ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
4th Edition
ISBN: 9781119761105
Author: Klein
Publisher: WILEY
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Question
Chapter 4.14, Problem 33CC
Interpretation Introduction
Interpretation:
TheHaworth projectionsof cis and trans-1-3-dimethylcyclohexane are drawn and its stability should be comparatively explained.
Concept Introduction:
Haworth projection:
- The representation of cyclic chemical compounds by normal ring structure and the substituents can either pointing up or down on this ring is called Haworth projection.
Conformational isomers:
- The two or more compounds have same molecular formula and different structural formulas from the result of C-C single bond rotations are called conformational isomers.
- The atom or group is occupy at similar to a vertical axis passing through the chair conformationof Cyclohexane ring is called axial position.
- The atom or group is occupy at similar to horizontal axis passing through the chair conformationof ring is called equatorial position.
- The substituents are occupy in equatorial position is more stable than axial because of the 1,3-diaxial interactions are less in equatorial position.
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Chapter 4 Solutions
ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
Ch. 4.2 - Prob. 1LTSCh. 4.2 - Prob. 1PTSCh. 4.2 - Prob. 2PTSCh. 4.2 - Prob. 3ATSCh. 4.2 - Prob. 2LTSCh. 4.2 - Prob. 4PTSCh. 4.2 - Prob. 5ATSCh. 4.2 - Prob. 3LTSCh. 4.2 - Prob. 6PTSCh. 4.2 - Prob. 7ATS
Ch. 4.2 - Prob. 4LTSCh. 4.2 - Prob. 8PTSCh. 4.2 - Prob. 9PTSCh. 4.2 - Prob. 10ATSCh. 4.2 - Prob. 5LTSCh. 4.3 - Prob. 6LTSCh. 4.3 - Prob. 14PTSCh. 4.6 - Prob. 7LTSCh. 4.6 - Prob. 16PTSCh. 4.8 - Prob. 8LTSCh. 4.12 - Prob. 11LTSCh. 4.12 - Prob. 25PTSCh. 4.14 - Prob. 33CCCh. 4.14 - Prob. 34CCCh. 4.14 - Prob. 35CCCh. 4 - Prob. 36PPCh. 4 - Prob. 51PPCh. 4 - Prob. 52PPCh. 4 - Prob. 53PPCh. 4 - Prob. 54PPCh. 4 - Prob. 55PPCh. 4 - Prob. 56PPCh. 4 - Prob. 57PPCh. 4 - Prob. 58PPCh. 4 - Prob. 59PPCh. 4 - Prob. 69ACPCh. 4 - Prob. 73IPCh. 4 - Prob. 76IP
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