Principles of Chemistry: A Molecular Approach (3rd Edition)
3rd Edition
ISBN: 9780321971944
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 4, Problem 62E
Interpretation Introduction
Interpretation:
The complete and balanced form of given gas-evolution reaction equation is to be stated.
Concept introduction: According to the law of conservation of mass, the mass of the reactants involved in a
Gas-evolution reactions are the reaction in which one of the product formed is gas. It can be
To determine: The complete and balanced form of given gas-evolution reaction equation.
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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed
a chemical structure shown below:
% Transmittance
4000
3500
3000
2500 2000
Wavenumber (cm-1)
1500
1000
(a) Explain why her proposed structure is inconsistent with the IR spectrum obtained
(b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure
and explain why it is more compatible with the obtained spectrum.
(C) what is the possible source for the fairly intense signal at
1621cm1
AE>AE₁ (Y/N)
AE=AE₁ (Y/N)
AE
Treatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and
gives compound A.
?
NH2
Br
Br
Propose a structural formula for compound A.
You do not have to explicitly draw H atoms.
You do not have to consider stereochemistry.
In cases where there is more than one answer, just draw one.
R3N
C14H19NO2
+ 2 R3NH*Br
A
Chapter 4 Solutions
Principles of Chemistry: A Molecular Approach (3rd Edition)
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2PCh. 4 - For Practice 4.3 Ammonia can also be synthesized...Ch. 4 - Prob. 4.4PCh. 4 - Prob. 4.5PCh. 4 - Prob. 4.5MPCh. 4 - Prob. 4.6PCh. 4 - Prob. 4.6MPCh. 4 - Prob. 4.7PCh. 4 - Prob. 4.7MP
Ch. 4 - Prob. 4.8PCh. 4 - Prob. 4.8MPCh. 4 - Prob. 4.9PCh. 4 - Prob. 4.10PCh. 4 - Prob. 4.11PCh. 4 - Prob. 4.12PCh. 4 - Prob. 4.12MPCh. 4 - Prob. 4.13PCh. 4 - Prob. 4.14PCh. 4 - Prob. 4.15PCh. 4 - For More Practice 4.15 Write a net ionic equation...Ch. 4 - For Practice 4.16 Assign an oxidation state to...Ch. 4 - Prob. 4.17PCh. 4 - Prob. 4.17MPCh. 4 - Prob. 4.18PCh. 4 - Prob. 4.19PCh. 4 - Prob. 1SAQCh. 4 - Q2. Sodium and chlorine react to form sodium...Ch. 4 - Prob. 3SAQCh. 4 - Prob. 4SAQCh. 4 - Prob. 5SAQCh. 4 - Prob. 6SAQCh. 4 - Prob. 7SAQCh. 4 - Potassium iodide reacts with lead(ll) nitrate in...Ch. 4 - Prob. 9SAQCh. 4 - Prob. 10SAQCh. 4 - Prob. 11SAQCh. 4 - Prob. 12SAQCh. 4 - Prob. 13SAQCh. 4 - Prob. 14SAQCh. 4 - Prob. 15SAQCh. 4 - Prob. 1ECh. 4 - Prob. 2ECh. 4 - Prob. 3ECh. 4 - Prob. 4ECh. 4 - Prob. 5ECh. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - Prob. 8ECh. 4 - Prob. 9ECh. 4 - Prob. 10ECh. 4 - Prob. 11ECh. 4 - For each precipitation reaction, calculate how...Ch. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - Prob. 15ECh. 4 - Prob. 16ECh. 4 - Prob. 17ECh. 4 - Prob. 18ECh. 4 - Prob. 19ECh. 4 - Prob. 20ECh. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - Prob. 27ECh. 4 - Prob. 28ECh. 4 - Prob. 29ECh. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - Prob. 33ECh. 4 - Prob. 34ECh. 4 - Prob. 35ECh. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - Prob. 38ECh. 4 - Prob. 39ECh. 4 - Prob. 40ECh. 4 - Prob. 41ECh. 4 - A 55.0 mL sample of a 0.102 M potassium sulfate...Ch. 4 - Prob. 43ECh. 4 - Prob. 44ECh. 4 - Determine whether each compound is soluble or...Ch. 4 - Prob. 46ECh. 4 - 47. Complete and balance each equation. If no...Ch. 4 - Complete and balance each equation. If no reactio...Ch. 4 - Prob. 49ECh. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Prob. 53ECh. 4 - Prob. 54ECh. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - Complete and balance each gas-evolution reaction...Ch. 4 - 62. Complete and balance each gas-evolution...Ch. 4 - Prob. 63ECh. 4 - Prob. 64ECh. 4 - Prob. 65ECh. 4 - What is the oxidation state of CI in each ion? a....Ch. 4 - Indicate which reactions are redox reactions. For...Ch. 4 - Prob. 68ECh. 4 - Prob. 69ECh. 4 - Prob. 70ECh. 4 - Prob. 71ECh. 4 - Prob. 72ECh. 4 - Prob. 73ECh. 4 - Prob. 74ECh. 4 - Prob. 75ECh. 4 - Prob. 76ECh. 4 - Prob. 77ECh. 4 - Prob. 78ECh. 4 - Prob. 79ECh. 4 - Prob. 80ECh. 4 - Predict the products of each reaction and write...Ch. 4 - Prob. 82ECh. 4 - Hard water often contains dissloved Ca2+ and Mg2+...Ch. 4 - An acid solution is 0.100 M in HCl and 0.200 M in...Ch. 4 - Prob. 85ECh. 4 - A solution contains Cr3+ ion and Mg2+ ion. The...Ch. 4 - Prob. 87ECh. 4 - Prob. 88ECh. 4 - Prob. 89ECh. 4 - 90. A solution is prepared by mixing 0.10 L of...Ch. 4 - Prob. 91ECh. 4 - Prob. 92ECh. 4 - Prob. 93ECh. 4 - An ilmenite-sand mixture contains 22.8% ilmenite...Ch. 4 - Prob. 95ECh. 4 - Prob. 96ECh. 4 - Lead poisoning is a serious condition resulting...Ch. 4 - Prob. 98ECh. 4 - Metallic aluminum reacts with MnO2 at elevated...Ch. 4 - Prob. 100ECh. 4 - Prob. 101ECh. 4 - Consider the reaction....Ch. 4 - Prob. 103ECh. 4 - Prob. 104ECh. 4 - Consider the generic ionic compounds with the...
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