(a) Interpretation: The free radical polymerization of low-density polyethylene (LDPE) is favorable is to be stated using bond dissociation energies. Concept introduction: A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The minimum amount of energy needed to dissociate a bond is known as the bond dissociation energy (BDE). The term bond dissociation energy is only used for diatomic species.

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Answer 1

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Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 5, Problem 5.45AP

Interpretation Introduction

(a)

Interpretation:

The free radical polymerization of low-density polyethylene (LDPE) is favorable is to be stated using bond dissociation energies.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The minimum amount of energy needed to dissociate a bond is known as the bond dissociation energy (BDE). The term bond dissociation energy is only used for diatomic species.

Interpretation Introduction

(b)

Interpretation:

The free radical polymerization for LDPE to form branched polyethylene chain is to be stated.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The free radical polymerization is an important process for the formation of variety of products with different structural arrangements.

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Answer 2

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Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 5, Problem 5.45AP

Interpretation Introduction

(a)

Interpretation:

The free radical polymerization of low-density polyethylene (LDPE) is favorable is to be stated using bond dissociation energies.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The minimum amount of energy needed to dissociate a bond is known as the bond dissociation energy (BDE). The term bond dissociation energy is only used for diatomic species.

Interpretation Introduction

(b)

Interpretation:

The free radical polymerization for LDPE to form branched polyethylene chain is to be stated.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The free radical polymerization is an important process for the formation of variety of products with different structural arrangements.

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Answer 3

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 5, Problem 5.45AP

Interpretation Introduction

(a)

Interpretation:

The free radical polymerization of low-density polyethylene (LDPE) is favorable is to be stated using bond dissociation energies.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The minimum amount of energy needed to dissociate a bond is known as the bond dissociation energy (BDE). The term bond dissociation energy is only used for diatomic species.

Interpretation Introduction

(b)

Interpretation:

The free radical polymerization for LDPE to form branched polyethylene chain is to be stated.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The free radical polymerization is an important process for the formation of variety of products with different structural arrangements.

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Answer 4

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 5, Problem 5.45AP

Interpretation Introduction

(a)

Interpretation:

The free radical polymerization of low-density polyethylene (LDPE) is favorable is to be stated using bond dissociation energies.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The minimum amount of energy needed to dissociate a bond is known as the bond dissociation energy (BDE). The term bond dissociation energy is only used for diatomic species.

Interpretation Introduction

(b)

Interpretation:

The free radical polymerization for LDPE to form branched polyethylene chain is to be stated.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The free radical polymerization is an important process for the formation of variety of products with different structural arrangements.

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Answer 5

Chapter 5, Problem 5.45AP

Interpretation Introduction

(a)

Interpretation:

The free radical polymerization of low-density polyethylene (LDPE) is favorable is to be stated using bond dissociation energies.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The minimum amount of energy needed to dissociate a bond is known as the bond dissociation energy (BDE). The term bond dissociation energy is only used for diatomic species.

Interpretation Introduction

(b)

Interpretation:

The free radical polymerization for LDPE to form branched polyethylene chain is to be stated.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The free radical polymerization is an important process for the formation of variety of products with different structural arrangements.

Answer 6

Chapter 5, Problem 5.45AP

Interpretation Introduction

(a)

Interpretation:

The free radical polymerization of low-density polyethylene (LDPE) is favorable is to be stated using bond dissociation energies.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The minimum amount of energy needed to dissociate a bond is known as the bond dissociation energy (BDE). The term bond dissociation energy is only used for diatomic species.

Answer 7

Chapter 5, Problem 5.45AP

Interpretation Introduction

(a)

Interpretation:

The free radical polymerization of low-density polyethylene (LDPE) is favorable is to be stated using bond dissociation energies.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The minimum amount of energy needed to dissociate a bond is known as the bond dissociation energy (BDE). The term bond dissociation energy is only used for diatomic species.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The free radical polymerization for LDPE to form branched polyethylene chain is to be stated.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The free radical polymerization is an important process for the formation of variety of products with different structural arrangements.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The free radical polymerization for LDPE to form branched polyethylene chain is to be stated.

Concept introduction:

A process of polymerization in which the growth of chain involves free radicals is known as free radical polymerization. The process includes three steps; the chain initiation step, the chain propagation step and the chain termination step. The free radical polymerization is an important process for the formation of variety of products with different structural arrangements.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Prob. 5.3P Ch. 5 - Prob. 5.4P Ch. 5 - Prob. 5.5P Ch. 5 - Prob. 5.6P Ch. 5 - Prob. 5.7P Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that the free radical polymerization of low-density polyethylene (LDPE) is favorable by using bond dissociation energies.

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