Glycerol (C 3 H 8 O 3 ) is commonly used as an additive to moisturizers. The amount of glycerol added can be determined by titration with permanganate in basic solution. 14MnO 4 − ( a q ) + C 3 H 8 O 3 ( a q ) + 2 0 OH − ( a q ) → 14MnO 4 2 − ( a q ) + 3CO 3 2 − ( a q ) + 14H 2 O How many milliliters of 6.15 M KMnO 4 are required to completely react with 7.25 mL of an aqueous solution of glycerol ( d = 1.144 g / mL ) that is 51.6% by mass?
Glycerol (C 3 H 8 O 3 ) is commonly used as an additive to moisturizers. The amount of glycerol added can be determined by titration with permanganate in basic solution. 14MnO 4 − ( a q ) + C 3 H 8 O 3 ( a q ) + 2 0 OH − ( a q ) → 14MnO 4 2 − ( a q ) + 3CO 3 2 − ( a q ) + 14H 2 O How many milliliters of 6.15 M KMnO 4 are required to completely react with 7.25 mL of an aqueous solution of glycerol ( d = 1.144 g / mL ) that is 51.6% by mass?
Glycerol (C3H8O3) is commonly used as an additive to moisturizers. The amount of glycerol added can be determined by titration with permanganate in basic solution.
14MnO
4
−
(
a
q
)
+
C
3
H
8
O
3
(
a
q
)
+
2
0
OH
−
(
a
q
)
→
14MnO
4
2
−
(
a
q
)
+
3CO
3
2
−
(
a
q
)
+
14H
2
O
How many milliliters of 6.15 M KMnO4 are required to completely react with 7.25 mL of an aqueous solution of glycerol
(
d
=
1.144
g
/
mL
)
that is 51.6% by mass?
The SN 1 mechanism starts with the rate-determining step which is the dissociation of the alkyl halide into a carbocation and a halide ion. The next step is
the rapid reaction of the carbocation intermediate with the nucleophile; this step completes the nucleophilic substitution stage. The step that follows the
nucleophilic substitution is a fast acid-base reaction. The nucleophile now acts as a base to remove the proton from the oxonium ion from the previous
step, to give the observed product. Draw a curved arrow mechanism for the reaction, adding steps as necessary. Be sure to include all nonzero formal
charges.
Cl:
Add/Remove step
G
Click and drag to start
drawing a structure.
Chapter 4 Solutions
OWLv2 with Student Solutions Manual eBook for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 4 terms (24 months)
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