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Concept explainers
(a)
Interpretation:
The curve arrow should be drawn for showing the movement of electrons.
Concept introduction:
Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a
Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.
Carbocation: Carbocation is a positive charged species and vital intermediate in
(b)
Interpretation:
The curve arrow should be drawn for showing the movement of electrons.
Concept introduction:
Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.
Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.
Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.
(c)
Interpretation:
The curve arrow should be drawn for showing the movement of electrons.
Concept introduction:
Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.
Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.
Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.
(d)
Interpretation:
The curve arrow should be drawn for showing the movement of electrons.
Concept introduction:
Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.
Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.
Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.
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Chapter 5 Solutions
Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+)
- Draw the most stable resonance form for the intermediate in the following electrophilic substitution reaction. LOCH3 LOCH3 HNO3 / CH3CO₂H O₂N • You do not have to consider stereochemistry. • Include all valence lone pairs in your answer. ● In cases where there is more than one answer, just draw one.arrow_forward10. Draw the most stable resonance form for the intermediate in the following electrophilic substitution reaction.arrow_forwardUsing the curved arrow convention, write a detailed, step-by-step mechanism for the reaction of 2-methyl-2-butanol with HCl to produce 2-chloro-2-methylbutane and water. Label the rate-determining step and state the reaction type. How would doubling the concentration of HCl affect the rate of this reaction in 1A? Write the rate equation for this reaction.arrow_forward
- Draw the most stable resonance form for the intermediate in the following electrophilic substitution reaction. OH CH3 + + H3C CH₂ CH3 First stage in synthesis of the preservative BHT • You do not have consider stereochemistry. • Include all valence lone pairs in your answer. • In cases where there is more than one answer, just draw one. ▼ H3PO4 ? OH CH3 CH3 CH3 CH3arrow_forwardCH3 || CH3 H₂O H2SO4 CH3CHCH2CH2C—ОCH₂CH₂CHCH3 a. Draw the structure of the tetrahedral intermediate INITIALLY-FORMED in the reaction shown. • • • You do not have to consider stereochemistry. Do not include counter-ions, e.g., Na+, I, in your answer. In cases where there is more than one answer, just draw one. √n [ ChemDoodle Ⓡ b. Draw the structures of the organic products of the acyl transfer reaction. • You do not have to consider stereochemistry. Draw the neutral form of the products; no charges. Draw one structure per sketcher. Add additionalarrow_forwardUse the dropdown menu to indicate whether the rate of the reaction shown below will increase, decrease, or remain the same when the reaction conditions are changed to X or to Y or to Z (see below). NaN3 'N3 Br CH3CN X: Change the leaving group from Br to CI Y: Increase the concentration of haloalkane Z: Increase the concentration of NaN3 X: choose your answer.. ^ Y: choose your answer... V Z: choose your answer... choose your answer... Remain the same Nex Decrease Increasearrow_forward
- Draw the least stable resonance form for the intermediate in the following electrophilic substitution reaction.arrow_forwardWrite a mechanism for the following reaction. You MUST use curved arrows to represent electron movement. Show the three possible termination steps as part of the mechanism. CH3 CH3 Br₂, heat Brarrow_forwardDraw the most stable resonance form for the intermediate in the following electrophilic substitution reaction. OH CCI3 H2SO4 CCI3 CI- First stage in synthesis of the insecticide DDT, which is now banned in the US You do not have to consider stereochemistry. Include all valence lone pairs in your answer. • In cases where there is more than one answer, just draw one.arrow_forward
- Draw the most stable resonance form for the intermediate in the following electrophilic substitution reaction. CH3 CH3 CH3CI / AICI3 • H3C • You do not have to consider stereochemistry. Include all valence lone pairs in your answer. In cases where there is more than one answer, just draw one.arrow_forwardPlz helparrow_forwardGive one example of elimination reaction (E2) type. Show the reactants materials and the product. Draw the reaction mechanism?arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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