ORGANIC CHEMISTRY-PRINT MULTI TERM
ORGANIC CHEMISTRY-PRINT MULTI TERM
4th Edition
ISBN: 9781119832614
Author: Klein
Publisher: WILEY
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Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name for the following compound should be determined.

  ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 4.2, Problem 10ATS , additional homework tip  1

Concept Introduction:

Compounds consisting of carbon and hydrogen are known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2 .

Rules of naming alkanes are:

  1. First, choose the longest continuous chain of carbon atoms known as the parent chain and determines the base name of the alkane.
  2. The numbering of the parent chain should be done in a way that the substituents get the lowest number.
  3. The appropriate name should be given to every alkyl group and denote its position on the parent chain with the number.
  4. The alkyl groups are written in alphabetical order.

(b)

Interpretation Introduction

Interpretation:

The systematic name for the following compound should be determined.

  ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 4.2, Problem 10ATS , additional homework tip  2

Concept Introduction:

Compounds consisting of carbon and hydrogen are known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2 .

Rules of naming alkanes are:

  1. First, choose the longest continuous chain of carbon atoms known as the parent chain and determines the base name of the alkane.
  2. The numbering of the parent chain should be done in a way that the substituents get the lowest number.
  3. The appropriate name should be given to every alkyl group and denote its position on the parent chain with the number.
  4. The alkyl groups are written in alphabetical order.

(c)

Interpretation Introduction

Interpretation:

The systematic name for the following compound should be determined.

  ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 4.2, Problem 10ATS , additional homework tip  3

Concept Introduction:

Compounds consisting of carbon and hydrogen are known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2 .

Rules of naming alkanes are:

  1. First, choose the longest continuous chain of carbon atoms known as the parent chain and determines the base name of the alkane.
  2. The numbering of the parent chain should be done in a way that the substituents get the lowest number.
  3. The appropriate name should be given to every alkyl group and denote its position on the parent chain with the number.
  4. The alkyl groups are written in alphabetical order.

(d)

Interpretation Introduction

Interpretation:

The systematic name for the following compound should be determined.

  ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 4.2, Problem 10ATS , additional homework tip  4

Concept Introduction:

Compounds consisting of carbon and hydrogen are known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2 .

The compounds in which a series of atoms are connected to form a ring is known as cyclic compound whereas the compounds which are open chain compounds and their atoms don't form a ring is known as acyclic compounds. The general molecular formula of a cyclic alkane is CnH2n .

Rules of naming cycloalkanes are:

  1. First, determine the cycloalkane present in the structure which is considered as a parent chain (maximum number of carbon atoms). If the acyclic alkane chain has more carbon atoms, then the alkyl chain is considered a parent chain.
  2. For a cyclic system, the number of carbon atoms must be identified as present in different paths connected with two bridgeheads.
  3. The numbering of the parent chain should be done in a way that the substituents get the lowest number.
  4. The appropriate name should be given to every alkyl group or cycloalkyl group and denote its position on the parent chain with the number
  5. The alkyl groups or cycloalkyl groups are written in alphabetical order.

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Students have asked these similar questions
a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)? b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here?  b. What is the purpose of the Na2SO4?  c. What equipment would you use to “concentrate [a solution] under reduced pressure”?
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