ATKINS' PHYSICAL CHEMISTRY
ATKINS' PHYSICAL CHEMISTRY
11th Edition
ISBN: 9780190053956
Author: ATKINS
Publisher: Oxford University Press
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Chapter 4, Problem 4B.6AE
Interpretation Introduction

Interpretation: The temperature where the vapour pressure of dichloromethane is 70.0kPa has to be calculated.

Concept introduction: Clausius-Clapeyron expression shows the correlation between pressure and temperature for the phase transition process.  Clausius-Clapeyron equation is shown below.

    ln(p2p1)=ΔHvaporizationR(1T21T1)

Where,

  • p1andp2 are the pressures at two different temperature T1andT2 respectively.
  • ΔHvaporization is the enthalpy of vaporization.

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