Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
9th Edition
ISBN: 9781319090241
Author: Daniel C. Harris, Sapling Learning
Publisher: W. H. Freeman
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Chapter 4, Problem 4.18P
Interpretation Introduction

Interpretation:

Whether the given sets of measurements gives equivalent results are not has to be explained using spreadsheet calculations.

Concept Introduction:

Comparison of Standard Deviation with F Test:

For the comparison of mean values of two sets of measurements, we decide whether the standard deviations of the two sets are “statistically different”. This is done by F test.

The F test with quotient F is given as:

Fcalculated=s12s22

Where, s1 and s2 are standard deviations for the set of measurements using original instrument and substitute instrument.

If Fcalculated>Ftable , then the difference is significant.

Degrees of Freedom:

For a n set of measurement, the degrees of freedom will be (n1)

Comparing replicate measurements:

When the standard deviations of two sets of measurements are significantly different, the equations used are:

tcalculated =|x1¯x2¯|(s12/n1+s22/n2)Degrees of freedom =(s12/n1+s22/n2)2(s12/n1)2n11+(s22/n2)2n21 =(u12+u22)2u14n11+u24n21

To Give: Whether the given sets of measurements gives equivalent results using spreadsheet calculations.

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