OWLV2 FOR MOORE/STANITSKI'S CHEMISTRY:
5th Edition
ISBN: 9781285460369
Author: STANITSKI
Publisher: Cengage Learning
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Textbook Question
Chapter 5, Problem 54QRT
Titanium metal and Cr2+ have the same number of electrons. However, the electron configuration of Ti is [Ar] 4s23d2, but that of Cr2+ is [Ar] 3d4. Explain.
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Decide which of the following electron configurations is correct for the species given. Co+, [Ar]4s13d7 Ti+, [Ar]4s23d1 V, [Ar]4s23d3 Cr, [Ar]4s23d4 Ni3+, [Ar]3d7 Co3+, [Ar]3d6
1.
Explain, in terms of Coulombic energy and Exchange energy, why the ground-state electron configuration of Cr is [Ar]4s13d5 instead of [Ar]4s23d4.
Chapter 5 Solutions
OWLV2 FOR MOORE/STANITSKI'S CHEMISTRY:
Ch. 5.1 - In the upper atmosphere there is solar radiation...Ch. 5.1 - A fellow chemistry student says that low-frequency...Ch. 5.1 - One type of solar radiation in the upper...Ch. 5.2 - Prob. 5.2PSPCh. 5.2 - Prob. 5.3ECh. 5.3 - Prob. 5.4ECh. 5.3 - Prob. 5.3PSPCh. 5.3 - The hydrogen atom contains only one electron, but...Ch. 5.3 - (a) Calculate the frequency and the wavelength of...Ch. 5.3 - Show that the value of the Rydberg constant per...
Ch. 5.4 - Calculate the de Broglie wavelength of a neutron...Ch. 5.5 - Prob. 5.7ECh. 5.5 - Prob. 5.8ECh. 5.5 - Prob. 5.6PSPCh. 5.5 - Prob. 5.9ECh. 5.5 - Prob. 5.10CECh. 5.5 - Prob. 5.11ECh. 5.5 - Prob. 5.12ECh. 5.5 - Prob. 5.13CECh. 5.7 - Use atomic orbital box diagrams to determine which...Ch. 5.7 - Prob. 5.7PSPCh. 5.7 - Prob. 5.15ECh. 5.7 - Prob. 5.8PSPCh. 5.8 - (a) What Period 3 anion with a 2 charge has the...Ch. 5.8 - Prob. 5.10PSPCh. 5.8 - Fluoride ion, F, has no unpaired electrons....Ch. 5.9 - Prob. 5.11PSPCh. 5.10 - Which of these isoelectronic ions, Ba2+, Cs+, or...Ch. 5.11 - Prob. 5.13PSPCh. 5.13 - Consider these ionic compounds: KCl, CaS, CaO,...Ch. 5 - Prob. 1QRTCh. 5 - Prob. 2QRTCh. 5 - Prob. 3QRTCh. 5 - Prob. 4QRTCh. 5 - Prob. 5QRTCh. 5 - Prob. 6QRTCh. 5 - Prob. 7QRTCh. 5 - Prob. 8QRTCh. 5 -
Write the electron configurations for the valence...Ch. 5 - Prob. 10QRTCh. 5 - Prob. 11QRTCh. 5 - Prob. 12QRTCh. 5 - Prob. 13QRTCh. 5 - The colors of the visible spectrum and the...Ch. 5 - Prob. 15QRTCh. 5 - Prob. 16QRTCh. 5 - Prob. 17QRTCh. 5 - Prob. 18QRTCh. 5 - Prob. 19QRTCh. 5 - Light of very long wavelength strikes a...Ch. 5 - Prob. 21QRTCh. 5 - Prob. 22QRTCh. 5 - Prob. 23QRTCh. 5 - A photoemissive material has a threshold energy,...Ch. 5 - Prob. 25QRTCh. 5 - Prob. 26QRTCh. 5 - Prob. 27QRTCh. 5 - Prob. 28QRTCh. 5 - Prob. 29QRTCh. 5 - Prob. 30QRTCh. 5 - Prob. 31QRTCh. 5 - Calculate the energy and wavelength of the photon...Ch. 5 - Calculate the energy and the wavelength of the...Ch. 5 - Spectroscopists have observed He+ in outer space....Ch. 5 - Prob. 35QRTCh. 5 - Prob. 36QRTCh. 5 - Prob. 37QRTCh. 5 - Prob. 38QRTCh. 5 - Prob. 39QRTCh. 5 - Prob. 40QRTCh. 5 - Prob. 41QRTCh. 5 - Give possible values for all four quantum numbers...Ch. 5 - Prob. 43QRTCh. 5 - Assign a correct set of four quantum numbers for...Ch. 5 - Prob. 45QRTCh. 5 - Prob. 46QRTCh. 5 - Assign a correct set of four quantum numbers for...Ch. 5 - Prob. 48QRTCh. 5 - Prob. 49QRTCh. 5 - Prob. 50QRTCh. 5 - Prob. 51QRTCh. 5 - Prob. 52QRTCh. 5 - Prob. 53QRTCh. 5 - Titanium metal and Cr2+ have the same number of...Ch. 5 - Consider a 2+ ion that has six 3d electrons; which...Ch. 5 - Prob. 56QRTCh. 5 - Prob. 57QRTCh. 5 - Prob. 58QRTCh. 5 - Prob. 59QRTCh. 5 - Prob. 60QRTCh. 5 - Prob. 61QRTCh. 5 - Prob. 62QRTCh. 5 - Prob. 63QRTCh. 5 - Prob. 64QRTCh. 5 - Prob. 65QRTCh. 5 - Prob. 66QRTCh. 5 - Prob. 67QRTCh. 5 - Prob. 68QRTCh. 5 - Prob. 69QRTCh. 5 - Prob. 70QRTCh. 5 - Prob. 71QRTCh. 5 - Prob. 72QRTCh. 5 - Prob. 73QRTCh. 5 - Prob. 74QRTCh. 5 - Prob. 75QRTCh. 5 - Prob. 76QRTCh. 