Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
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Textbook Question
Chapter 4, Problem 8RQ
What is an acid-base reaction? Strong bases are soluble ionic compounds that contain the hydroxide ion. List the strong bases. When a strong base reacts with an acid, what is always produced? Explain the terms titration, stoichiometric point, neutralization, and standardization.
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Can you please explain why structure 3 is the correct answer? Please give a detailed explanation.
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
Chapter 4 Solutions
Chemistry
Ch. 4 - The (aq) designation listed after a solute...Ch. 4 - Characterize strong electrolytes versus weak...Ch. 4 - Distinguish between the terms slightly soluble and...Ch. 4 - Molarity is a conversion factor relating moles of...Ch. 4 - What is a dilution? What stays constant in a...Ch. 4 - When the following beakers are mixed, draw a...Ch. 4 - Differentiate between the formula equation, the...Ch. 4 - What is an acid-base reaction? Strong bases are...Ch. 4 - Define the terms oxidation, reduction, oxidizing...Ch. 4 - Prob. 10RQ
Ch. 4 - Assume you have a highly magnified view of a...Ch. 4 - You have a solution of table salt in water. What...Ch. 4 - You have a sugar solution (solution A) with...Ch. 4 - You add an aqueous solution of lead nitrate to an...Ch. 4 - Order the following molecules from lowest to...Ch. 4 - Why is it that when something gains electrons, it...Ch. 4 - Consider separate aqueous solutions of HCl and...Ch. 4 - Prob. 8ALQCh. 4 - Prob. 9ALQCh. 4 - The exposed electrodes of a light bulb are placed...Ch. 4 - Differentiate between what happens when the...Ch. 4 - A typical solution used in general chemistry...Ch. 4 - Prob. 15QCh. 4 - A student wants to prepare 1.00 L of a 1.00-M...Ch. 4 - List the formulas of three soluble bromide salts...Ch. 4 - When 1.0 mole of solid lead nitrate is added to...Ch. 4 - What is an acid and what is a base? An acid-base...Ch. 4 - A student had 1.00 L of a 1.00-M acid solution....Ch. 4 - Differentiate between the following terms. a....Ch. 4 - How does one balance redox reactions by the...Ch. 4 - Prob. 23ECh. 4 - Match each name below with the following...Ch. 4 - Calcium chloride is a strong electrolyte and is...Ch. 4 - Commercial cold packs and hot packs are available...Ch. 4 - Calculate the molarity of each of these solutions....Ch. 4 - A solution of ethanol (C2H5OH) in water is...Ch. 4 - Calculate the concentration of all ions present in...Ch. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - Prob. 33ECh. 4 - If 10. g of AgNO3 is available, what volume of...Ch. 4 - A solution is prepared by dissolving 10.8 g...Ch. 4 - A solution was prepared by mixing 50.00 mL of...Ch. 4 - Calculate the sodium ion concentration when 70.0...Ch. 4 - Suppose 50.0 mL of 0.250 M CoCl2 solution is added...Ch. 4 - Prob. 41ECh. 4 - A stock solution containing Mn2+ ions was prepaned...Ch. 4 - On the basis of the general solubility rules given...Ch. 4 - On the basis of the general solubility rules given...Ch. 4 - When the following solutions are mixed together,...Ch. 4 - When the following solutions are mixed together,...Ch. 4 - For the reactions in Exercise 47, write the...Ch. 4 - For the reactions in Exercise 48, write the...Ch. 4 - Write the balanced formula and net ionic equation...Ch. 4 - Give an example how each of the following...Ch. 4 - Write net ionic equations for the reaction, if...Ch. 4 - Write net ionic equations for the reaction, if...Ch. 4 - Separate samples of a solution of an unknown...Ch. 4 - A sample may contain any or all of the following...Ch. 4 - What mass of Na2CrO4 is required to precipitate...Ch. 4 - What volume of 0.100 M Na3PO4 is required to...Ch. 4 - What mass of iron(III) hydroxide precipitate can...Ch. 4 - What mass of silver chloride can be prepared by...Ch. 4 - A 100.0-mL aliquot of 0.200 M aqueous potassium...Ch. 4 - A 1.42-g sample of a pure compound, with formula...Ch. 4 - You are given a 1.50-g mixture of sodium nitrate...Ch. 4 - Write the balanced formula, complete ionic, and...Ch. 4 - Write