5 - Prob. 5.37SPCh. 5 - What is the wavelength in meters of ultraviolet...Ch. 5 - What is the frequency of a microwave with...Ch. 5 - A certain cellular telephone transmits at a...Ch. 5 - Optical fibers allow the fast transmission of vast...Ch. 5 - Calculate the energies of the following waves in...Ch. 5 - The magnetic resonance imaging (MRI) body scanners...Ch. 5 - What is the wavelength in meters of photons with...Ch. 5 - What is the energy of each of the following...Ch. 5 - You’re probably familiar with using Scotch rape...Ch. 5 - Hard wintergreen-flavored candies are...Ch. 5 - Prob. 5.48SPCh. 5 - Photochromic sunglasses, which darken when exposed...Ch. 5 - Prob. 5.50SPCh. 5 - Prob. 5.51SPCh. 5 - The work function of cesium metal is 188 kJ/mol,...Ch. 5 - Prob. 5.53SPCh. 5 - The work function of silver metal is 436 kJ/mol....Ch. 5 - Cesium metal is frequently used in photoelectric...Ch. 5 - Spectroscopy is a technique that uses the...Ch. 5 - Prob. 5.57SPCh. 5 - According to the equation for the Balmer line...Ch. 5 - According to the equation for the Balmer line...Ch. 5 - Calculate the wavelength and energy in kilojoules...Ch. 5 - Calculate the wavelength and energy in kilojoules...Ch. 5 - One series of lines of the hydrogen spectrum is...Ch. 5 - One series of lines of the hydrogen spectrum is...Ch. 5 - Use the Balmer equation to calculate the...Ch. 5 - Prob. 5.65SPCh. 5 - Protons and electrons can be given very high...Ch. 5 - What is the wavelength in meters of a proton...Ch. 5 - What is the de Broglie wavelength in meters of a...Ch. 5 - What is the de Brogue wavelength in meters of a...Ch. 5 - At what speed in meters per second must a 145 g...Ch. 5 - What velocity would an electron (mass=9.111031kg)...Ch. 5 - Use the Heisenberg uncertainty principle to...Ch. 5 - The mass of a helium atom is 40026 amu, and its...Ch. 5 - What is the Heisenberg uncertainty principle, and...Ch. 5 - Why do we have to use an arbitrary value such as...Ch. 5 - What are the four quantum numbers, and what does...Ch. 5 - Tell which of the following combinations of...Ch. 5 - Give the allowable combinations of quantum numbers...Ch. 5 - Give the orbital designations of electrons with...Ch. 5 - Which of the following combinations of quantum...Ch. 5 - Which of the following combinations of quantum...Ch. 5 - What is the maximum number of electrons in an atom...Ch. 5 - What is the maximum number of electrons in an atom...Ch. 5 - Sodium atoms emit light with a wavelength of 330...Ch. 5 - Prob. 5.85SPCh. 5 - Prob. 5.86SPCh. 5 - Assign a set of four quantum numbers to each...Ch. 5 - Assign a set of four quantum numbers for the outer...Ch. 5 - Which of the following is a valid set of four...Ch. 5 - Prob. 5.90SPCh. 5 - Prob. 5.91SPCh. 5 - Prob. 5.92SPCh. 5 - Prob. 5.93SPCh. 5 - Prob. 5.94SPCh. 5 - Prob. 5.95SPCh. 5 - Order the electrons in the following orbitals...Ch. 5 - Order the following elements according to...Ch. 5 - Prob. 5.98SPCh. 5 - Prob. 5.99SPCh. 5 - Which orbital in each of the following pairs is...Ch. 5 - Order the orbitals for a multi electron atom in...Ch. 5 - According to the aufbau principle, which orbital...Ch. 5 - According to the autbau principle, which orbital...Ch. 5 - Give the expected ground-state electron...Ch. 5 - Give the expected ground-state electron...Ch. 5 - Draw orbital-filling diagrams for the following...Ch. 5 - Draw orbital-filling diagrams for atoms with the...Ch. 5 - How many unpaired electrons are present in each of...Ch. 5 - Identify the following atoms. (a) It has the...Ch. 5 - Prob. 5.110SPCh. 5 - Given the sub shells 1s, 2s, 2p, 3s, 3p and 3d,...Ch. 5 - Prob. 5.112SPCh. 5 - Prob. 5.113SPCh. 5 - Take a guess. What do you think is a likely...Ch. 5 - Take a guess. What is a likely ground-state...Ch. 5 - Prob. 5.116SPCh. 5 - Prob. 5.117SPCh. 5 - Prob. 5.118SPCh. 5 - Prob. 5.119SPCh. 5 - Prob. 5.120SPCh. 5 - Prob. 5.121SPCh. 5 - Prob. 5.122SPCh. 5 - Which atom in each of the following pairs has a...Ch. 5 - Orbital energies in single-electron atoms or ions,...Ch. 5 - Like He+ , the Li2+ ion is a single-electron...Ch. 5 - Prob. 5.126MPCh. 5 - Draw orbital-filling diagrams for the following...Ch. 5 - The atomic radii of Y (180 pm) and Li (187 pm) are...Ch. 5 - Prob. 5.129MPCh. 5 - Prob. 5.130MPCh. 5 - Prob. 5.131MPCh. 5 - The amount of energy necessary to remove an...Ch. 5 - Prob. 5.133MPCh. 5 - Prob. 5.134MPCh. 5 - Prob. 5.135MPCh. 5 - A minimum energy of 7.211019J is required to...Ch. 5 - Prob. 5.137MPCh. 5 - An energetically excited hydrogen atom has its...Ch. 5 - Prob. 5.139MP
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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