CHEMISTRY (LOOSELEAF) >CUSTOM<
13th Edition
ISBN: 9781264348992
Author: Chang
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Question
Chapter 5, Problem 5.137QP
(a)
Interpretation Introduction
Interpretation:
The mass of Mercury vapor has to be calculated.
Concept Introduction:
Ideal gas is the most usually used form of the ideal gas equation, which describes the relationship among the four variables P, V, n, and T. An ideal gas is a hypothetical sample of gas whose pressure-volume-temperature behavior is predicted accurately by the ideal gas equation.
(b)
Interpretation Introduction
Interpretation:
The concentration of mercury vapor has to be calculated.
(c)
Interpretation Introduction
Interpretation:
The concentration of mercury vapor and a physical and a chemical reason for this action has to be calculated.
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Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Chapter 5 Solutions
CHEMISTRY (LOOSELEAF) >CUSTOM<
Ch. 5.2 - Prob. 1PECh. 5.2 - Prob. 2PECh. 5.2 - Express 1184 torr in units of mmHg, atm, and kPa.Ch. 5.2 - Rank the following pressures from lowest to...Ch. 5.2 - Prob. 3RCFCh. 5.3 - A gas occupies a volume of 2.50 L at 375 mmHg....Ch. 5.3 - Prob. 2RCFCh. 5.3 - What volume of ClF3 will be produced when 75.0 mL...Ch. 5.4 - Calculate the volume (in liters) occupied by 2.12...Ch. 5.4 - Prob. 4PE
Ch. 5.4 - A sample of chlorine gas occupies a volume of 946...Ch. 5.4 - Prob. 6PECh. 5.4 - A gas initially at 4.0 L, 1.2 atm, and 66C...Ch. 5.4 - What is the density (in g/L) of uranium...Ch. 5.4 - Prob. 9PECh. 5.4 - Prob. 10PECh. 5.4 - Prob. 1RCFCh. 5.4 - Prob. 2RCFCh. 5.4 - Prob. 3RCFCh. 5.5 - Prob. 11PECh. 5.5 - The equation for the metabolic breakdown of...Ch. 5.5 - Prob. 13PECh. 5.5 - Zinc metal reacts with hydrochloric acid according...Ch. 5.5 - Prob. 2RCFCh. 5.6 - Prob. 14PECh. 5.6 - Prob. 15PECh. 5.6 - Prob. 1RCFCh. 5.6 - Prob. 2RCFCh. 5.6 - Prob. 3RCFCh. 5.7 - Prob. 16PECh. 5.7 - Prob. 17PECh. 5.7 - Prob. 1RCFCh. 5.7 - Prob. 2RCFCh. 5.8 - Using the data shown in Table 5.4, calculate the...Ch. 5.8 - Prob. 1RCFCh. 5.8 - Prob. 2RCFCh. 5 - Prob. 5.1QPCh. 5 - Prob. 5.2QPCh. 5 - Prob. 5.3QPCh. 5 - Prob. 5.4QPCh. 5 - Prob. 5.5QPCh. 5 - Prob. 5.6QPCh. 5 - Prob. 5.7QPCh. 5 - Prob. 5.8QPCh. 5 - Prob. 5.9QPCh. 5 - Prob. 5.10QPCh. 5 - Prob. 5.11QPCh. 5 - Prob. 5.12QPCh. 5 - Convert 562 mmHg to atm.Ch. 5 - Prob. 5.14QPCh. 5 - Prob. 5.15QPCh. 5 - A gaseous sample of a substance is cooled at...Ch. 5 - Consider the following gaseous sample in a...Ch. 5 - Prob. 5.19QPCh. 5 - Prob. 5.20QPCh. 5 - Prob. 5.21QPCh. 5 - A sample of air occupies 3.8 L when the pressure...Ch. 5 - Prob. 5.23QPCh. 5 - Under constant-pressure conditions a sample of...Ch. 5 - Ammonia burns in oxygen gas to form nitric oxide...Ch. 5 - Molecular chlorine and molecular fluorine combine...Ch. 5 - Prob. 5.27QPCh. 5 - Prob. 5.28QPCh. 5 - Prob. 5.29QPCh. 5 - Prob. 5.30QPCh. 5 - Prob. 5.31QPCh. 5 - Given that 6.9 moles of carbon monoxide gas are...Ch. 5 - What volume will 5.6 moles of sulfur hexafluoride...Ch. 5 - Prob. 5.34QPCh. 5 - Prob. 5.35QPCh. 5 - Prob. 5.36QPCh. 5 - Prob. 5.37QPCh. 5 - Prob. 5.38QPCh. 5 - An ideal gas originally at 0.85 atm and 66C was...Ch. 5 - Prob. 5.40QPCh. 5 - Prob. 5.41QPCh. 5 - Dry ice is solid carbon dioxide. A 0.050-g sample...Ch. 5 - Prob. 5.43QPCh. 5 - At 741 torr and 44C, 7.10 g of a gas occupy a...Ch. 5 - Ozone molecules in the stratosphere absorb much of...Ch. 5 - Prob. 5.46QPCh. 5 - A 2.10-L vessel contains 4.65 g of a gas at 1.00...Ch. 5 - Calculate the density of hydrogen bromide (HBr)...Ch. 5 - A certain anesthetic contains 64.9 percent C, 13.5...Ch. 5 - A compound has the empirical formula SF4. At 20C,...Ch. 5 - Prob. 5.51QPCh. 5 - The density of a mixture of fluorine and chlorine...Ch. 5 - Consider the formation of nitrogen dioxide from...Ch. 5 - Methane, the principal component of natural gas,...Ch. 5 - When coal is burned, the sulfur present in coal is...Ch. 5 - In alcohol fermentation, yeast converts glucose to...Ch. 5 - Prob. 5.57QPCh. 5 - A quantity of 0.225 g of a metal M (molar mass =...Ch. 5 - What is the mass of the solid NH4Cl formed when...Ch. 5 - Prob. 5.60QPCh. 5 - Prob. 5.61QPCh. 5 - Ethanol (C2H5OH) burns in air:...Ch. 5 - (a) What volumes (in liters) of ammonia and oxygen...Ch. 5 - Prob. 5.64QPCh. 5 - Prob. 5.65QPCh. 5 - A sample of air contains only nitrogen and oxygen...Ch. 5 - A mixture of gases contains 0.31 mol CH4, 0.25 mol...Ch. 5 - A 2.5-L flask at 15C contains a mixture of N2, He,...Ch. 5 - Dry air near sea level has the following...Ch. 5 - Prob. 5.70QPCh. 5 - Prob. 5.71QPCh. 5 - A sample of zinc metal reacts completely with an...Ch. 5 - Prob. 5.73QPCh. 5 - A sample of ammonia (NH3) gas is completely...Ch. 5 - Prob. 5.75QPCh. 5 - The volume of the box on the right is twice that...Ch. 5 - Prob. 5.78QPCh. 5 - Prob. 5.79QPCh. 5 - Prob. 5.80QPCh. 5 - Compare the root-mean-square speeds of O2 and UF6...Ch. 5 - Prob. 5.82QPCh. 5 - The average distance traveled by a molecule...Ch. 5 - At a certain temperature the speeds of six gaseous...Ch. 5 - Prob. 5.85QPCh. 5 - The 235U isotope undergoes fission when bombarded...Ch. 5 - Prob. 5.87QPCh. 5 - Prob. 