5 - Prob. 77QRTCh. 5 - Prob. 78QRTCh. 5 - Use electron configurations to explain why (a)...Ch. 5 - Prob. 80QRTCh. 5 - Arrange these elements in order of increasing...Ch. 5 - Prob. 82QRTCh. 5 - Arrange these elements in order of increasing...Ch. 5 - Prob. 84QRTCh. 5 - Prob. 85QRTCh. 5 - Prob. 86QRTCh. 5 - Prob. 87QRTCh. 5 - Prob. 88QRTCh. 5 - Prob. 89QRTCh. 5 - Compare the elements B, Al, C, Si. (a) Which has...Ch. 5 - Prob. 91QRTCh. 5 - Prob. 92QRTCh. 5 - Prob. 93QRTCh. 5 - Prob. 94QRTCh. 5 - Determine the lattice energy for LiCl(s) given...Ch. 5 - Prob. 96QRTCh. 5 - Prob. 97QRTCh. 5 - Prob. 98QRTCh. 5 - Prob. 99QRTCh. 5 - Prob. 100QRTCh. 5 - Prob. 101QRTCh. 5 - Prob. 102QRTCh. 5 - Prob. 103QRTCh. 5 - Prob. 104QRTCh. 5 - Prob. 105QRTCh. 5 - Prob. 106QRTCh. 5 - Prob. 107QRTCh. 5 - Prob. 108QRTCh. 5 - Prob. 109QRTCh. 5 - Prob. 113QRTCh. 5 - Prob. 114QRTCh. 5 - Prob. 115QRTCh. 5 - Prob. 116QRTCh. 5 - Prob. 117QRTCh. 5 - Prob. 119QRTCh. 5 - Prob. 120QRTCh. 5 - Prob. 121QRTCh. 5 - Prob. 123QRTCh. 5 - Prob. 124QRTCh. 5 - Prob. 125QRTCh. 5 - Prob. 126QRTCh. 5 - Prob. 127QRTCh. 5 - Prob. 128QRTCh. 5 - Prob. 129QRTCh. 5 - Calculate the effective nuclear charge, Z, on...Ch. 5 - Prob. 131QRTCh. 5 - Prob. 133QRTCh. 5 - Prob. 134QRTCh. 5 - Prob. 135QRTCh. 5 - According to a relationship developed by Niels...Ch. 5 - Prob. 137QRTCh. 5 - Prob. 138QRTCh. 5 - Prob. 139QRTCh. 5 - Prob. 140QRTCh. 5 - Prob. 141QRTCh. 5 - Prob. 142QRTCh. 5 - Prob. 143QRTCh. 5 - Prob. 144QRTCh. 5 - Prob. 5.ACPCh. 5 - Prob. 5.CCP
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- Write the ground state electron configuration for (a) Mg, Mg2+(b) N, N3- (c) Ti, Ti4+ (d) Sn2+ Sn4+arrow_forwardTi(NH3)63+ has a d-orbital electron transition at 399 nm. Find o at this wavelength.arrow_forwardUse partial atomic orbital box diagrams to explain the number of unpaired electrons shown in Figure 20.2 for (a) Mn2+ and (b) Cr3+.arrow_forward
- 6arrow_forwardAn ion with a +4 charge has a ground state electron configuration of [Ar]3d3. What is the ion?arrow_forward29) Give the correct electron configurations of Cr and Cu. Explain why they do not have the expected electron configurations. a) Which of the following are correct electron configuration(s) for Cr? a) [Ar]3d44s2 b) [Ar]3d54s1 c) [Ar]4s23d5 d) [Ar]4s13d4 b) Which of the following are correct electron configuration(s) for Cu? a) [Ar]3d94s2 b) [Ar]3d104s1 c) [Ar]4s13d9 d) [Ar]4s23d10 c) Why do Cr and Cu not have the expected electron configurations? a) Half filled orbitals are more stable than partially filled orbitals. b) Completely filled orbitals are more stable than partially filled orbitals. c) Partially filled orbitals are more stable than completely filled orbitals. d) Moving an electron from the s to d orbital lowers the energy of the atom. e) Moving an electron from the s to d orbital increases the energy of the atom.arrow_forward
- Which 2+ ion has the ground state electron configuration [Ar]3d³? Co2+ Fe2+ Mn²+ Cr²+ O V2+arrow_forwardWhich items from the following list are diamagnetic? Mg, Mo, Si , Hgarrow_forwardWhich metal ion is expected to have the electron configuration, [Kr]4d4? Hint: Remember that positive ions lose electrons Zr2+ Mo2+ Sr2+ Ru2+ Mn2+arrow_forward
- Fe 4s 3d 4s 3d Ni 1! 1 1L Ar]3d°4s² 4s 3d Cu 4s 3d Zn 1 1 1 I CAr]3d1®4s? 3d Shown above are actual electron configurations for the indicated atoms. Which of these is not the configuration predicted by theory? Explain why the metal has that particular configuration. Please type your answer below.arrow_forward[Ar]4s23d2 is the electron configuration for Zirconium Titanium Vanadium Scandiumarrow_forwardAn element X has the electron configuration [Kr] 5s24d105p. The formula for the bromide of X is most likelyarrow_forward
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