To drraw: The structure of ( S ) − 2 − iodobutane . Interpretation: The structure of ( S ) − 2 − iodobutane is to be drawn. Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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Answer 1

Question

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Answer 2

Question

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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Answer 3

Question

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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Answer 4

Question

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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Answer 5

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 6

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 7

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 8

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 9

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 10

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 11

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 5.2 - Determine whether the following objects are chiral...Ch. 5.2A - Prob. 5.2P Ch. 5.2B - Prob. 5.3P Ch. 5.2B - Prob. 5.4P Ch. 5.2C - Prob. 5.5P Ch. 5.3 - Prob. 5.6P Ch. 5.3 - Prob. 5.7P Ch. 5.4D - Prob. 5.8P Ch. 5.4D - Prob. 5.9P Ch. 5.4D - Prob. 5.10P

Solution Summary: The author explains how the enantiomers of a chiral compound can be named with the help of right hand and left hand configuration.

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Chapter 5 Solutions