Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
9th Edition
ISBN: 9781319090241
Author: Daniel C. Harris, Sapling Learning
Publisher: W. H. Freeman
Question
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Chapter 4, Problem 4.EE

(a)

Interpretation Introduction

Interpretation:

The mean, standard deviation and standard uncertainty for each of the given analysis has to be calculated.

Concept Introduction:

Mean:

The Mean or the arithmetic mean ( x¯ ) is given as the summation of measured values divided by the number of measurements (n). Mean is also called as average.

x¯=ixin

Standard deviation:

Standard deviation measures how closely the data are clustered about the mean.

The standard deviation (s) is given by the formula:

s=i(xix¯)2n1

Standard deviation of the mean: (Standard uncertainty)

Standard deviation of the mean of sets of n values is:

σn=σn

To Compute: The mean and standard deviation of a given column of numbers in two different ways using spreadsheet.

(b)

Interpretation Introduction

Interpretation:

Whether the standard deviation differ significantly at the 95% confidence level has to be given.

Concept Introduction:

Comparison of Standard Deviation with F Test:

For the comparison of mean values of two sets of measurements, we decide whether the standard deviations of the two sets are “statistically different”. This is done by F test.

The F test with quotient F is given as:

Fcalculated=s12s22

Where, s1 and s2 are standard deviations for the set of measurements using original instrument and substitute instrument.

If Fcalculated>Ftable , then the difference is significant.

Degrees of Freedom:

For a n set of measurement, the degrees of freedom will be (n1)

To Give: Whether the standard deviation differ significantly at the 95% confidence level

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