Chemical Principles: The Quest for Insight
Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Chapter 4, Problem 4B.1AST
Interpretation Introduction

Interpretation:

The change in the internal energy of the engine has to be determined.

Concept Introduction:

The first law of thermodynamics states that the total change in the internal energy of the system is the equal to the net addition result of the amount of heat absorbed or released by the system and the amount of work done.  The mathematical relation representing the first law of thermodynamics is shown below.

  ΔU=q+w

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3. a. Use the periodic table to add up the molecular weight of thionyl chloride (SOCl2) and show your work. b. The actual value obtained for the molecular ion on a high resolution mass spectrometer is 117.9041. Explain the discrepancy. c. Show the calculations that correctly result in the exact mass of 117.9041 for SOC₁₂. Use Table 11.2 or Appendix E in your calculations.
6. Draw the molecular orbital diagram shown to determine which of the following is paramagnetic. B₂2+ B22+, B2, C22, B22- and N22+ Molecular Orbital Diagram B2 C22- B22- N22+ Which molecule is paramagnetic?
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Chapter 4 Solutions

Chemical Principles: The Quest for Insight

Ch. 4 - Prob. 4A.3ECh. 4 - Prob. 4A.4ECh. 4 - Prob. 4A.5ECh. 4 - Prob. 4A.6ECh. 4 - Prob. 4A.7ECh. 4 - Prob. 4A.8ECh. 4 - Prob. 4A.9ECh. 4 - Prob. 4A.10ECh. 4 - Prob. 4A.11ECh. 4 - Prob. 4A.12ECh. 4 - Prob. 4A.13ECh. 4 - Prob. 4A.14ECh. 4 - Prob. 4B.1ASTCh. 4 - Prob. 4B.1BSTCh. 4 - Prob. 4B.2ASTCh. 4 - Prob. 4B.2BSTCh. 4 - Prob. 4B.3ASTCh. 4 - Prob. 4B.3BSTCh. 4 - Prob. 4B.1ECh. 4 - Prob. 4B.2ECh. 4 - Prob. 4B.3ECh. 4 - Prob. 4B.4ECh. 4 - Prob. 4B.5ECh. 4 - Prob. 4B.6ECh. 4 - Prob. 4B.7ECh. 4 - Prob. 4B.8ECh. 4 - Prob. 4B.9ECh. 4 - Prob. 4B.10ECh. 4 - Prob. 4B.11ECh. 4 - Prob. 4B.12ECh. 4 - Prob. 4B.13ECh. 4 - Prob. 4B.14ECh. 4 - Prob. 4B.15ECh. 4 - Prob. 4B.16ECh. 4 - Prob. 4C.1ASTCh. 4 - Prob. 4C.1BSTCh. 4 - Prob. 4C.2ASTCh. 4 - Prob. 4C.2BSTCh. 