OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
5th Edition
ISBN: 9781285460420
Author: John W. Moore; Conrad L. Stanitski
Publisher: Cengage Learning US
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Question
Chapter 4.8, Problem 4.15CE
Interpretation Introduction
Interpretation:
The balanced equation for glucose combustion has to be determined. Whether
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Students have asked these similar questions
Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
Theoretical
mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 4 Solutions
OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
Ch. 4.1 - (a) If you eat a hot dog, it will provide 160...Ch. 4.2 - Prob. 4.1CECh. 4.2 - Prob. 4.2CECh. 4.3 - Prob. 4.3CECh. 4.3 - Prob. 4.2PSPCh. 4.4 - A piece of aluminum with a mass of 250. g is at an...Ch. 4.4 - Prob. 4.4CECh. 4.4 - Prob. 4.5CECh. 4.4 - Prob. 4.4PSPCh. 4.4 - Prob. 4.5PSP
Ch. 4.5 - Prob. 4.6PSPCh. 4.5 - Prob. 4.6ECh. 4.5 - Assume you have 1 cup of ice (237 g) at 0.0 C....Ch. 4.6 - Prob. 4.9CECh. 4.6 - Prob. 4.10CECh. 4.6 - Prob. 4.11ECh. 4.6 - The reaction enthalpy for sublimation of 1 mol...Ch. 4.6 - Prob. 4.12ECh. 4.6 - Prob. 4.8PSPCh. 4.7 - Prob. 4.13CECh. 4.7 - Prob. 4.14CECh. 4.8 - Prob. 4.9PSPCh. 4.8 - Prob. 4.15CECh. 4.8 - Prob. 4.10PSPCh. 4.8 - Prob. 4.16CECh. 4.8 - Prob. 4.17ECh. 4.9 - When iron is obtained from iron ore, an important...Ch. 4.10 - Write an appropriate thermochemical expression in...Ch. 4.10 - Prob. 4.18CECh. 4.10 - Prob. 4.13PSPCh. 4.10 - Use data from Table 4.2 to calculate the standard...Ch. 4.11 - Prob. 4.15PSPCh. 4.11 - Correlate the fuel values and caloric values...Ch. 4.11 - Prob. 4.20ECh. 4.11 - Prob. 4.21ECh. 4 - Prob. 1QRTCh. 4 - For each situation, define a system and its...Ch. 4 - What is the value of the standard formation...Ch. 4 - Prob. 4QRTCh. 4 - Prob. 5QRTCh. 4 - Name two exothermic processes and two endothermic...Ch. 4 - Prob. 7QRTCh. 4 - Prob. 8QRTCh. 4 - (a) A 2-inch piece of two-layer chocolate cake...Ch. 4 - Prob. 10QRTCh. 4 - Melting lead requires 5.50 cal/g. Calculate how...Ch. 4 - Prob. 12QRTCh. 4 - Prob. 13QRTCh. 4 - Prob. 14QRTCh. 4 - Prob. 15QRTCh. 4 - Analyze transfer of energy from one form to...Ch. 4 - Prob. 17QRTCh. 4 - Suppose that you are studying kinetic energy of...Ch. 4 - Solid ammonium chloride is added to water in a...Ch. 4 - Prob. 20QRTCh. 4 - Prob. 21QRTCh. 4 - Prob. 22QRTCh. 4 - Prob. 23QRTCh. 4 - Prob. 24QRTCh. 4 - Prob. 25QRTCh. 4 - Prob. 26QRTCh. 4 - The specific heat capacity of benzene, C6H6, is...Ch. 4 - The specific heat capacity of carbon...Ch. 4 - Prob. 29QRTCh. 4 - Prob. 30QRTCh. 4 - A piece of iron (400. g) is heated in a flame and...Ch. 4 - Prob. 32QRTCh. 4 - Prob. 33QRTCh. 