CHEMICAL PRINCIPLES (LL) W/ACCESS
7th Edition
ISBN: 9781319421175
Author: ATKINS
Publisher: MAC HIGHER
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 4, Problem 4D.4AST
Interpretation Introduction
Interpretation:
The standard reaction enthalpy for the incomplete combustion of liquid octane has to be determined.
Concept Introduction:
The enthalpy of the reaction is considered as the state function that is it depends only on the initial and the final path of the states. The reaction which is carried out in more than one step then the sum of all the steps gives the overall reaction and by adding the enthalpy change corresponding to each individual step gives thestandard reaction enthalpy. This method of finding the standard reaction enthalpy is referred as Hess’s law.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
R lactam or lactone considering as weak acid or weak base and why
81. a. Propose a mechanism for the following reaction:
OH
CH2=CHCHC=N
b. What is the product of the following reaction?
HO
H₂O
N=CCH2CH2CH
OH
HO
CH3CCH=CH2
H₂O
C=N
82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia
Chapter 4 Solutions
CHEMICAL PRINCIPLES (LL) W/ACCESS
Ch. 4 - Prob. 4A.1ASTCh. 4 - Prob. 4A.1BSTCh. 4 - Prob. 4A.2ASTCh. 4 - Prob. 4A.2BSTCh. 4 - Prob. 4A.3ASTCh. 4 - Prob. 4A.3BSTCh. 4 - Prob. 4A.4ASTCh. 4 - Prob. 4A.4BSTCh. 4 - Prob. 4A.1ECh. 4 - Prob. 4A.2E
Ch. 4 - Prob. 4A.3ECh. 4 - Prob. 4A.4ECh. 4 - Prob. 4A.5ECh. 4 - Prob. 4A.6ECh. 4 - Prob. 4A.7ECh. 4 - Prob. 4A.8ECh. 4 - Prob. 4A.9ECh. 4 - Prob. 4A.10ECh. 4 - Prob. 4A.11ECh. 4 - Prob. 4A.12ECh. 4 - Prob. 4A.13ECh. 4 - Prob. 4A.14ECh. 4 - Prob. 4B.1ASTCh. 4 - Prob. 4B.1BSTCh. 4 - Prob. 4B.2ASTCh. 4 - Prob. 4B.2BSTCh. 4 - Prob. 4B.3ASTCh. 4 - Prob. 4B.3BSTCh. 4 - Prob. 4B.1ECh. 4 - Prob. 4B.2ECh. 4 - Prob. 4B.3ECh. 4 - Prob. 4B.4ECh. 4 - Prob. 4B.5ECh. 4 - Prob. 4B.6ECh. 4 - Prob. 4B.7ECh. 4 - Prob. 4B.8ECh. 4 - Prob. 4B.9ECh. 4 - Prob. 4B.10ECh. 4 - Prob. 4B.11ECh. 4 - Prob. 4B.12ECh. 4 - Prob. 4B.13ECh. 4 - Prob. 4B.14ECh. 4 - Prob. 4B.15ECh. 4 - Prob. 4B.16ECh. 4 - Prob. 4C.1ASTCh. 4 - Prob. 4C.1BSTCh. 4 - Prob. 4C.2ASTCh. 4 - Prob. 4C.2BSTCh. 4 - Prob. 4C.3ASTCh. 4 - Prob. 4C.3BSTCh. 4 - Prob. 4C.4ASTCh. 4 - Prob. 4C.4BSTCh. 4 - Prob. 4C.1ECh. 4 - Prob. 4C.2ECh. 4 - Prob. 4C.3ECh. 4 - Prob. 4C.4ECh. 4 - Prob. 4C.5ECh. 4 - Prob. 4C.6ECh. 4 - Prob. 4C.7ECh. 4 - Prob. 4C.8ECh. 4 - Prob. 4C.9ECh. 4 - Prob. 4C.10ECh. 4 - Prob. 4C.11ECh. 4 - Prob. 4C.12ECh. 4 - Prob. 4C.13ECh. 4 - Prob. 4C.14ECh. 4 - Prob. 4C.15ECh. 4 - Prob. 4C.16ECh. 4 - Prob. 4D.1ASTCh. 4 - Prob. 4D.1BSTCh. 4 - Prob. 4D.2ASTCh. 