University Physics with Modern Physics (14th Edition)
University Physics with Modern Physics (14th Edition)
14th Edition
ISBN: 9780321973610
Author: Hugh D. Young, Roger A. Freedman
Publisher: PEARSON
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Chapter 42, Problem 42.1DQ

Van der Waals bonds occur in many molecules, but hydrogen bonds occur only with materials that contain hydrogen. Why is this type of bond unique to hydrogen?

Expert Solution & Answer
Check Mark
To determine

Why hydrogen bonds occur only with materials that contain hydrogen.

Answer to Problem 42.1DQ

The hydrogen bonds occur only with materials that contain hydrogen because only hydrogen has a singly ionized state with no remaining electron cloud.

Explanation of Solution

Explanation:

Hydrogen bond is an attraction between hydrogen bound to a more electronegative atom and another adjacent atom having a lone pair of electrons. It is stronger than van der Waals bond while weaker than ionic and covalent bonds.

In hydrogen bond, a proton gets between two atoms, polarizing them and attracting them by means of the induced dipoles. Hydrogen bond is unique to hydrogen containing compounds because only hydrogen has a singly ionized state with no remaining electron cloud. The hydrogen ion is a bare proton, much smaller than any other singly ionized atom.

Conclusion:

Thus the hydrogen bonds occur only with materials that contain hydrogen because only hydrogen has a singly ionized state with no remaining electron cloud.

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Chapter 42 Solutions

University Physics with Modern Physics (14th Edition)

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