4 - Prob. 34QRTCh. 4 - Prob. 35QRTCh. 4 - Prob. 36QRTCh. 4 - Prob. 37QRTCh. 4 - Prob. 38QRTCh. 4 - Prob. 39QRTCh. 4 - Calculate the quantity of heating required to...Ch. 4 - Prob. 41QRTCh. 4 - Prob. 42QRTCh. 4 - Prob. 43QRTCh. 4 - Prob. 44QRTCh. 4 - Prob. 45QRTCh. 4 - Calcium carbide, CaC2, is manufactured by reducing...Ch. 4 - Prob. 47QRTCh. 4 - Prob. 48QRTCh. 4 - Prob. 49QRTCh. 4 - Given the thermochemical expression CaO(s) + 3C(s)...Ch. 4 - Prob. 51QRTCh. 4 - Prob. 52QRTCh. 4 - Isooctane (2,2,4-trimethylpentane), one of the...Ch. 4 - Prob. 54QRTCh. 4 - Gasohol, a mixture of gasoline and ethanol,...Ch. 4 - White phosphorus, P4, ignites in air to produce...Ch. 4 - Prob. 57QRTCh. 4 - Prob. 58QRTCh. 4 - Which molecule, HF, HCl, HBr, or HI, has the...Ch. 4 - Which molecule, F2, Cl2, Br2, or I2, has the...Ch. 4 - For the reactions of molecular hydrogen with...Ch. 4 - Prob. 62QRTCh. 4 - A diamond can be considered a giant all-carbon...Ch. 4 - Prob. 64QRTCh. 4 - Prob. 65QRTCh. 4 - Prob. 66QRTCh. 4 - Prob. 67QRTCh. 4 - A 0.692-g sample of glucose, C6H12O6, is burned in...Ch. 4 - Benzoic acid, C7H6O2, occurs naturally in many...Ch. 4 - Prob. 70QRTCh. 4 - Prob. 71QRTCh. 4 - Prob. 72QRTCh. 4 - Three reactions very important to the...Ch. 4 - Prob. 74QRTCh. 4 - Prob. 75QRTCh. 4 - Prob. 76QRTCh. 4 - Prob. 77QRTCh. 4 - Prob. 78QRTCh. 4 - We burn 3.47 g lithium in excess oxygen at...Ch. 4 - Prob. 80QRTCh. 4 - Prob. 81QRTCh. 4 - Prob. 82QRTCh. 4 - The reaction enthalpy for oxidation of styrene,...Ch. 4 - Oxygen is not normally found in positive oxidation...Ch. 4 - Iron can react with oxygen to give iron(III)...Ch. 4 - The formation of aluminum oxide from its elements...Ch. 4 - Prob. 87QRTCh. 4 - If you want to convert 56.0 g ice (at 0 °C) to...Ch. 4 - Prob. 89QRTCh. 4 - Prob. 90QRTCh. 4 - Prob. 91QRTCh. 4 - Prob. 92QRTCh. 4 - Prob. 93QRTCh. 4 - Prob. 94QRTCh. 4 - Prob. 95QRTCh. 4 - Prob. 96QRTCh. 4 - Prob. 97QRTCh. 4 - Prob. 98QRTCh. 4 - Prob. 99QRTCh. 4 - Prob. 100QRTCh. 4 - Prob. 101QRTCh. 4 - Prob. 102QRTCh. 4 - Prob. 103QRTCh. 4 - Prob. 104QRTCh. 4 - Prob. 105QRTCh. 4 - Prob. 106QRTCh. 4 - The specific heat capacity of copper is 0.385 J g1...Ch. 4 - Consider this graph, which presents data for a...Ch. 4 - Prob. 109QRTCh. 4 - The sketch shows two identical beakers with...Ch. 4 - Prob. 111QRTCh. 4 - Prob. 112QRTCh. 4 - Prob. 113QRTCh. 4 - Prob. 114QRTCh. 4 - Prob. 115QRTCh. 4 - Prob. 116QRTCh. 4 - Prob. 117QRTCh. 4 - Prob. 118QRTCh. 4 - Prob. 119QRTCh. 4 - Prob. 120QRTCh. 4 - Prob. 121QRTCh. 4 - Prob. 122QRTCh. 4 - Prob. 123QRTCh. 4 - Prob. 124QRTCh. 4 - Prob. 4.ACPCh. 4 - Prob. 4.BCPCh. 4 - Prob. 4.CCPCh. 4 - Prob. 4.DCPCh. 4 - Prob. 4.ECPCh. 4 - Prob. 4.FCP
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