Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
9th Edition
ISBN: 9781319090241
Author: Daniel C. Harris, Sapling Learning
Publisher: W. H. Freeman
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Chapter 4, Problem 4.20P
Interpretation Introduction

Interpretation:

The concentration of HCl is measured by titrating with different indicators.

Whether the difference between the indicators 1 and 2 , indicators 2 and 3 are significant at the 95% confidence level has to be given.

Concept Introduction:

Comparing replicate measurements:

When the two standard deviations are not significantly different from each other, the equation used is:

t test for comparison of means: t=|x1¯x2¯|(spooled)n1n2n1+n2 (since spooled=s12(n11)+s22(n21)n1+n22)

When the standard deviations of two sets of measurements are significantly different, the equations used are:

tcalculated =|x1¯x2¯|(s12/n1+s22/n2)Degrees of freedom =(s12/n1+s22/n2)2(s12/n1)2n11+(s22/n2)2n21 =(u12+u22)2u14n11+u24n21

To Give: Whether the difference between the indicators 1 and 2 , indicators 2 and 3 are significant at the 95% confidence level

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