The relative priorities for the given set of groups has to be assigned. Concept introduction: Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other. Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers. According to Cahn-Ingold-Prelog system, The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Question

2.

Answer 1

Question

Chapter 4.7, Problem 14P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(c)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(d)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

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2.

Please solve for the following Electrochemistry that occurs

Commercial bleach contains either chlorine or oxygen as an active ingredient. A commercial oxygenated bleach is much safer to handle and less likely to ruin your clothes. It is possible to determine the amount of active ingredient in an oxygenated bleach product by performing a redox titration. The balance reaction for such a titration is: 6H+ +5H2O2 +2MnO4- à 5O2 + 2Mn2+ + 8H2O If you performed the following procedure: “First, dilute the Seventh Generation Non-Chlorine Bleach by pipetting 10 mL of bleach in a 100 mL volumetric flask and filling the flask to the mark with distilled water. Next, pipet 10 mL of the diluted bleach solution into a 250 mL Erlenmeyer flask and add 20 mL of 1.0 M H2SO4 to the flask. This solution should be titrated with 0.0100 M KMnO4 solution.” It took 18.47mL of the KMnO4 to reach the endpoint on average. What was the concentration of H2O2 in the original bleach solution in weight % assuming the density of bleach is 1g/mL?

Answer 2

Question

Chapter 4.7, Problem 14P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(c)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(d)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

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Answer 3

Question

Chapter 4.7, Problem 14P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(c)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(d)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

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Answer 4

Question

Chapter 4.7, Problem 14P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(c)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(d)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

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Answer 5

Chapter 4.7, Problem 14P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(c)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(d)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 6

Chapter 4.7, Problem 14P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 7

Chapter 4.7, Problem 14P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of groups has to be assigned.

Concept introduction:

Enantiomers are stereoisomers of compounds having one asymmetric center, in which these isomers are non-superimposable mirror images of each other.

Enantiomers are named by following Cahn-Ingold-Prelog system, in which R or S letter is used to differentiate between enantiomers.

According to Cahn-Ingold-Prelog system,

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

Answer 14

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Answer 25

Ch. 4.1 - Prob. 2P Ch. 4.1 - Prob. 3P Ch. 4.1 - Prob. 4P Ch. 4.1 - Prob. 5P Ch. 4.1 - Which of the roll owing compounds have a dipole...Ch. 4.2 - Prob. 7P Ch. 4.3 - Prob. 8P Ch. 4.4 - Prob. 10P Ch. 4.4 - Prob. 11P Ch. 4.6 - Prob. 12P

Solution Summary: The author explains that the relative priorities for the given set of groups have to be assigned. Enantiomers are non-superimposable mirror images of each other.

Chapter 4 Solutions