the balanced formula, complete ionic, and...Ch. 4 - Write the balanced formula equation for the...Ch. 4 - Prob. 68ECh. 4 - What volume of each of the following acids will...Ch. 4 - Prob. 70ECh. 4 - Hydrochloric acid (75.0 mL of 0.250 M) is added to...Ch. 4 - A student mixes four reagents together, thinking...Ch. 4 - A 25.00-mL sample of hydrochloric acid solution...Ch. 4 - A 10.00-mL sample of vinegar, an aqueous solution...Ch. 4 - What volume of 0.0200 M calcium hydroxide is...Ch. 4 - A 30.0-mL sample of an unknown strong base is...Ch. 4 - A student titrates an unknown amount of potassium...Ch. 4 - The concentration of a certain sodium hydroxide...Ch. 4 - Assign oxidation states for all atoms in each of...Ch. 4 - Assign the oxidation state for nitrogen in each of...Ch. 4 - Assign oxidatioo numbers to all the atoms in each...Ch. 4 - Specify which of the following are...Ch. 4 - Specify which of the following equations represent...Ch. 4 - Consider the reaction between sodium metal and...Ch. 4 - Consider the reaction between oxygen (O2) gas and...Ch. 4 - Balance each of the following oxidationreduction...Ch. 4 - Balance each of the following oxidationreduction...Ch. 4 - You wish to prepare 1 L of a 0.02-M potassium...Ch. 4 - The figures below are molecular-level...Ch. 4 - Prob. 91AECh. 4 - Prob. 92AECh. 4 - Using the general solubility rules given in Table...Ch. 4 - Consider a 1.50-g mixture of magnesium nitrate and...Ch. 4 - A 1.00-g sample of an alkaline earth metal...Ch. 4 - A mixture contains only NaCl and Al2(SO4)3. A...Ch. 4 - A mixture contains only NaCl and Fe(NO3)3. A...Ch. 4 - A student added 50.0 mL of an NaOH solution to...Ch. 4 - Some of the substances commonly used in stomach...Ch. 4 - Acetylsalicylic acid is the active ingredient in...Ch. 4 - When hydrochloric acid reacts with magnesium...Ch. 4 - A 2.20-g sample of an unknown acid (empirical...Ch. 4 - Carminic acid, a naturally occurring red pigment...Ch. 4 - Chlorisondamine chloride (C14H20Cl6N2) is a drug...Ch. 4 - Saccharin (C7H5NO3S) is sometimes dispensed in...Ch. 4 - Douglasite is a mineral with the formula 2KC1...Ch. 4 - Many oxidationreduction reactions can be balanced...Ch. 4 - The blood alcohol (C2H5OH) level can be determined...Ch. 4 - Calculate the concentration of all ions present...Ch. 4 - A solution is prepared by dissolving 0.6706 g...Ch. 4 - For the following chemical reactions, determine...Ch. 4 - What volume of 0.100 M NaOH is required to...Ch. 4 - Prob. 114CWPCh. 4 - A 450.0-mL sample of a 0.257-M solution of silver...Ch. 4 - The zinc in a 1.343-g sample of a foot powder was...Ch. 4 - A 50.00-mL sample of aqueous Ca(OH)2 requires...Ch. 4 - When organic compounds containing sulfur are...Ch. 4 - Assign the oxidation state for the element Listed...Ch. 4 - A 10.00-g sample consisting of a mixture of sodium...Ch. 4 - The units of parts per million (ppm) and parts per...Ch. 4 - In the spectroscopic analysis of many substances,...Ch. 4 - In most of its ionic compounds, cobalt is either...Ch. 4 - Polychlorinated biphenyls (PCBs) have been used...Ch. 4 - Consider the reaction of 19.0 g of zinc with...Ch. 4 - A mixture contains only sodium chloride and...Ch. 4 - Prob. 127CPCh. 4 - Zinc and magnesium metal each react with...Ch. 4 - You made 100.0 mL of a lead(II) nitrate solution...Ch. 4 - Consider reacting copper(II) sulfate with iron....Ch. 4 - Consider an experiment in which two burets, Y and...Ch. 4 - Complete and balance each acid-base reaction. a....Ch. 4 - What volume of 0.0521 M Ba(OH)2 is required to...Ch. 4 - A 10.00-mL sample of sulfuric acid from an...Ch. 4 - A 0.500-L sample of H2SO4 solution was analyzed by...Ch. 4 - A 6.50-g sample of a diprotic acid requires 137.5...Ch. 4 - Citric acid, which can be obtained from lemon...Ch. 4 - Prob. 138CPCh. 4 - It took 25.06 0.05 mL of a sodium hydroxide...Ch. 4 - Prob. 140IPCh. 4 - In a 1-L beaker, 203 mL of 0.307 M ammonium...Ch. 4 - Prob. 142IPCh. 4 - The unknown acid H2X can be neutralized completely...Ch. 4 - Three students were asked to find the identity of...Ch. 4 - You have two 500.0-mL aqueous solutions. Solution...
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