Physical Chemistry Plus Mastering Chemistry With Etext -- Access Card Package (3rd Edition) (engel Physical Chemistry Series)
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Chapter 5, Problem 5.16NP

(a)

Interpretation Introduction

Interpretation: The value of heat, work done, change in internal energy, change in entropy and change in enthalpy needs to be determined if a gas undergoes a reversible adiabatic expansion and final pressure is 1/3rd of the initial.

Concept Introduction:

The change in enthalpy for a process can be calculated as follows:

  ΔH=CP,mnΔT

Here, CP,m is molar heat capacity at constant pressure.

Also, the change in internal energy as follows:

  ΔU=CV,mnΔT

Here, CV,m is molar heat capacity at constant volume.

Also,

  ΔU=q+w

Here, q is heat and w is work done.

The ideal gas equation is represented as follows:

  PV=nRT

Here, P is pressure, V is volume, n is number of moles, R is Universal gas constant and T is temperature.

(b)

Interpretation Introduction

Interpretation: The value of heat, work done, change in internal energy, change in entropy and change in enthalpy needs to be determined if a gas undergoes an adiabatic expansion at constant external pressure and final pressure is 1/3rd of the initial volume.

Concept Introduction:

The change in enthalpy for a process can be calculated as follows:

  ΔH=CP,mnΔT

Here, CP,m is molar heat capacity at constant pressure.

Also, the change in internal energy as follows:

  ΔU=CV,mnΔT

Here, CV,m is molar heat capacity at constant volume.

Also,

  ΔU=q+w

Here, q is heat and w is work done.

The ideal gas equation is represented as follows:

  PV=nRT

Here, P is pressure, V is volume, n is number of moles, R is Universal gas constant and T is temperature.

(c)

Interpretation Introduction

Interpretation: The value of heat, work done, change in internal energy, change in entropy and change in enthalpy needs to be determined if a gas undergoes an expansion at zero external pressure and final pressure is 1/3rd of the initial volume.

Concept Introduction:

The change in enthalpy for a process can be calculated as follows:

  ΔH=CP,mnΔT

Here, CP,m is molar heat capacity at constant pressure.

Also, the change in internal energy as follows:

  ΔU=CV,mnΔT

Here, CV,m is molar heat capacity at constant volume.

Also,

  ΔU=q+w

Here, q is heat and w is work done.

The ideal gas equation is represented as follows:

  PV=nRT

Here, P is pressure, V is volume, n is number of moles, R is Universal gas constant and T is temperature.

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