ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
2nd Edition
ISBN: 9781118872925
Author: Klein
Publisher: JOHN WILEY+SONS INC.CUSTOM
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Question
Chapter 4, Problem 63PP
Interpretation Introduction
Interpretation:
Possible constitutional isomers have to be determined for the given propene molecule and needed to be given the systematic name for the isomer.
Concept introduction:
- Constitutional isomers are isomers, which are having the same molecular formula and different bond connectivity between the atoms.
IUPAC nomenclature : systematic has given for the organic compound by following certain rules, which are assigned by IUPAC (International Union and Pure Applied Chemistry).
- Word root: word root of the name indicates the parent carbon chain (longest carbon chain) present in the molecule.
- Prefix: prefix part in IUPAC name indicates the substituents present on the parent carbon chain.
- Suffix: suffix indicates that any
function group present in the molecule.
To draw: the constitutional isomer for the molecule propene.
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EXERCISE B
pH, pOH, pка, AND PKD CALCULATIONS
1. Complete the following table.
Solution
[H+]
[OH-]
PH
РОН
Nature of Solution
A
2 x 10-8 M
B
1 x 10-7 M
C
D
12.3
6.8
2. The following table contains the names, formulas, ka or pka for some common acids. Fill
in the blanks in the table. (17 Points)
Acid Name
Formula
Dissociation reaction
Ka
pka
Phosphoric acid
H₂PO₁
H3PO4
H++ H₂PO
7.08 x 10-3
Dihydrogen
H₂PO
H₂PO
H+ HPO
6.31 x 10-6
phosphate
Hydrogen
HPO₁
12.4
phosphate
Carbonic acid
H2CO3
Hydrogen
HCO
6.35
10.3
carbonate or
bicarbonate
Acetic acid
CH,COOH
4.76
Lactic acid
CH₂CHOH-
COOH
1.38 x 10
Ammonium
NH
5.63 x 10-10
Phenol
CH₂OH
1 x 10-10
Protonated form
CH3NH3*
3.16 x 10-11
of methylamine
Indicate whether it is true that Co(III) complexes are very stable.
MnO2 acts as an oxidant in the chlorine synthesis reaction.
Chapter 4 Solutions
ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
Ch. 4.2 - Prob. 1LTSCh. 4.2 - Prob. 1PTSCh. 4.2 - Prob. 2ATSCh. 4.2 - Prob. 3ATSCh. 4.2 - Prob. 4ATSCh. 4.2 - Prob. 2LTSCh. 4.2 - Prob. 5PTSCh. 4.2 - Prob. 6ATSCh. 4.2 - Prob. 3LTSCh. 4.2 - Prob. 7PTS
Ch. 4.2 - Prob. 8ATSCh. 4.2 - Prob. 9ATSCh. 4.2 - Prob. 4LTSCh. 4.2 - Prob. 10PTSCh. 4.2 - Prob. 11ATSCh. 4.2 - Prob. 5LTSCh. 4.2 - Prob. 12PTSCh. 4.2 - Prob. 13ATSCh. 4.3 - Prob. 6LTSCh. 4.3 - Prob. 14PTSCh. 4.3 - Prob. 15ATSCh. 4.6 - Prob. 7LTSCh. 4.6 - Prob. 16PTSCh. 4.6 - Prob. 17ATSCh. 4.6 - Prob. 18ATSCh. 4.7 - Prob. 19CCCh. 4.8 - Prob. 8LTSCh. 4.8 - Prob. 20PTSCh. 4.8 - Prob. 21ATSCh. 4.11 - Prob. 9LTSCh. 4.11 - Prob. 22PTSCh. 4.11 - Prob. 23ATSCh. 4.11 - Prob. 10LTSCh. 4.11 - Prob. 24PTSCh. 4.11 - Prob. 25PTSCh. 4.11 - Prob. 26PTSCh. 4.11 - Prob. 27ATSCh. 4.12 - Prob. 11LTSCh. 4.12 - Prob. 28PTSCh. 4.12 - Prob. 29ATSCh. 4.12 - Prob. 30CCCh. 4.12 - Prob. 12LTSCh. 4.12 - Prob. 31PTSCh. 4.12 - Prob. 32ATSCh. 4.12 - Prob. 13LTSCh. 4.12 - Prob. 33PTSCh. 4.12 - Prob. 34ATSCh. 4.12 - Prob. 35ATSCh. 4.14 - Prob. 36CCCh. 4.14 - Prob. 37CCCh. 4.14 - Prob. 38CCCh. 4 - Prob. 39PPCh. 4 - Prob. 40PPCh. 4 - Prob. 41PPCh. 4 - Prob. 42PPCh. 4 - Prob. 43PPCh. 4 - Prob. 44PPCh. 4 - Prob. 45PPCh. 4 - Prob. 46PPCh. 4 - Prob. 47PPCh. 4 - Prob. 48PPCh. 4 - Prob. 49PPCh. 4 - Prob. 50PPCh. 4 - Prob. 51PPCh. 4 - Prob. 52PPCh. 4 - Prob. 53PPCh. 4 - Prob. 54PPCh. 4 - Prob. 55PPCh. 4 - Prob. 56PPCh. 4 - Prob. 57PPCh. 4 - Prob. 58PPCh. 4 - Prob. 59PPCh. 4 - Prob. 60PPCh. 4 - Prob. 61PPCh. 4 - Prob. 62PPCh. 4 - Prob. 63PPCh. 4 - Prob. 64IPCh. 4 - Prob. 65IPCh. 4 - Prob. 67IPCh. 4 - Prob. 68IPCh. 4 - Prob. 69IP
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