PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
11th Edition
ISBN: 9780198826910
Author: ATKINS
Publisher: Oxford University Press
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Question
Chapter 4, Problem 4B.5P
(a)
Interpretation Introduction
Interpretation: The slope of normal freezing point of water for the curve of chemical potential against temperature has to be predicted.
Concept introduction: Chemical potential of a system is defined as the rate of change of free energy when
(b)
Interpretation Introduction
Interpretation: The slope of normal boiling point of water for the curve of chemical potential against temperature has to be predicted.
Concept introduction: Chemical potential of a system is defined as the rate of change of free energy when
(c)
Interpretation Introduction
Interpretation: The exceed in chemical potential of water has to be predicted.
Concept introduction: Chemical potential of a system is defined as the rate of change of free energy when
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2) Draw the correct chemical structure (using line-angle drawings / "line structures") from their
given IUPAC name:
a.
(E)-1-chloro-3,4,5-trimethylhex-2-ene
b. (Z)-4,5,7-trimethyloct-4-en-2-ol
C. (2E,6Z)-4-methylocta-2,6-diene
පිපිම
Draw curved arrows to represent the flow of electrons in the reaction on the left
Label the reactants on the left as either "Acid" or "Base"
(iii) Decide which direction the equilibrium arrows will point in each reaction, based on
the given pk, values
(a)
+
H-O
H
3-H
+
(c)
H"
H
+
H****H
000
44-00
NH₂
(e)
i
Дон
OH
Ө
NH
3) Label the configuration in each of the following alkenes as E, Z, or N/A (for
non-stereogenic centers).
00
E
000
N/A
E
Br
N/A
N/A
(g)
E
N/A
OH
E
(b)
Oz
N/A
Br
(d)
00
E
Z
N/A
E
(f) Oz
N/A
E
(h)
Z
N/A
Chapter 4 Solutions
PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
Ch. 4 - Prob. 4B.1STCh. 4 - Prob. 4B.2STCh. 4 - Prob. 4A.1DQCh. 4 - Prob. 4A.2DQCh. 4 - Prob. 4A.3DQCh. 4 - Prob. 4A.1AECh. 4 - Prob. 4A.1BECh. 4 - Prob. 4A.2AECh. 4 - Prob. 4A.2BECh. 4 - Prob. 4A.3AE
Ch. 4 - Prob. 4A.3BECh. 4 - Prob. 4A.4AECh. 4 - Prob. 4A.4BECh. 4 - Prob. 4A.5AECh. 4 - Prob. 4A.5BECh. 4 - Prob. 4A.1PCh. 4 - Prob. 4A.2PCh. 4 - Prob. 4A.3PCh. 4 - Prob. 4A.4PCh. 4 - Prob. 4B.1DQCh. 4 - Prob. 4B.2DQCh. 4 - Prob. 4B.3DQCh. 4 - Prob. 4B.1AECh. 4 - Prob. 4B.1BECh. 4 - Prob. 4B.2AECh. 4 - Prob. 4B.2BECh. 4 - Prob. 4B.3AECh. 4 - Prob. 4B.3BECh. 4 - Prob. 4B.4AECh. 4 - Prob. 4B.4BECh. 4 - Prob. 4B.5AECh. 4 - Prob. 4B.5BECh. 4 - Prob. 4B.6AECh. 4 - Prob. 4B.6BECh. 4 - Prob. 4B.7AECh. 4 - Prob. 4B.7BECh. 4 - Prob. 4B.8AECh. 4 - Prob. 4B.8BECh. 4 - Prob. 4B.9AECh. 4 - Prob. 4B.9BECh. 4 - Prob. 4B.10AECh. 4 - Prob. 4B.10BECh. 4 - Prob. 4B.11AECh. 4 - Prob. 4B.11BECh. 4 - Prob. 4B.12AECh. 4 - Prob. 4B.12BECh. 4 - Prob. 4B.13AECh. 4 - Prob. 4B.13BECh. 4 - Prob. 4B.14AECh. 4 - Prob. 4B.14BECh. 4 - Prob. 4B.1PCh. 4 - Prob. 4B.2PCh. 4 - Prob. 4B.3PCh. 4 - Prob. 4B.4PCh. 4 - Prob. 4B.5PCh. 4 - Prob. 4B.6PCh. 4 - Prob. 4B.7PCh. 4 - Prob. 4B.8PCh. 4 - Prob. 4B.9PCh. 4 - Prob. 4B.10PCh. 4 - Prob. 4B.11PCh. 4 - Prob. 4B.12PCh. 4 - Prob. 4B.13PCh. 4 - Prob. 4B.14PCh. 4 - Prob. 4B.15PCh. 4 - Prob. 4B.16PCh. 4 - Prob. 4.1IACh. 4 - Prob. 4.3IACh. 4 - Prob. 4.4IA
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- Nonearrow_forward1) For the following molecules: (i) Label the indicated alkenes as either cis (Z), trans (E), or N/A (for non-stereogenic centers) by bubbling in the appropriate label on the molecule. (ii) Complete the IUPAC name located below the structure (HINT: Put the letter of the configuration in parentheses at the beginning of the name!) E z N/A ()-3,4,6-trimethylhept-2-ene E Oz O N/A ()-3-ethyl-1-fluoro-4-methylhex-3-ene E -+- N/A Me )-2,3-dimethylpent-2-ene (d) (b) E O N/A Br ()-5-bromo-1-chloro-3-ethyloct-4-ene ОЕ Z N/A Et (___)-3-ethyl-4-methylhex-3-ene E (f) Oz N/A z N/A HO (4.7)-4-(2-hydroxyethyl)-7-methylnona-4,7-dien-2-onearrow_forwardO 9:21AM Tue Mar 4 ## 64% Problem 51 of 15 Submit Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. H :0: CI. AI :CI: :CI: Cl AI Select to Add Arrows Select to Add Arrows O: Cl :CI: :0: H CI: CI CO Select to Add Arrows Select to Add Arrows :O: CI :0: Cl. 10: AIarrow_forward
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