Introductory Chemistry (5th Edition) (Standalone Book)
5th Edition
ISBN: 9780321910295
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 4, Problem 4E
What are the main ideas in the nuclear theory of the atom?
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
?
000
18
Ar
B
1
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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?
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
18
Ar
Chapter 4 Solutions
Introductory Chemistry (5th Edition) (Standalone Book)
Ch. 4 - Q1. Which statement is not part of Dalton’s...Ch. 4 - Q2. Which statement best summarizes the nuclear...Ch. 4 - Q3. An ion composed of which of these particles...Ch. 4 - Which element is a maingroup metal with an even...Ch. 4 - Which element is a halo0gen? a. Ne b. O c. Ca d. ICh. 4 - Prob. 6SAQCh. 4 - Q7. Which element is a row 4 noble gas?
a. Ne
b....Ch. 4 - How many element does the predictable (most...Ch. 4 - Q9. How many neutrons does the Fe-56 isotope...Ch. 4 - Q10. Determine the number of protons, neutrons,...
Ch. 4 - Q11. What is the charge of the Cr ion that...Ch. 4 - An element has four naturally occurring isotopes;...Ch. 4 - What did Democritus contribute to our modern...Ch. 4 - 2. What are three man ideas in Dalton’s atomic...Ch. 4 - Describe Rutherfords gold foil experiment and the...Ch. 4 - What are the main ideas in the nuclear theory of...Ch. 4 - List the three subatomic particles and their...Ch. 4 - What is electrical charge?Ch. 4 - Is matter usually charge-neutral? How would be...Ch. 4 - 8. What does the atomic number of an element...Ch. 4 - What is a chemical symbol?Ch. 4 - Prob. 10ECh. 4 - What Dmitri Mendeleevs main contribution to our...Ch. 4 - What is the man idea in the periodic law?Ch. 4 - How is the periodic table organized?Ch. 4 - Prob. 14ECh. 4 - Prob. 15ECh. 4 - Prob. 16ECh. 4 - Prob. 17ECh. 4 - Locate each group of elements on the periodic...Ch. 4 - 19. What is an ion?
Ch. 4 - Prob. 20ECh. 4 - 21. Locate each group on the periodic table and...Ch. 4 - 22. What are isotopes?
Ch. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - What notations are commonly used to specify...Ch. 4 - What is the atomic mass of an element?Ch. 4 - 27. Which statement are inconsistent with Dalton’s...Ch. 4 - Which statements are consistent with Daltons...Ch. 4 - Which statements are inconsistent with Rutherfords...Ch. 4 - 30. Which statement are consistent with...Ch. 4 - Prob. 31ECh. 4 - 32. Some of the alpha particles used in...Ch. 4 - 33. Which statement about electrons is true?
a....Ch. 4 - Which statements about neutrons are...Ch. 4 - 35. Which statement about protons is true?
a....Ch. 4 - Prob. 36ECh. 4 - 37. How many electrons would it take to equal the...Ch. 4 - A helium nucleus has two has two neutrons. How...Ch. 4 - Prob. 39ECh. 4 - 40. What mass of protons is required to neutralize...Ch. 4 - Prob. 41ECh. 4 - Prob. 42ECh. 4 - Prob. 43ECh. 4 - How many protons are in the nucleus of an atom of...Ch. 4 - 45. List the symbol and atomic number of each...Ch. 4 - 46. List the symbol and atomic number of each...Ch. 4 - List the name and the atomic number of each...Ch. 4 - List the name and the atomic number of each...Ch. 4 - Fill in the blanks to complete the table. Element...Ch. 4 - Fill in the blanks to complete the table. Element...Ch. 4 - Classify each element as a metal, nonmetal, or...Ch. 4 - Classify each element as a metal, nonmetal, or...Ch. 4 - Which elements would you expect to lose electrons...Ch. 4 - 54. Which elements would you expect to gain...Ch. 4 - 55. Which elements are main group elements?
a....Ch. 4 - Which elements are not main-group elements? a. AI...Ch. 4 - 57. Which elements are alkaline earth metals?
a....Ch. 4 - Which elements are alkaline earth metal? a....Ch. 4 - 59. Which elements are alkali metals?
a. barium
b....Ch. 4 - Which elements are alkali metals? a. scandium b....Ch. 4 - Classify each element as a halogen, a noble gas,...Ch. 4 - Prob. 62ECh. 4 - 63. To what group number does each element...Ch. 4 - Prob. 64ECh. 4 - Which element do you expect to be most like...Ch. 4 - Which element do you expect to be most like...Ch. 4 - Which pair of elements do you expect to be most...Ch. 4 - Prob. 68ECh. 4 - 69. Which element is a main – group nonmetal?
a....Ch. 4 - Prob. 70ECh. 4 - Prob. 71ECh. 4 - Prob. 72ECh. 4 - Prob. 73ECh. 4 - Prob. 74ECh. 4 - Prob. 75ECh. 4 - Prob. 76ECh. 4 - Prob. 77ECh. 4 - 78. Determine the number of protons and electrons...Ch. 4 - Prob. 79ECh. 4 - Determine whether each statement is true or false....Ch. 4 - Predict the ion formed by each element. a. Rb b. K...Ch. 4 - 82. Predict ion formed by each element.
a. F
b....Ch. 4 - Predict how many electrons each element will most...Ch. 4 - Predict how many electrons each element will most...Ch. 4 - 85. Fill in the blanks to compele the...Ch. 4 - Fill in the blacks to complete the table. Symbol...Ch. 4 - Prob. 87ECh. 4 - 88. How many neutrons are in an atom each atomic...Ch. 4 - 89. Write isotopic symbols in the form for each...Ch. 4 - Write isotopic symbol in the form X-A (for...Ch. 4 - Write the symbol for each isotope in the form XZA....Ch. 4 - Write the symbol for each isotope in the form XZA....Ch. 4 - 93. Determine the number of protons and neutrons...Ch. 4 - Prob. 94ECh. 4 - Carbon 14, present within living organisms and...Ch. 4 - Plutonium-239 is used in nuclear bombs. Determine...Ch. 4 - Rubidium has two naturally occurring isotopes:...Ch. 4 - 98. Silicon has three naturally occurring...Ch. 4 - Bromine has two naturally occurring isotopes...Ch. 4 - Silver has two naturally occurring isotopes...Ch. 4 - 101. An element has two naturally occurring...Ch. 4 - Copper has two naturally occurring isotopes. Cu-63...Ch. 4 - Electrical charge is sometimes reported in...Ch. 4 - 104. How many excess protons are in a charged...Ch. 4 - 105. The hydrogen atom contains 1 proton 1...Ch. 4 - 106. Carbon-12 contains 6 protons and 6 neutrons....Ch. 4 - Prob. 107ECh. 4 - 108. Determine the number of protons and neutrons...Ch. 4 - Fill in the blanks to complete the table. Symbol Z...Ch. 4 - 110. Fill in the blanks to complete the...Ch. 4 - Prob. 112ECh. 4 - Chapter 1 describes the difference between...Ch. 4 - 114. Chapter1 describes the difference between...Ch. 4 - The atomic mass of fluorine is 19. 00 amu, and all...Ch. 4 - 116. The atomic mass of germanium is 72.61 amu. Is...Ch. 4 - Prob. 117ECh. 4 - Gallium has only two naturally occurring isotopes,...Ch. 4 - 119. The figure shown here is a representation of...Ch. 4 - 120. Neutron stars are believed to be composed of...Ch. 4 - 121. Complete the following...Ch. 4 - Prob. 122ECh. 4 - Prob. 123ECh. 4 - Prob. 124E
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