(a) Interpretation: A curve-arrow mechanism for the given reaction is to be drawn. Concept introduction: The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile. There are two types of nuclephilic substitution reaction. The S N 1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. There is generation of carbocation in the first step and in the second step the nucleophile attacks at the carbocation for the corresponding product.

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Answer 1

Question

Chapter 5, Problem 5.49AP

Interpretation Introduction

(a)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile. There are two types of nuclephilic substitution reaction.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. There is generation of carbocation in the first step and in the second step the nucleophile attacks at the carbocation for the corresponding product.

Interpretation Introduction

(b)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The reactions in which two substances are combined to give the products is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(c)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(d)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(e)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value.

Interpretation Introduction

(f)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propogation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions. The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value

Interpretation Introduction

(g)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

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An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.

The reaction of solid dimethylhydrazine, (CH3)2N2H2, and liquefied dinitrogen tetroxide, N2O4, has been investigated for use as rocket fuel. The reaction produces the gases carbon dioxide (CO2), nitrogen (N2), and water vapor (H2O), which are ejected in the exhaust gases. In a controlled experiment, solid dimethylhydrazine was reacted with excess dinitrogen tetroxide, and the gases were collected in a closed balloon until a pressure of 2.50 atm and a temperature of 400.0 K were reached.(a) What are the partial pressures of CO2, N2, and H2O?(b) When the CO2 is removed by chemical reaction, what are the partial pressures of the remaining gases?

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Answer 2

Question

Chapter 5, Problem 5.49AP

Interpretation Introduction

(a)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile. There are two types of nuclephilic substitution reaction.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. There is generation of carbocation in the first step and in the second step the nucleophile attacks at the carbocation for the corresponding product.

Interpretation Introduction

(b)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The reactions in which two substances are combined to give the products is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(c)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(d)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(e)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value.

Interpretation Introduction

(f)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propogation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions. The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value

Interpretation Introduction

(g)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

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Answer 3

Question

Chapter 5, Problem 5.49AP

Interpretation Introduction

(a)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile. There are two types of nuclephilic substitution reaction.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. There is generation of carbocation in the first step and in the second step the nucleophile attacks at the carbocation for the corresponding product.

Interpretation Introduction

(b)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The reactions in which two substances are combined to give the products is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(c)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(d)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(e)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value.

Interpretation Introduction

(f)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propogation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions. The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value

Interpretation Introduction

(g)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

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See solution

Answer 4

Question

Chapter 5, Problem 5.49AP

Interpretation Introduction

(a)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile. There are two types of nuclephilic substitution reaction.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. There is generation of carbocation in the first step and in the second step the nucleophile attacks at the carbocation for the corresponding product.

Interpretation Introduction

(b)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The reactions in which two substances are combined to give the products is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(c)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(d)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(e)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value.

Interpretation Introduction

(f)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propogation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions. The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value

Interpretation Introduction

(g)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

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Answer 5

Chapter 5, Problem 5.49AP

Interpretation Introduction

(a)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile. There are two types of nuclephilic substitution reaction.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. There is generation of carbocation in the first step and in the second step the nucleophile attacks at the carbocation for the corresponding product.

Interpretation Introduction

(b)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The reactions in which two substances are combined to give the products is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(c)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(d)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Interpretation Introduction

(e)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value.

Interpretation Introduction

(f)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propogation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions. The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value

Interpretation Introduction

(g)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

Answer 6

Chapter 5, Problem 5.49AP

Interpretation Introduction

(a)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile. There are two types of nuclephilic substitution reaction.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. There is generation of carbocation in the first step and in the second step the nucleophile attacks at the carbocation for the corresponding product.

Answer 7

Chapter 5, Problem 5.49AP

Interpretation Introduction

(a)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile. There are two types of nuclephilic substitution reaction.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. There is generation of carbocation in the first step and in the second step the nucleophile attacks at the carbocation for the corresponding product.

Answer 8

Interpretation Introduction

(b)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The reactions in which two substances are combined to give the products is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The reactions in which two substances are combined to give the products is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Answer 10

Interpretation Introduction

(c)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Answer 11

Interpretation Introduction

(c)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Answer 12

Interpretation Introduction

(d)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Answer 13

Interpretation Introduction

(d)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

The chemical reactions in which one molecules combines with the another molecule is known as addition reaction. The polymerization is also a type of addition reaction. The addition of molecules, electrophile or nucleophile to the alkene rings is also a type of addition reaction.

Answer 14

Interpretation Introduction

(e)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value.

Answer 15

Interpretation Introduction

(e)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value.

Answer 16

Interpretation Introduction

(f)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propogation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions. The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value

Answer 17

Interpretation Introduction

(f)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propogation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions. The free radicals are generated by the hemolytic cleavage of the bond between the atoms and such atoms shares same electronegativity value

Answer 18

Interpretation Introduction

(g)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

Answer 19

Interpretation Introduction

(g)

Interpretation:

A curve-arrow mechanism for the given reaction is to be drawn.

Concept introduction:

A chemical reaction which involves free radicals is known as free radical reaction. These reactions are comprised of three steps, the chain initiation step, the chain propagation step and the last, the chain termination step. The polymerization reactions are a type of free radical reactions.

Answer 20

Expert Solution & Answer

Answer 21

Expert Solution & Answer

Answer 22

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Answer 23

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Prob. 5.3P Ch. 5 - Prob. 5.4P Ch. 5 - Prob. 5.5P Ch. 5 - Prob. 5.6P Ch. 5 - Prob. 5.7P Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that the curve-arrow mechanism of the given reaction is shown in Figure 2, 3 and 4.

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Chapter 5 Solutions