4 - Prob. 4C.3ASTCh. 4 - Prob. 4C.3BSTCh. 4 - Prob. 4C.4ASTCh. 4 - Prob. 4C.4BSTCh. 4 - Prob. 4C.1ECh. 4 - Prob. 4C.2ECh. 4 - Prob. 4C.3ECh. 4 - Prob. 4C.4ECh. 4 - Prob. 4C.5ECh. 4 - Prob. 4C.6ECh. 4 - Prob. 4C.7ECh. 4 - Prob. 4C.8ECh. 4 - Prob. 4C.9ECh. 4 - Prob. 4C.10ECh. 4 - Prob. 4C.11ECh. 4 - Prob. 4C.12ECh. 4 - Prob. 4C.13ECh. 4 - Prob. 4C.14ECh. 4 - Prob. 4C.15ECh. 4 - Prob. 4C.16ECh. 4 - Prob. 4D.1ASTCh. 4 - Prob. 4D.1BSTCh. 4 - Prob. 4D.2ASTCh. 4 - Prob. 4D.2BSTCh. 4 - Prob. 4D.3ASTCh. 4 - Prob. 4D.3BSTCh. 4 - Prob. 4D.4ASTCh. 4 - Prob. 4D.4BSTCh. 4 - Prob. 4D.5ASTCh. 4 - Prob. 4D.5BSTCh. 4 - Prob. 4D.6ASTCh. 4 - Prob. 4D.6BSTCh. 4 - Prob. 4D.7ASTCh. 4 - Prob. 4D.7BSTCh. 4 - Prob. 4D.1ECh. 4 - Prob. 4D.2ECh. 4 - Prob. 4D.3ECh. 4 - Prob. 4D.4ECh. 4 - Prob. 4D.5ECh. 4 - Prob. 4D.6ECh. 4 - Prob. 4D.7ECh. 4 - Prob. 4D.8ECh. 4 - Prob. 4D.10ECh. 4 - Prob. 4D.11ECh. 4 - Prob. 4D.13ECh. 4 - Prob. 4D.14ECh. 4 - Prob. 4D.15ECh. 4 - Prob. 4D.16ECh. 4 - Prob. 4D.17ECh. 4 - Prob. 4D.18ECh. 4 - Prob. 4D.19ECh. 4 - Prob. 4D.20ECh. 4 - Prob. 4D.21ECh. 4 - Prob. 4D.22ECh. 4 - Prob. 4D.23ECh. 4 - Prob. 4D.24ECh. 4 - Prob. 4D.25ECh. 4 - Prob. 4D.26ECh. 4 - Prob. 4D.29ECh. 4 - Prob. 4D.30ECh. 4 - Prob. 4E.1ASTCh. 4 - Prob. 4E.1BSTCh. 4 - Prob. 4E.2ASTCh. 4 - Prob. 4E.2BSTCh. 4 - Prob. 4E.5ECh. 4 - Prob. 4E.6ECh. 4 - Prob. 4E.7ECh. 4 - Prob. 4E.8ECh. 4 - Prob. 4E.9ECh. 4 - Prob. 4E.10ECh. 4 - Prob. 4F.1ASTCh. 4 - Prob. 4F.1BSTCh. 4 - Prob. 4F.2ASTCh. 4 - Prob. 4F.2BSTCh. 4 - Prob. 4F.3ASTCh. 4 - Prob. 4F.3BSTCh. 4 - Prob. 4F.4ASTCh. 4 - Prob. 4F.4BSTCh. 4 - Prob. 4F.5ASTCh. 4 - Prob. 4F.5BSTCh. 4 - Prob. 4F.6ASTCh. 4 - Prob. 4F.6BSTCh. 4 - Prob. 4F.7ASTCh. 4 - Prob. 4F.7BSTCh. 4 - Prob. 4F.8ASTCh. 4 - Prob. 4F.8BSTCh. 4 - Prob. 4F.9ASTCh. 4 - Prob. 4F.9BSTCh. 4 - Prob. 4F.1ECh. 4 - Prob. 4F.2ECh. 4 - Prob. 4F.3ECh. 4 - Prob. 4F.4ECh. 4 - Prob. 4F.5ECh. 4 - Prob. 4F.6ECh. 4 - Prob. 4F.7ECh. 4 - Prob. 4F.9ECh. 4 - Prob. 4F.10ECh. 4 - Prob. 4F.11ECh. 4 - Prob. 4F.12ECh. 4 - Prob. 4F.13ECh. 4 - Prob. 4F.14ECh. 4 - Prob. 4F.15ECh. 4 - Prob. 4F.16ECh. 4 - Prob. 4F.17ECh. 4 - Prob. 4G.1ASTCh. 