PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
11th Edition
ISBN: 9780198826910
Author: ATKINS
Publisher: Oxford University Press
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Chapter 4, Problem 4B.10AE
Interpretation Introduction

Interpretation: The difference between the standard and normal melting points of ice has to be predicted.

Concept introduction: The melting point of ice is the temperature where the liquid and the solid state of a substance coexist in thermodynamic equilibrium.  The melting point of ice can be calculated by using the Clausius-Clapeyron equation.

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.
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