Chemistry: The Molecular Nature of Matter and Change
Chemistry: The Molecular Nature of Matter and Change
9th Edition
ISBN: 9781260477467
Author: Martin Silberberg
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 5, Problem 5.1P

(a)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is transferred from one container to a large one.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas. 

(a)

Expert Solution
Check Mark

Answer to Problem 5.1P

When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant. 

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. Due to high kinetic energy, the particles can move randomly so they occupy the volume of the container. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

(b)

Interpretation Introduction

Interpretation:  The difference in the behavior of the sample of gas and liquid should be determined if the sample is heated in an expandable container without any change in the state of matter.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas. 

(b)

Expert Solution
Check Mark

Answer to Problem 5.1P

When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the container will increase whereas the volume of a sample with liquid does not change on heating.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the gas will increase whereas the volume of a sample with liquid does not change on heating.

(c)

Interpretation Introduction

Interpretation:  The difference in the behavior of the sample of gas and liquid should be determined if the sample is placed in a cylinder with a piston and external force is applied.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas. 

(c)

Expert Solution
Check Mark

Answer to Problem 5.1P

When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant whereas the volume of the gas is reduced.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces and lesser intermolecular space between particles compared to gases. When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant as liquids are not compressible whereas the volume of the gas is reduced because gases are highly compressible due to large intermolecular distance.

