(a) Interpretation: The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated. Concept introduction: The general steps involved in the free-radical chain mechanism are as follows: • The first step is the initiation step. • The next step is the propagation step. • The third step is the termination step.

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Answer 1

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Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

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A J то گای ه +0 Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01 number of moles= 0.400/277.15 = 0.00144 moles 2 x 0.00 144=0.00288 moves arams of acetophenone = 0.00144 X 120.16 = 0.1739 0.1739x2=0.3469 grams of benzaldehyde = 0.00144X106.12=0.1539 0.1539x2 = 0.3069 Starting materials: 0.3469 Ox acetophenone, 0.3069 of benzaldehyde 3

1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.

3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗ

Answer 2

Question

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

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Answer 3

Question

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

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Answer 4

Question

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

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Answer 5

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Answer 6

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Answer 7

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Prob. 5.3P Ch. 5 - Prob. 5.4P Ch. 5 - Prob. 5.5P Ch. 5 - Prob. 5.6P Ch. 5 - Prob. 5.7P Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains the steps involved in the free-radical chain mechanism. The bromine free radical attacks the molecule of 1-pentene.

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