EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
3rd Edition
ISBN: 9780133858501
Author: Bruice
Publisher: PEARSON CO
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Chapter 4.12, Problem 41P

Draw all the stereoisomers for each of the following:

  1. a. 1-chloro-3-methylpentane
  2. b. 1-bromo-2-methylpropane
  3. c. 3-chloro-3-methylpentane
  4. d. 3,4-dichlorohexane
  5. e. 1,2-dichlorocyclobutane
  6. f. 1,3-dichlorocyclohexane
  7. g. 1,4-dichlorocyclohexane
  8. h. 1-bromo-2-chlorocyclobutane
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What is the final volume after you reach the final temperature? I put 1.73 but the answer is wrong not sure why  The initial volume of gas is   1.60 LL  , the initial temperature of the gas is   23.0 °C°C  , and the system is in equilibrium with an external pressure of 1.2 bar (given by the sum of a 1 bar atmospheric pressure and a 0.2 bar pressure due to a brick that rests on top of the piston). Then, as you did in Exercise 1, you heat the gas slowly until the temperature reaches  48.2 °C
Q4: Identify the type of Carbon ( methyl, primary, secondary, etc. ) indicated by this arrow.
Q3: Curved Arrows, Lewis Acids & Bases, Nucleophiles and Electrophiles Considering the following reactions: a) Predict the products to complete the reactions. b) Use curved electron-pushing arrows to show the mechanism for the reaction in the forward direction. Redraw some of the compounds to explicitly illustrate all bonds that are broken and all bonds that are formed. c) Label Lewis acids and bases, nucleophiles and electrophiles in the reactions. A. S + AICI 3 B. + H₂O

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How to Design a Total Synthesis; Author: Chemistry Unleashed;https://www.youtube.com/watch?v=9jRfAJJO7mM;License: Standard YouTube License, CC-BY