5.88QPCh. 5 - Prob. 5.90QPCh. 5 - (a) A real gas is introduced into a flask of...Ch. 5 - Using the data shown in Table 5.4, calculate the...Ch. 5 - Prob. 5.94QPCh. 5 - Prob. 5.95QPCh. 5 - Prob. 5.96QPCh. 5 - Prob. 5.97QPCh. 5 - Prob. 5.98QPCh. 5 - When ammonium nitrite (NH4NO2) is heated, it...Ch. 5 - The percent by mass of bicarbonate (HCO3) in a...Ch. 5 - Prob. 5.101QPCh. 5 - Prob. 5.102QPCh. 5 - Prob. 5.103QPCh. 5 - A healthy adult exhales about 5.0 102 mL of a...Ch. 5 - Prob. 5.105QPCh. 5 - Prob. 5.106QPCh. 5 - Some commercial drain cleaners contain a mixture...Ch. 5 - The volume of a sample of pure HCl gas was 189 mL...Ch. 5 - Prob. 5.109QPCh. 5 - Prob. 5.110QPCh. 5 - Prob. 5.111QPCh. 5 - Prob. 5.112QPCh. 5 - Prob. 5.113QPCh. 5 - Prob. 5.114QPCh. 5 - Prob. 5.115QPCh. 5 - Prob. 5.116QPCh. 5 - Prob. 5.117QPCh. 5 - Commercially, compressed oxygen is sold in metal...Ch. 5 - Prob. 5.119QPCh. 5 - Prob. 5.120QPCh. 5 - Prob. 5.121QPCh. 5 - Prob. 5.122QPCh. 5 - Prob. 5.123QPCh. 5 - Prob. 5.124QPCh. 5 - Prob. 5.125QPCh. 5 - Prob. 5.126QPCh. 5 - Prob. 5.127QPCh. 5 - Prob. 5.128QPCh. 5 - Acidic oxides such as carbon dioxide react with...Ch. 5 - Prob. 5.130QPCh. 5 - Prob. 5.131QPCh. 5 - Prob. 5.132QPCh. 5 - Atop Mt. Everest, the atmospheric pressure is 210...Ch. 5 - Prob. 5.134QPCh. 5 - Prob. 5.135QPCh. 5 - Prob. 5.136QPCh. 5 - Prob. 5.137QPCh. 5 - Prob. 5.138QPCh. 5 - Prob. 5.139QPCh. 5 - Prob. 5.140QPCh. 5 - Prob. 5.141QPCh. 5 - Prob. 5.142QPCh. 5 - Prob. 5.143QPCh. 5 - Prob. 5.144QPCh. 5 - Prob. 5.145QPCh. 5 - At what temperature will He atoms have the same...Ch. 5 - Prob. 5.148QPCh. 5 - Prob. 5.149QPCh. 5 - Prob. 5.150QPCh. 5 - Prob. 5.151QPCh. 5 - Prob. 5.152QPCh. 5 - Prob. 5.153QPCh. 5 - A 6.11-g sample of a Cu-Zn alloy reacts with HCl...Ch. 5 - Prob. 5.155QPCh. 5 - Prob. 5.156QPCh. 5 - Prob. 5.157QPCh. 5 - A mixture of methane (CH4) and ethane (C2H6) is...Ch. 5 - Prob. 5.159QPCh. 5 - One way to gain a physical understanding of b in...Ch. 5 - Use the van der Waals constants in Table 5.4. to...Ch. 5 - Prob. 5.162QPCh. 5 - Prob. 5.163QPCh. 5 - Prob. 5.164QPCh. 5 - Referring to Figure 5.17, we see that the maximum...Ch. 5 - Prob. 5.166QPCh. 5 - A gaseous hydrocarbon (containing C and H atoms)...Ch. 5 - Three flasks (a)(c) contain gases A (red) and B...Ch. 5 - Prob. 5.169QPCh. 5 - Prob. 5.170QPCh. 5 - In 2012, Felix Baumgartner jumped from a balloon...Ch. 5 - Prob. 5.172QPCh. 5 - A flask with a volume of 14.5 L contains 1.25...Ch. 5 - Prob. 5.174QPCh. 5 - Prob. 5.175QPCh. 5 - Prob. 5.176QPCh. 5 - Prob. 5.177QP
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