Pushing Electrons
4th Edition
ISBN: 9781133951889
Author: Weeks, Daniel P.
Publisher: Cengage Learning
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We know that trivalent cations (Cr3+, Mn3+, V3+) with a large difference between octahedral and tetrahedral EECC, form exclusively normal spinels. Bivalent cations (Ni2+ and Cu2+) with high EECC, form inverse spinels. Is this statement correct?
(b) Draw the product A that would be formed through the indicated sequence of steps from the given starting material.
MeO
(1) Br₂, hv
(2) NaOEt,
EtOH, A
(3) BH3:THF
(4) H₂O2, HO-
B
H₂C.
CH₂
OH
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