Pushing Electrons
4th Edition
ISBN: 9781133951889
Author: Weeks, Daniel P.
Publisher: Cengage Learning
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A.
What is the correct structure for a-D-glucopyranose?
CH₂OH
a
HO
HO-
OH
b
HO
HO-
OH
HOH₂C
OH
OH
OH
CH₂OH
HO
C.
HO
HO-
OH
OH
CH₂OH
OH
OH
B. Draw structures for the products you would expect to obtain from reaction of B-D-galactopyranose
with each of the following reagents. Be sure to include all relevant stereochemistry. [FOUR only]
A. CH, Ag₂O
B. warm dilute HNO3
C. (CH3CO)20, pryridine
D. NaBH in H₂O
E. CH₂OH, HCI
F. Br₂, H₂O
HO
CH₂OH
HO-
OH
OH
B-D-galactopyranose
Give the major organic product(s) for each of the following reactions or reaction sequences.
CH₂CN
5% NaOEt, EIOH
سجد سی . بلی
H
1. NaOCH, CH,OH
CH3
OCH3
2 H₂O*
Draw the structures for each of the intermediates in the boxes provided for the synthesis below.
004
HNO
F HO
CHCO) D
Dydre
R.SO.
1.1 NO
fe
HO
H.SO.
2. CC1
NOH
HO
MCL
HNO,
H.50.
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- .. Name each of the following compounds by IUPAC rules. [three Only] A. 0 B. C. Cl NH₂ OCH N CH3 NHCH2CH3 D. CH O₁₂N NH₂arrow_forwardDraw the structure of the aldol self condensation product for each of the following compounds if a compound does not under go aldol self condensation explain whyarrow_forwardIndicate how the addition of a nucleophile :NuH2 to a ketone R-CO-R occurs.arrow_forward
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- Draw a Haworth projection of a common cyclic form of this monosaccharide CH₂OH HO H HO H H OH CH₂OHarrow_forwardCan you explain how I get these here and show the steps plz?arrow_forwardGive the IUPAC name for this compound Hydrocarbon Condensed Formulas Hint C2H5 CH2CH3 expand that in all the formula Part A: (CH3)2CHCH(C2H5)CH2CH2CH3 Give the IUPAC name for this compound. Part B: CH2=C(C2H5)CH2CH2CH3 Give the IUPAC name for this compound. Part C: (CH3)2C=CHC(C2H5)=CH2 Give the IUPAC name for this compound. Part D: CH3C=CCH(C2H5)2 Give the IUPAC name for this compound. Part E: (CH3)3CC=CCH2CH=C(CH3)2arrow_forward
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