CHEMISTRY-TEXT
8th Edition
ISBN: 9780134856230
Author: Robinson
Publisher: PEARSON
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Chapter 5, Problem 5.35SP
Interpretation Introduction
To determine:
The light which has higher frequency, infrared light or ultraviolet light, which has longer wavelength and which has greater energy?
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1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
None
Part II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization
of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm").
Determine the following:
(a) molecular Formula and Degree of unsaturation of compound Brian
(b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts
(ii) integration, ciii) multiplicity and (iv) interferences made for each signal
(c) Draw the structure of compound Brian.
)
ΕΙ
43
41
27
71
114 (M+)
Hmmm
20
30
40
50 60
70
80
90 100 110 120
1H NMR spectrum
300 MHz in CDCl3
2.0
alle
1.0
Chapter 5 Solutions
CHEMISTRY-TEXT
Ch. 5 - What is the wavelength in meters of an FM radio...Ch. 5 - Conceptual APPLY 5.2 Two electromagnetic waves are...Ch. 5 - PRACTICE 5.3 The biological effects of a given...Ch. 5 - Prob. 5.4ACh. 5 - Prob. 5.5PCh. 5 - Conceptual APPLY 5.6 Compare the two elements Rb...Ch. 5 - PRACTICE 5.7 The Balmer equation can be extended...Ch. 5 - APPLY 5.8 (a) What is the longest-wavelength line...Ch. 5 - Prob. 5.9PCh. 5 - Prob. 5.10A
Ch. 5 - Give the or bital notation for an electron in an...Ch. 5 - APPLY 5.10 Extend Table 5.2 to show allowed...Ch. 5 - Conceptual PRACTICE 5.13 Give a possible...Ch. 5 - Conceptual APPLY 5.14 How many nodal planes...Ch. 5 - Give the expected ground state electron...Ch. 5 - Conceptual APPLY 5.16 Identify the atoms with the...Ch. 5 - Order the atoms from smallest to largest: Cs,...Ch. 5 - APPLY 5.18 Predict which bond length will be the...Ch. 5 - What percentage of electrical energy is converted...Ch. 5 - Prob. 5.20PCh. 5 - (a) How is the emission spectrum from the...Ch. 5 - PROBLEM 5.19 Mercury vapor is contained inside the...Ch. 5 - PROBLEM 5.20 When electricity is used to add...Ch. 5 - Atomic emission spectra arise from electron...Ch. 5 - PROBLEM 5.22 Three different wavelengths in the...Ch. 5 - Two electromagnetic waves are represented below....Ch. 5 - The following diagram shows the energy levels of...Ch. 5 - Identify each of the following orbitals, and give...Ch. 5 - Where on the blank outline of the periodic table...Ch. 5 - One of the elements shown on the following...Ch. 5 - What atom has the following orbital-filling...Ch. 5 - The following orbital-filling diagram represents...Ch. 5 - Prob. 5.33CPCh. 5 - Which has the higher frequency, red light or...Ch. 5 - Prob. 5.35SPCh. 5 - The Hubble Space Telescope detects electromagnetic...Ch. 5 - Prob. 5.37SPCh. 5 - What is the wavelength in meters of ultraviolet...Ch. 5 - What is the frequency of a microwave with...Ch. 5 - A certain cellular telephone transmits at a...Ch. 5 - Optical fibers allow the fast transmission of vast...Ch. 5 - Calculate the energies of the following waves in...Ch. 5 - The magnetic resonance imaging (MRI) body scanners...Ch. 5 - What is the wavelength in meters of photons with...Ch. 5 - What is the energy of each of the following...Ch. 5 - You’re probably familiar with using Scotch rape...Ch. 5 - Hard wintergreen-flavored candies are...Ch. 5 - Prob. 5.48SPCh. 5 - Photochromic sunglasses, which darken when exposed...Ch. 5 - Prob. 5.50SPCh. 5 - Prob. 5.51SPCh. 5 - The work function of cesium metal is 188 kJ/mol,...Ch. 5 - Prob. 5.53SPCh. 5 - The work function of silver metal is 436 kJ/mol....Ch. 5 - Cesium metal is frequently used in photoelectric...Ch. 5 - Spectroscopy