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Concept explainers
(a)
Interpretation:
Given compound has to be named.
Concept Introduction:
Nomenclature of bicyclic compounds:
The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,
Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.
Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.
Arrange the substituents alphabetically.
In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.
(b)
Interpretation:
Given compound has to be named.
Concept Introduction:
Nomenclature of bicyclic compounds:
The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,
Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] (each number represent number of carbon atoms) and placed in the middle of the parent.
Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.
Arrange the substituents alphabetically.
In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.
(c)
Interpretation:
Given compound has to be named.
Concept Introduction:
Nomenclature of bicyclic compounds:
The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,
Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.
Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.
Arrange the substituents alphabetically.
In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.
(d)
Interpretation:
Given compound has to be named.
Concept Introduction:
Nomenclature of bicyclic compounds:
The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,
Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.
Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.
Arrange the substituents alphabetically.
In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.
(e)
Interpretation:
Given compound has to be named.
Concept Introduction:
Nomenclature of bicyclic compounds:
The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,
Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.
Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.
Arrange the substituents alphabetically.
In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.
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Chapter 4 Solutions
Organic Chemistry
- Don't used hand raitingarrow_forwardCHEM2323 Problem 2-24 Tt O e: ל Predict the product(s) of the following acid/base reactions. Draw curved arrows to show the formation and breaking of bonds. If the bonds needed are not drawn out, you should redraw them. + BF3 (a) (b) HI + (c) OH -BF Problem 2-25 Use curved arrows and a proton (H+) to draw the protonated form of the following Lewis bases. Before starting, add all missing lone pairs. (a) (b) :0: (c) N 1 CHEM2323 PS CH02 Name:arrow_forwardCHEM2323 Problem 2-26 Tt O PS CH02 Name: Use the curved-arrow formalism to show how the electrons flow in the resonance form on the left to give the one on the right. (Draw all lone pairs first) (a) NH2 NH2 + (b) Problem 2-27 Double bonds can also act like Lewis bases, sharing their electrons with Lewis acids. Use curved arrows to show how each of the following double bonds will react with H-Cl and draw the resulting carbocation. (a) H2C=CH2 (b) (c) Problem 2-28 Identify the most electronegative element in each of the following molecules: (a) CH2FCI F Problem 2-29 (b) FCH2CH2CH2Br (c) HOCH2CH2NH2 (d) CH3OCH2Li F 0 0 Use the electronegativity table in Figure 2.3 to predict which bond in the following pairs is more polar and indicate the direction of bond polarity for each compound. (a) H3C-Cl or Cl-CI (b) H3C-H or H-CI (c) HO-CH3 or (CH3)3Si-CH3 (d) H3C-Li or Li-OHarrow_forward
- Reagan is doing an atomic absorption experiment that requires a set of zinc standards in the 0.4-1.6 ppm range. A 1000 ppm Zn solution was prepared by dissolving the necessary amount of solid Zn(NO3)2 in water. The standards can be prepared by diluting the 1000 ppm Zn solution. Table 1 shows one possible set of serial dilutions (stepwise dilution of a solution) that Reagan could perform to make the necessary standards. Solution A was prepared by diluting 5.00 ml of the 1000 ppm Zn standard to 50.00 ml. Solutions C-E are called "calibration standards" because they will be used to calibrate the atomic absorption spectrometer. a. Compare the solution concentrations expressed as ppm Zn and ppm Zn(NO3)2. Compare the concentrations expressed as M Zn and M Zn(NO3)2 - Which units allow easy conversion between chemical species (e.g. Zn and Zn(NO3)2)? - Which units express concentrations in numbers with easily expressed magnitudes? - Suppose you have an analyte for which you don't know the molar…arrow_forwardNonearrow_forwardHow will you prepare the following buffers? 2.5 L of 1.5M buffer, pH = 10.5 from NH4Cl and NH3arrow_forward
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