General, Organic, and Biochemistry
9th Edition
ISBN: 9780078021541
Author: Katherine J Denniston, Joseph J Topping, Dr Danae Quirk Dorr
Publisher: McGraw-Hill Education
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Chapter 5, Problem 5.27QP
Interpretation Introduction
Interpretation:
Gases exhibit more ideal behavior at low pressure or high pressure has to be given.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 5 Solutions
General, Organic, and Biochemistry
Ch. 5.1 - Prob. 5.1QCh. 5.1 - Prob. 5.2QCh. 5.1 - Prob. 5.1PPCh. 5.1 - Prob. 5.2PPCh. 5.1 - Prob. 5.3PPCh. 5.1 - Prob. 5.4PPCh. 5.1 - Prob. 5.5PPCh. 5.1 - Prob. 5.6PPCh. 5.1 - Prob. 5.7PPCh. 5.1 - Prob. 5.8PP
Ch. 5.1 - Prob. 5.3QCh. 5.1 - Prob. 5.4QCh. 5.1 - Prob. 5.5QCh. 5.1 - Prob. 5.6QCh. 5.2 - Prob. 5.7QCh. 5.2 - Prob. 5.8QCh. 5.2 - Prob. 5.9QCh. 5.2 - Prob. 5.10QCh. 5.2 - Prob. 5.11QCh. 5.2 - Prob. 5.12QCh. 5.3 - Prob. 5.13QCh. 5.3 - Prob. 5.14QCh. 5 - Prob. 5.15QPCh. 5 - Prob. 5.16QPCh. 5 - Prob. 5.17QPCh. 5 - Prob. 5.18QPCh. 5 - Prob. 5.19QPCh. 5 - Prob. 5.20QPCh. 5 - Prob. 5.21QPCh. 5 - Prob. 5.22QPCh. 5 - Prob. 5.23QPCh. 5 - Prob. 5.24QPCh. 5 - Prob. 5.25QPCh. 5 - Prob. 5.26QPCh. 5 - Prob. 5.27QPCh. 5 - Prob. 5.28QPCh. 5 - Prob. 5.29QPCh. 5 - Prob. 5.30QPCh. 5 - Prob. 5.31QPCh. 5 - Prob. 5.32QPCh. 5 - Prob. 5.33QPCh. 5 - Prob. 5.34QPCh. 5 - Prob. 5.35QPCh. 5 - Prob. 5.36QPCh. 5 - Prob. 5.37QPCh. 5 - Prob. 5.38QPCh. 5 - Calculate the pressure, in atm, required to...Ch. 5 - A balloon filled with helium gas at 1.00 atm...Ch. 5 - Prob. 5.41QPCh. 5 - Prob. 5.42QPCh. 5 - Prob. 5.43QPCh. 5 - The temperature on a summer day may be 90°F....Ch. 5 - Prob. 5.45QPCh. 5 - Prob. 5.46QPCh. 5 - Prob. 5.47QPCh. 5 - Prob. 5.48QPCh. 5 - A balloon containing a sample of helium gas is...Ch. 5 - The balloon described in Question 5.49 was then...Ch. 5 - Prob. 5.51QPCh. 5 - A balloon, filled with an ideal gas, has a volume...Ch. 5 - Prob. 5.53QPCh. 5 - Prob. 5.54QPCh. 5 - Prob. 5.55QPCh. 5 - Prob. 5.56QPCh. 5 - Prob. 5.57QPCh. 5 - A sealed balloon filled with helium gas occupies...Ch. 5 - A 5.00-L balloon exerts a pressure of 2.00 atm at...Ch. 5 - If we double the pressure and temperature of the...Ch. 5 - State Avogadro’s law in words.
Ch. 5 - Prob. 5.62QPCh. 5 - Prob. 5.63QPCh. 5 - Prob. 5.64QPCh. 5 - Prob. 5.65QPCh. 5 - Prob. 5.66QPCh. 5 - Prob. 5.67QPCh. 5 - Prob. 5.68QPCh. 5 - Prob. 5.69QPCh. 5 - Prob. 5.70QPCh. 5 - Prob. 5.71QPCh. 5 - Prob. 5.72QPCh. 5 - Prob. 5.73QPCh. 5 - Prob. 5.74QPCh. 5 - Prob. 5.75QPCh. 5 - Calculate the pressure (atm) exerted by 1.00 mol...Ch. 5 - A sample of argon (Ar) gas occupies 65.0 mL at...Ch. 5 - A sample of O2 gas occupies 257 mL at 20°C and...Ch. 5 - Prob. 5.79QPCh. 5 - Prob. 5.80QPCh. 5 - Prob. 5.81QPCh. 5 - Calculate the volume of 6.00 mol O2 gas at 30 cm...Ch. 5 - State Dalton’s law in words.
Ch. 5 - Prob. 5.84QPCh. 5 - Prob. 5.85QPCh. 5 - Prob. 5.86QPCh. 5 - Prob. 5.87QPCh. 5 - Prob. 5.88QPCh. 5 - Prob. 5.89QPCh. 5 - Prob. 5.90QPCh. 5 - Prob. 5.91QPCh. 5 - Prob. 5.92QPCh. 5 - Prob. 5.93QPCh. 5 - Prob. 5.94QPCh. 5 - Prob. 5.95QPCh. 5 - Prob. 5.96QPCh. 5 - Prob. 5.97QPCh. 5 - Prob. 5.98QPCh. 5 - Prob. 5.99QPCh. 5 - Prob. 5.100QPCh. 5 - Prob. 5.101QPCh. 5 - Prob. 5.102QPCh. 5 - Prob. 5.103QPCh. 5 - Prob. 5.104QPCh. 5 - Prob. 5.105QPCh. 5 - Prob. 5.106QPCh. 5 - Prob. 5.107QPCh. 5 - Prob. 5.108QPCh. 5 - Prob. 5.109QPCh. 5 - Prob. 5.110QPCh. 5 - Prob. 5.111QPCh. 5 - Prob. 5.112QPCh. 5 - Prob. 1CPCh. 5 - Prob. 2CPCh. 5 - Prob. 3CPCh. 5 - Prob. 4CPCh. 5 - Prob. 5CPCh. 5 - Prob. 6CP
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