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Chapter 5 Solutions

Chemistry: The Molecular Nature of Matter and Change

Ch. 5.3 - Prob. 5.6AFPCh. 5.3 - A blimp is filled with 3950 kg of helium at 731...Ch. 5.3 - Prob. 5.7AFPCh. 5.3 - Prob. 5.7BFPCh. 5.4 - Prob. 5.8AFPCh. 5.4 - Prob. 5.8BFPCh. 5.4 - Prob. 5.9AFPCh. 5.4 - Prob. 5.9BFPCh. 5.4 - To prevent air from interacting with highly...Ch. 5.4 - Prob. 5.10BFPCh. 5.4 - Prob. 5.11AFPCh. 5.4 - Prob. 5.11BFPCh. 5.4 - Prob. 5.12AFPCh. 5.4 - Prob. 5.12BFPCh. 5.4 - Ammonia and hydrogen chloride gases react to form...Ch. 5.4 - Prob. 5.13BFPCh. 5.5 - If it takes 1.25 min for 0.010 mol of He to...Ch. 5.5 - If 7.23 mL of an unknown gas effuses in the same...Ch. 5.5 - Prob. 5.1PCh. 5.5 - Prob. 5.2PCh. 5.5 - Prob. 5.3PCh. 5.5 - Prob. 5.4PCh. 5 - Prob. 5.1PCh. 5 - Prob. 5.2PCh. 5 - Prob. 5.3PCh. 5 - Prob. 5.4PCh. 5 - Prob. 5.5PCh. 5 - Prob. 5.6PCh. 5 - Prob. 5.7PCh. 5 - Prob. 5.8PCh. 5 - Prob. 5.9PCh. 5 - In Figure P5.10, what is the pressure of the gas...Ch. 5 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Prob. 5.13PCh. 5 - Prob. 5.14PCh. 5 - The gravitational force exerted by an object is...Ch. 5 - Prob. 5.16PCh. 5 - Prob. 5.17PCh. 5 - Prob. 5.18PCh. 5 - Prob. 5.19PCh. 5 - What is the effect of the following on volume of 1...Ch. 5 - Prob. 5.21PCh. 5 - Prob. 5.22PCh. 5 - What is the effect of the following on the volume...Ch. 5 - Prob. 5.24PCh. 5 - Prob. 5.25PCh. 5 - Prob. 5.26PCh. 5 - Prob. 5.27PCh. 5 - Prob. 5.28PCh. 5 - Prob. 5.29PCh. 5 - Prob. 5.30PCh. 5 - Prob. 5.31PCh. 5 - Prob. 5.32PCh. 5 - Prob. 5.33PCh. 5 - Prob. 5.34PCh. 5 - Prob. 5.35PCh. 5 - You have 357 mL of chlorine trifluoride gas at 699...Ch. 5 - Prob. 5.37PCh. 5 - Prob. 5.38PCh. 5 - Prob. 5.39PCh. 5 - Prob. 5.40PCh. 5 - Prob. 5.41PCh. 5 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Prob. 5.44PCh. 5 - Prob. 5.45PCh. 5 - Prob. 5.46PCh. 5 - Prob. 5.47PCh. 5 - Prob. 5.48PCh. 5 - Prob. 5.49PCh. 5 - Prob. 5.50PCh. 5 - After 0.600 L of Ar at 1.20 atm and 227°C is mixed...Ch. 5 - A 355-mL container holds 0.146 g of Ne and an...Ch. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - Prob. 5.55PCh. 5 - Prob. 5.56PCh. 5 - Prob. 5.57PCh. 5 - How many liters of hydrogen gas are collected over...Ch. 5 - Prob. 5.59PCh. 5 - Prob. 5.60PCh. 5 - Prob. 5.61PCh. 5 - Prob. 5.62PCh. 5 - Prob. 5.63PCh. 5 - Prob. 5.64PCh. 5 - Freon-12 (CF2C12), widely used as a refrigerant...Ch. 5 - Prob. 5.66PCh. 5 - Prob. 5.67PCh. 5 - Prob. 5.68PCh. 5 - Prob. 5.69PCh. 5 - Prob. 5.70PCh. 5 - Prob. 5.71PCh. 5 - Prob. 5.72PCh. 5 - Prob. 5.73PCh. 5 - Prob. 5.74PCh. 5 - Prob. 5.75PCh. 5 - Prob. 5.76PCh. 5 - Prob. 5.77PCh. 5 - Prob. 5.78PCh. 5 - Prob. 5.79PCh. 5 - Prob. 5.80PCh. 5 - Prob. 5.81PCh. 5 - Prob. 5.82PCh. 5 - Prob. 5.83PCh. 5 - Do interparticle attractions cause negative or...Ch. 5 - Prob. 5.85PCh. 5 - Prob. 5.86PCh. 5 - Prob. 5.87PCh. 5 - Prob. 5.88PCh. 5 - Prob. 5.89PCh. 5 - Prob. 5.90PCh. 5 - Prob. 5.91PCh. 5 - Prob. 5.92PCh. 5 - Prob. 5.93PCh. 5 - Prob. 5.94PCh. 5 - Prob. 5.95PCh. 5 - Prob. 5.96PCh. 5 - Prob. 5.97PCh. 5 - Prob. 5.98PCh. 5 - Prob. 5.99PCh. 5 - Prob. 5.100PCh. 5 - Prob. 5.101PCh. 5 - Prob. 5.102PCh. 5 - Prob. 5.103PCh. 5 - Prob. 5.104PCh. 5 - Prob. 5.105PCh. 5 - An atmospheric chemist studying the pollutant SO2...Ch. 5 - The thermal decomposition of ethylene occurs...Ch. 5 - Prob. 5.108PCh. 5 - Prob. 5.109PCh. 5 - Prob. 5.110PCh. 5 - Prob. 5.111PCh. 5 - Prob. 5.112PCh. 5 - Containers A, B and C are attached by closed...Ch. 5 - Prob. 5.114PCh. 5 - Prob. 5.115PCh. 5 - Prob. 5.116PCh. 5 - Prob. 5.117PCh. 5 - Prob. 5.118PCh. 5 - Prob. 5.119PCh. 5 - Prob. 5.120PCh. 5 - Prob. 5.121PCh. 5 - Prob. 5.122PCh. 5 - Prob. 5.123PCh. 5 - Prob. 5.124PCh. 5 - Prob. 5.125PCh. 5 - For each of the following, which shows the greater...Ch. 5 - Prob. 5.127PCh. 5 - Prob. 5.128PCh. 5 - Prob. 5.129PCh. 5 - Prob. 5.130PCh. 5 - Prob. 5.131PCh. 5 - Gases such as CO are gradually oxidized in the...Ch. 5 - Aqueous sulfurous acid (H2SO3) was made by...Ch. 5 - Prob. 5.134PCh. 5 - Prob. 5.135PCh. 5 - The lunar surface reaches 370 K at midday. The...Ch. 5 - Prob. 5.137PCh. 5 - Popcorn pops because the horny endosperm, a...Ch. 5 - Prob. 5.139PCh. 5 - Prob. 5.140PCh. 5 - Prob. 5.141PCh. 5 - Prob. 5.142PCh. 5 - Prob. 5.143PCh. 5 - Prob. 5.144PCh. 5 - Prob. 5.145PCh. 5 - Prob. 5.146PCh. 5 - Prob. 5.147PCh. 5 - Prob. 5.148PCh. 5 - An equimolar mixture of Ne and Xe is accidentally...Ch. 5 - Prob. 5.150PCh. 5 - A slight deviation from ideal behavior exists even...Ch. 5 - In preparation for a combustion demonstration, a...Ch. 5 - Prob. 5.153PCh. 5 - A truck tire has a volume of 218 L and is filled...Ch. 5 - Allotropes are different molecular forms of an...Ch. 5 - Prob. 5.156PCh. 5 - Prob. 5.157P
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