4 - Prob. 4G.1BSTCh. 4 - Prob. 4G.2ASTCh. 4 - Prob. 4G.2BSTCh. 4 - Prob. 4G.1ECh. 4 - Prob. 4G.2ECh. 4 - Prob. 4G.3ECh. 4 - Prob. 4G.5ECh. 4 - Prob. 4G.7ECh. 4 - Prob. 4G.8ECh. 4 - Prob. 4G.9ECh. 4 - Prob. 4G.10ECh. 4 - Prob. 4H.1ASTCh. 4 - Prob. 4H.1BSTCh. 4 - Prob. 4H.2ASTCh. 4 - Prob. 4H.2BSTCh. 4 - Prob. 4H.1ECh. 4 - Prob. 4H.2ECh. 4 - Prob. 4H.3ECh. 4 - Prob. 4H.4ECh. 4 - Prob. 4H.5ECh. 4 - Prob. 4H.6ECh. 4 - Prob. 4H.7ECh. 4 - Prob. 4H.8ECh. 4 - Prob. 4H.9ECh. 4 - Prob. 4H.10ECh. 4 - Prob. 4H.11ECh. 4 - Prob. 4I.1ASTCh. 4 - Prob. 4I.1BSTCh. 4 - Prob. 4I.2ASTCh. 4 - Prob. 4I.2BSTCh. 4 - Prob. 4I.3ASTCh. 4 - Prob. 4I.3BSTCh. 4 - Prob. 4I.4ASTCh. 4 - Prob. 4I.4BSTCh. 4 - Prob. 4I.1ECh. 4 - Prob. 4I.2ECh. 4 - Prob. 4I.3ECh. 4 - Prob. 4I.4ECh. 4 - Prob. 4I.5ECh. 4 - Prob. 4I.6ECh. 4 - Prob. 4I.7ECh. 4 - Prob. 4I.8ECh. 4 - Prob. 4I.9ECh. 4 - Prob. 4I.10ECh. 4 - Prob. 4I.11ECh. 4 - Prob. 4I.12ECh. 4 - Prob. 4J.1ASTCh. 4 - Prob. 4J.1BSTCh. 4 - Prob. 4J.2ASTCh. 4 - Prob. 4J.2BSTCh. 4 - Prob. 4J.3ASTCh. 4 - Prob. 4J.3BSTCh. 4 - Prob. 4J.4ASTCh. 4 - Prob. 4J.4BSTCh. 4 - Prob. 4J.5ASTCh. 4 - Prob. 4J.5BSTCh. 4 - Prob. 4J.6ASTCh. 4 - Prob. 4J.6BSTCh. 4 - Prob. 4J.1ECh. 4 - Prob. 4J.2ECh. 4 - Prob. 4J.3ECh. 4 - Prob. 4J.4ECh. 4 - Prob. 4J.5ECh. 4 - Prob. 4J.6ECh. 4 - Prob. 4J.7ECh. 4 - Prob. 4J.8ECh. 4 - Prob. 4J.9ECh. 4 - Prob. 4J.11ECh. 4 - Prob. 4J.12ECh. 4 - Prob. 4J.13ECh. 4 - Prob. 4J.14ECh. 4 - Prob. 4J.15ECh. 4 - Prob. 4J.16ECh. 4 - Prob. 4.8ECh. 4 - Prob. 4.14ECh. 4 - Prob. 4.16ECh. 4 - Prob. 4.19ECh. 4 - Prob. 4.20ECh. 4 - Prob. 4.21ECh. 4 - Prob. 4.23ECh. 4 - Prob. 4.25ECh. 4 - Prob. 4.27ECh. 4 - Prob. 4.28ECh. 4 - Prob. 4.29ECh. 4 - Prob. 4.30ECh. 4 - Prob. 4.31ECh. 4 - Prob. 4.32ECh. 4 - Prob. 4.33ECh. 4 - Prob. 4.34ECh. 4 - Prob. 4.35ECh. 4 - Prob. 4.36ECh. 4 - Prob. 4.37ECh. 4 - Prob. 4.39ECh. 4 - Prob. 4.40ECh. 4 - Prob. 4.41ECh. 4 - Prob. 4.45ECh. 4 - Prob. 4.46ECh. 4 - Prob. 4.48ECh. 4 - Prob. 4.49ECh. 4 - Prob. 4.53ECh. 4 - Prob. 4.57ECh. 4 - Prob. 4.59E
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