(a) Interpretation: Fischer projection structure of the given molecule is to be drawn. Concept introduction: The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

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Answer 1

Question

Chapter 5, Problem 5.23P

Interpretation Introduction

(a)

Interpretation:

Fischer projection structure of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

Interpretation Introduction

Interpretation:

(b)

Fischer projection of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

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34. Give the expected major product of each of the following reactions. Conc. HI a. CH3CH2CH2OH b. (CH3)2CHCH2CH2OH Conc. HBr H Conc. HI C. OH Conc.HCI d. (CH3CH2)3COH

42. Which of the following halogenated compounds can be used successfully to prepare a Grignard reagent for alcohol synthesis by subsequent reaction with an aldehyde or ketone? Which ones cannot and why? H3C CH3 a. Br H OH b. Cl C. I H H d. Cl e. H OCH3 Br H

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? Will the first MgBr product that forms in this reaction create a new CC bond? olo ? OH جمله O Yes Ⓒ No MgCl ? Will the first product that forms in this reaction create a new CC bond? Click and drag to start drawing a structure. Yes No X ☐ : ☐ टे PH

Answer 2

Question

Chapter 5, Problem 5.23P

Interpretation Introduction

(a)

Interpretation:

Fischer projection structure of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

Interpretation Introduction

Interpretation:

(b)

Fischer projection of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

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Answer 3

Question

Chapter 5, Problem 5.23P

Interpretation Introduction

(a)

Interpretation:

Fischer projection structure of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

Interpretation Introduction

Interpretation:

(b)

Fischer projection of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

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Answer 4

Question

Chapter 5, Problem 5.23P

Interpretation Introduction

(a)

Interpretation:

Fischer projection structure of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

Interpretation Introduction

Interpretation:

(b)

Fischer projection of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

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Answer 5

Chapter 5, Problem 5.23P

Interpretation Introduction

(a)

Interpretation:

Fischer projection structure of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

Interpretation Introduction

Interpretation:

(b)

Fischer projection of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

Answer 6

Chapter 5, Problem 5.23P

Interpretation Introduction

(a)

Interpretation:

Fischer projection structure of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

Answer 7

Chapter 5, Problem 5.23P

Interpretation Introduction

(a)

Interpretation:

Fischer projection structure of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

Answer 8

Interpretation Introduction

Interpretation:

(b)

Fischer projection of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

Answer 9

Interpretation Introduction

Interpretation:

(b)

Fischer projection of the given molecule is to be drawn.

Concept introduction:

The two-dimensional projection of a three-dimensional organic molecule is nothing but Fischer projection. Fischer projections are generally drawn with the longest carbon chain vertical. The two groups attached to each carbon except the first and last are shown on horizontal bonds. The carbon atoms in the middle of the chain are represented by the intersections of vertical and horizontal lines. The vertical lines show bonds that aligned away from the observer, while the horizontal bonds are aligned towards the observer.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Prob. 5.3P Ch. 5 - Prob. 5.4P Ch. 5 - Prob. 5.5P Ch. 5 - Prob. 5.6P Ch. 5 - Prob. 5.7P Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that the dash-wedge structure of a three-dimensional organic molecule is nothing but Fischer projection.

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