is a technique that uses the...Ch. 5 - Prob. 5.57SPCh. 5 - According to the equation for the Balmer line...Ch. 5 - According to the equation for the Balmer line...Ch. 5 - Calculate the wavelength and energy in kilojoules...Ch. 5 - Calculate the wavelength and energy in kilojoules...Ch. 5 - One series of lines of the hydrogen spectrum is...Ch. 5 - One series of lines of the hydrogen spectrum is...Ch. 5 - Use the Balmer equation to calculate the...Ch. 5 - Prob. 5.65SPCh. 5 - Protons and electrons can be given very high...Ch. 5 - What is the wavelength in meters of a proton...Ch. 5 - What is the de Broglie wavelength in meters of a...Ch. 5 - What is the de Brogue wavelength in meters of a...Ch. 5 - At what speed in meters per second must a 145 g...Ch. 5 - What velocity would an electron (mass=9.111031kg)...Ch. 5 - Use the Heisenberg uncertainty principle to...Ch. 5 - The mass of a helium atom is 40026 amu, and its...Ch. 5 - What is the Heisenberg uncertainty principle, and...Ch. 5 - Why do we have to use an arbitrary value such as...Ch. 5 - What are the four quantum numbers, and what does...Ch. 5 - Tell which of the following combinations of...Ch. 5 - Give the allowable combinations of quantum numbers...Ch. 5 - Give the orbital designations of electrons with...Ch. 5 - Which of the following combinations of quantum...Ch. 5 - Which of the following combinations of quantum...Ch. 5 - What is the maximum number of electrons in an atom...Ch. 5 - What is the maximum number of electrons in an atom...Ch. 5 - Sodium atoms emit light with a wavelength of 330...Ch. 5 - Prob. 5.85SPCh. 5 - Prob. 5.86SPCh. 5 - Assign a set of four quantum numbers to each...Ch. 5 - Assign a set of four quantum numbers for the outer...Ch. 5 - Which of the following is a valid set of four...Ch. 5 - Prob. 5.90SPCh. 5 - Prob. 5.91SPCh. 5 - Prob. 5.92SPCh. 5 - Prob. 5.93SPCh. 5 - Prob. 5.94SPCh. 5 - Prob. 5.95SPCh. 5 - Order the electrons in the following orbitals...Ch. 5 - Order the following elements according to...Ch. 5 - Prob. 5.98SPCh. 5 - Prob. 5.99SPCh. 5 - Which orbital in each of the following pairs is...Ch. 5 - Order the orbitals for a multi electron atom in...Ch. 5 - According to the aufbau principle, which orbital...Ch. 5 - According to the autbau principle, which orbital...Ch. 5 - Give the expected ground-state electron...Ch. 5 - Give the expected ground-state electron...Ch. 5 - Draw orbital-filling diagrams for the following...Ch. 5 - Draw orbital-filling diagrams for atoms with the...Ch. 5 - How many unpaired electrons are present in each of...Ch. 5 - Identify the following atoms. (a) It has the...Ch. 5 - Prob. 5.110SPCh. 5 - Given the sub shells 1s, 2s, 2p, 3s, 3p and 3d,...Ch. 5 - Prob. 5.112SPCh. 5 - Prob. 5.113SPCh. 5 - Take a guess. What do you think is a likely...Ch. 5 - Take a guess. What is a likely ground-state...Ch. 5 - Prob. 5.116SPCh. 5 - Prob. 5.117SPCh. 5 - Prob. 5.118SPCh. 5 - Prob. 5.119SPCh. 5 - Prob. 5.120SPCh. 5 - Prob. 5.121SPCh. 5 - Prob. 5.122SPCh. 5 - Which atom in each of the following pairs has a...Ch. 5 - Orbital energies in single-electron atoms or ions,...Ch. 5 - Like He+ , the Li2+ ion is a single-electron...Ch. 5 - Prob. 5.126MPCh. 5 - Draw orbital-filling diagrams for the following...Ch. 5 - The atomic radii of Y (180 pm) and Li (187 pm) are...Ch. 5 - Prob. 5.129MPCh. 5 - Prob. 5.130MPCh. 5 - Prob. 5.131MPCh. 5 - The amount of energy necessary to remove an...Ch. 5 - Prob. 5.133MPCh. 5 - Prob. 5.134MPCh. 5 - Prob. 5.135MPCh. 5 - A minimum energy of 7.211019J is required to...Ch. 5 - Prob. 5.137MPCh. 5 - An energetically excited hydrogen atom has its...Ch. 5 - Prob. 5.139MP
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