Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Chapter 4.4, Problem 30PP
Interpretation Introduction
To Determine:
Name and
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 4 Solutions
Basic Chemistry
Ch. 4.1 - Write the symbols for the following elements: a....Ch. 4.1 - Write the symbols for the following elements: a....Ch. 4.1 - Determine if each of the following symbols is...Ch. 4.1 - Determine if each of the following symbols is...Ch. 4.1 - Write the name for the symbol of each of the...Ch. 4.1 - Prob. 6PPCh. 4.1 - Write the names for the elements in each of the...Ch. 4.1 - Write the names for the elements in each of the...Ch. 4.2 - Prob. 9PPCh. 4.2 - Identify the group or period number described by...
Ch. 4.2 - Prob. 11PPCh. 4.2 - Prob. 12PPCh. 4.2 - Prob. 13PPCh. 4.2 - Identify each of the following elements as a...Ch. 4.2 - Using Table 4.4, identify the function of each of...Ch. 4.2 - Using Table 4.4, identify the function of each of...Ch. 4.2 - Prob. 17PPCh. 4.2 - Prob. 18PPCh. 4.3 - Prob. 19PPCh. 4.3 - Prob. 20PPCh. 4.3 - What did Rutherford determine about the structure...Ch. 4.3 - Prob. 22PPCh. 4.3 - Is each of the following statements true or false?...Ch. 4.3 - Is each of the following statements true or false?...Ch. 4.3 - Prob. 25PPCh. 4.3 - Sometimes clothes cling together when removed from...Ch. 4.4 - Would you use the atomic number, mass number, or...Ch. 4.4 - Prob. 28PPCh. 4.4 - Write the names and symbols for the elements with...Ch. 4.4 - Prob. 30PPCh. 4.4 - How many protons and electrons are there in a...Ch. 4.4 - Prob. 32PPCh. 4.4 - Prob. 33PPCh. 4.4 - Prob. 34PPCh. 4.5 - What are the number of protons, neutrons, and...Ch. 4.5 - Prob. 36PPCh. 4.5 - Write the atomic symbol for the isotope with each...Ch. 4.5 - Write the atomic symbol for the isotope with each...Ch. 4.5 - Argon has three naturally occurring isotopes, with...Ch. 4.5 - Strontium has four naturally occurring isotopes,...Ch. 4.5 - What is the difference between the mass of an...Ch. 4.5 - Prob. 42PPCh. 4.5 - Prob. 43PPCh. 4.5 - Prob. 44PPCh. 4.5 - Prob. 45PPCh. 4.5 - Zinc consists of five naturally occurring...Ch. 4.5 - Prob. 47PPCh. 4.5 - Prob. 48PPCh. 4.5 - a. What is the group number and name of the group...Ch. 4.5 - a. How many neutrons are in K-41? b. If John’s...Ch. 4 - The chapter sections to review are shown in...Ch. 4 - Prob. 52UTCCh. 4 - Prob. 53UTCCh. 4 - Prob. 54UTCCh. 4 - Prob. 55UTCCh. 4 - Prob. 56UTCCh. 4 - Prob. 57UTCCh. 4 - Prob. 58UTCCh. 4 - Prob. 59UTCCh. 4 - Prob. 60UTCCh. 4 - Prob. 61APPCh. 4 - Prob. 62APPCh. 4 - Prob. 63APPCh. 4 - Prob. 64APPCh. 4 - The following trace elements have been found to be...Ch. 4 - The following trace elements have been found to be...Ch. 4 - Indicate if each of the following statements is...Ch. 4 - Prob. 68APPCh. 4 - Prob. 69APPCh. 4 - Prob. 70APPCh. 4 - Prob. 71APPCh. 4 - Complete the following table: (4.4, 4.5Ch. 4 - Provide the following: (4.2. 4.4) a. the atomic...Ch. 4 - Prob. 74APPCh. 4 - Prob. 75APPCh. 4 - Prob. 76APPCh. 4 - Prob. 77APPCh. 4 - Prob. 78APPCh. 4 - Prob. 79APPCh. 4 - Prob. 80APPCh. 4 - Prob. 81APPCh. 4 - Prob. 82APPCh. 4 - Prob. 83CPCh. 4 - Prob. 84CPCh. 4 - Prob. 85CPCh. 4 - Prob. 86CPCh. 4 - Prob. 87CPCh. 4 - Prob. 88CPCh. 4 - Prob. 89CPCh. 4 - Prob. 90CP
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