4 - Prob. 4D.2BSTCh. 4 - Prob. 4D.3ASTCh. 4 - Prob. 4D.3BSTCh. 4 - Prob. 4D.4ASTCh. 4 - Prob. 4D.4BSTCh. 4 - Prob. 4D.5ASTCh. 4 - Prob. 4D.5BSTCh. 4 - Prob. 4D.6ASTCh. 4 - Prob. 4D.6BSTCh. 4 - Prob. 4D.7ASTCh. 4 - Prob. 4D.7BSTCh. 4 - Prob. 4D.1ECh. 4 - Prob. 4D.2ECh. 4 - Prob. 4D.3ECh. 4 - Prob. 4D.4ECh. 4 - Prob. 4D.5ECh. 4 - Prob. 4D.6ECh. 4 - Prob. 4D.7ECh. 4 - Prob. 4D.8ECh. 4 - Prob. 4D.10ECh. 4 - Prob. 4D.11ECh. 4 - Prob. 4D.13ECh. 4 - Prob. 4D.14ECh. 4 - Prob. 4D.15ECh. 4 - Prob. 4D.16ECh. 4 - Prob. 4D.17ECh. 4 - Prob. 4D.18ECh. 4 - Prob. 4D.19ECh. 4 - Prob. 4D.20ECh. 4 - Prob. 4D.21ECh. 4 - Prob. 4D.22ECh. 4 - Prob. 4D.23ECh. 4 - Prob. 4D.24ECh. 4 - Prob. 4D.25ECh. 4 - Prob. 4D.26ECh. 4 - Prob. 4D.29ECh. 4 - Prob. 4D.30ECh. 4 - Prob. 4E.1ASTCh. 4 - Prob. 4E.1BSTCh. 4 - Prob. 4E.2ASTCh. 4 - Prob. 4E.2BSTCh. 4 - Prob. 4E.5ECh. 4 - Prob. 4E.6ECh. 4 - Prob. 4E.7ECh. 4 - Prob. 4E.8ECh. 4 - Prob. 4E.9ECh. 4 - Prob. 4E.10ECh. 4 - Prob. 4F.1ASTCh. 4 - Prob. 4F.1BSTCh. 4 - Prob. 4F.2ASTCh. 4 - Prob. 4F.2BSTCh. 4 - Prob. 4F.3ASTCh. 4 - Prob. 4F.3BSTCh. 4 - Prob. 4F.4ASTCh. 4 - Prob. 4F.4BSTCh. 4 - Prob. 4F.5ASTCh. 4 - Prob. 4F.5BSTCh. 4 - Prob. 4F.6ASTCh. 4 - Prob. 4F.6BSTCh. 4 - Prob. 4F.7ASTCh. 4 - Prob. 4F.7BSTCh. 4 - Prob. 4F.8ASTCh. 4 - Prob. 4F.8BSTCh. 4 - Prob. 4F.9ASTCh. 4 - Prob. 4F.9BSTCh. 4 - Prob. 4F.1ECh. 4 - Prob. 4F.2ECh. 4 - Prob. 4F.3ECh. 4 - Prob. 4F.4ECh. 4 - Prob. 4F.5ECh. 4 - Prob. 4F.6ECh. 4 - Prob. 4F.7ECh. 4 - Prob. 4F.9ECh. 4 - Prob. 4F.10ECh. 4 - Prob. 4F.11ECh. 4 - Prob. 4F.12ECh. 4 - Prob. 4F.13ECh. 4 - Prob. 4F.14ECh. 4 - Prob. 4F.15ECh. 4 - Prob. 4F.16ECh. 4 - Prob. 4F.17ECh. 4 - Prob. 4G.1ASTCh. 4 - Prob. 4G.1BSTCh. 4 - Prob. 4G.2ASTCh. 4 - Prob. 4G.2BSTCh. 4 - Prob. 4G.1ECh. 4 - Prob. 4G.2ECh. 4 - Prob. 4G.3ECh. 4 - Prob. 4G.5ECh. 4 - Prob. 4G.7ECh. 4 - Prob. 4G.8ECh. 4 - Prob. 4G.9ECh. 4 - Prob. 4G.10ECh. 4 - Prob. 4H.1ASTCh. 4 - Prob. 4H.1BSTCh. 4 - Prob. 4H.2ASTCh. 4 - Prob. 4H.2BSTCh. 4 - Prob. 4H.1ECh. 4 - Prob. 4H.2ECh. 4 - Prob. 4H.3ECh. 4 - Prob. 4H.4ECh. 4 - Prob. 4H.5ECh. 4 - Prob. 4H.6ECh. 4 - Prob. 4H.7ECh. 4 - Prob. 4H.8ECh. 4 - Prob. 4H.9ECh. 4 - Prob. 4H.10ECh. 4 - Prob. 4H.11ECh. 4 - Prob. 4I.1ASTCh. 4 - Prob. 4I.1BSTCh. 4 - Prob. 4I.2ASTCh. 4 - Prob. 4I.2BSTCh. 4 - Prob. 4I.3ASTCh. 4 - Prob. 4I.3BSTCh. 4 - Prob. 4I.4ASTCh. 4 - Prob. 4I.4BSTCh. 4 - Prob. 4I.1ECh. 4 - Prob. 4I.2ECh. 4 - Prob. 4I.3ECh. 4 - Prob. 4I.4ECh. 4 - Prob. 4I.5ECh. 4 - Prob. 4I.6ECh. 4 - Prob. 4I.7ECh. 4 - Prob. 4I.8ECh. 4 - Prob. 4I.9ECh. 4 - Prob. 4I.10ECh. 4 - Prob. 4I.11ECh. 4 - Prob. 4I.12ECh. 4 - Prob. 4J.1ASTCh. 4 - Prob. 4J.1BSTCh. 