Physical Chemistry Plus Mastering Chemistry With Etext -- Access Card Package (3rd Edition) (engel Physical Chemistry Series)
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Chapter 5, Problem 5.10NP
Interpretation Introduction

Interpretation:

The maximum theoretical efficiency of an internal combustion engine operating in the Otto cycle for a fuel-air mixture at 273 K at a compression ratio of 6.9 and 15 needs to be calculated

Concept Introduction:

The efficiency (e) of a Carnot engine is a function of the reservoir temperatures and can be expressed as:

  ε = 1TcoldThot ------(1)

For the expansion of an ideal gas mixture from an initial temperature and volume of Ti and Vi to a final temperature and volume of Tfand Vf respectively, the various parameters are related by the following equation:

  TfTi = ( V f V i )1γ  ------(2)γ = CpCv and ViVf= compression ratio

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