ORGANIC CHEMISTRY
9th Edition
ISBN: 9780134645704
Author: WADE AND SIMEK
Publisher: PEARSON
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Textbook Question
Chapter 5, Problem 5.25SP
The following four structures are naturally occurring optically active compounds. Star (*) the asymmetric carbon atoms in these structures.
Expert Solution & Answer
Interpretation Introduction
Interpretation: The asymmetric carbon atoms in the given structures are to be marked by star.
Concept introduction: A chiral carbon atom is attached to four different atoms or group of atoms and shows a tetrahedral geometry. The mirror image of a chiral compound is non-super imposable. The two different forms in which a single chiral carbon can exist are referred as enantiomers. The number of enantiomers of a molecule depends on the number of chiral centers.
To determine: The asymmetric carbon atoms in the given structures marked by star.
Answer to Problem 5.25SP
The asymmetric carbon atoms in the given structure have been marked by star.
Explanation of Solution
The given compound is serine. It is attached to
The asymmetric carbon atom present in it is marked by star as shown below.
Figure 1
The given compound is erythrose. There are two chiral centres present in it.
The asymmetric carbon atoms present in it are marked by star as shown below.
Figure 2
The given compound is menthol. There are three chiral centres present in it.
The asymmetric carbon atoms present in it are marked by star as shown below.
Figure 3
The given compound is camphor. There are two chiral centres present in it.
The asymmetric carbon atoms present in it are marked by star as shown below.
Figure 4
Conclusion
The asymmetric carbon atoms in the given structure have been marked by star.
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QUESTION 1
Write the IUPAC names for the following compounds.
(a)
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Chapter 5 Solutions
ORGANIC CHEMISTRY
Ch. 5.2 - Determine whether the following objects are chiral...Ch. 5.2A - Prob. 5.2PCh. 5.2B - Prob. 5.3PCh. 5.2B - Prob. 5.4PCh. 5.2C - Prob. 5.5PCh. 5.3 - Prob. 5.6PCh. 5.3 - Prob. 5.7PCh. 5.4D - Prob. 5.8PCh. 5.4D - Prob. 5.9PCh. 5.4D - Prob. 5.10P
Ch. 5.5 - Prob. 5.11PCh. 5.7 - When optically pure (R)-2-bromobutane is heated...Ch. 5.7 - Prob. 5.13PCh. 5.8 - Prob. 5.14PCh. 5.9B - Draw three-dimensional representations of the...Ch. 5.10A - For each sot of examples, make a model of the...Ch. 5.10A - Draw a Fischer projection for each compound....Ch. 5.10B - Prob. 5.18PCh. 5.10C - For each Fischer projection, label each asymmetric...Ch. 5.11C - Prob. 5.20PCh. 5.13 - Prob. 5.21PCh. 5.13 - Prob. 5.22PCh. 5.15 - Prob. 5.23PCh. 5.16A - Prob. 5.24PCh. 5 - The following four structures are naturally...Ch. 5 - For each structure, 1. star () any asymmetric...Ch. 5 - Prob. 5.27SPCh. 5 - Prob. 5.28SPCh. 5 - Prob. 5.29SPCh. 5 - Prob. 5.30SPCh. 5 - Prob. 5.31SPCh. 5 - Prob. 5.32SPCh. 5 - Prob. 5.33SPCh. 5 - Prob. 5.34SPCh. 5 - For each structure, 1. draw all the stereoisomers....Ch. 5 - Prob. 5.36SPCh. 5 - Prob. 5.37SPCh. 5 - 3,4-Dimethylpent-1-ene has the formula...Ch. 5 - A graduate student was studying enzymatic...Ch. 5 - Prob. 5.40SPCh. 5 - Prob. 5.41SP
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