4 - Prob. 4J.2ASTCh. 4 - Prob. 4J.2BSTCh. 4 - Prob. 4J.3ASTCh. 4 - Prob. 4J.3BSTCh. 4 - Prob. 4J.4ASTCh. 4 - Prob. 4J.4BSTCh. 4 - Prob. 4J.5ASTCh. 4 - Prob. 4J.5BSTCh. 4 - Prob. 4J.6ASTCh. 4 - Prob. 4J.6BSTCh. 4 - Prob. 4J.1ECh. 4 - Prob. 4J.2ECh. 4 - Prob. 4J.3ECh. 4 - Prob. 4J.4ECh. 4 - Prob. 4J.5ECh. 4 - Prob. 4J.6ECh. 4 - Prob. 4J.7ECh. 4 - Prob. 4J.8ECh. 4 - Prob. 4J.9ECh. 4 - Prob. 4J.11ECh. 4 - Prob. 4J.12ECh. 4 - Prob. 4J.13ECh. 4 - Prob. 4J.14ECh. 4 - Prob. 4J.15ECh. 4 - Prob. 4J.16ECh. 4 - Prob. 4.8ECh. 4 - Prob. 4.14ECh. 4 - Prob. 4.16ECh. 4 - Prob. 4.19ECh. 4 - Prob. 4.20ECh. 4 - Prob. 4.21ECh. 4 - Prob. 4.23ECh. 4 - Prob. 4.25ECh. 4 - Prob. 4.27ECh. 4 - Prob. 4.28ECh. 4 - Prob. 4.29ECh. 4 - Prob. 4.30ECh. 4 - Prob. 4.31ECh. 4 - Prob. 4.32ECh. 4 - Prob. 4.33ECh. 4 - Prob. 4.34ECh. 4 - Prob. 4.35ECh. 4 - Prob. 4.36ECh. 4 - Prob. 4.37ECh. 4 - Prob. 4.39ECh. 4 - Prob. 4.40ECh. 4 - Prob. 4.41ECh. 4 - Prob. 4.45ECh. 4 - Prob. 4.46ECh. 4 - Prob. 4.48ECh. 4 - Prob. 4.49ECh. 4 - Prob. 4.53ECh. 4 - Prob. 4.57ECh. 4 - Prob. 4.59E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HEarrow_forwardPredicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.arrow_forwardHighlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers. OH OH OH OH OH OHarrow_forward
- Using wedge-and-dash bonds, modify the bonds on the chiral carbon in the molecule below so the molecule has R stereochemical configuration. NH H Br X टेarrow_forwardProvide photos of models of the following molecules. (Include a key for identification of the atoms) 1,2-dichloropropane 2,3,3-trimethylhexane 2-bromo-3-methybutanearrow_forwardPlease draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forward
- A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardFirefly luciferin exhibits three rings. Identify which of the rings are aromatic. Identify which lone pairs are involved in establishing aromaticity. The lone pairs are labeled A-D below.arrow_forwardA 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forward
- Given a complex reaction with rate equation v = k1[A] + k2[A]2, what is the overall reaction order?arrow_forwardPlease draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forwardCHEMICAL KINETICS. One of the approximation methods for solving the rate equation is the steady-state approximation method. Explain what it consists of.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Calorimetry Concept, Examples and Thermochemistry | How to Pass Chemistry; Author: Melissa Maribel;https://www.youtube.com/watch?v=nSh29lUGj00;License: Standard YouTube License, CC-BY