Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Chapter 4, Problem 47E
If 1 cubic foot-28.3 L-of air at common room conditions of 230C and 0.985 bar is adjusted to STP, what does the volume become?
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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that
both of them
have a molecular ion peak at m/2 =128. However ketone
(A) has a fragment peak at m/2 = 99 and 72
while ketone (B) snowed a
fragment peak at m/2 = 113 and 58.
9) Propose the most plausible structures for both ketones
b) Explain how you arrived at your conclusion by drawing the
Structures of the distinguishing fragments for each ketone,
including their fragmentation mechanisms.
Part V. Draw the structure of compound tecla using the IR spectrum Cobtained from
the compound in KBr pellet) and the mass spectrum as shown below.
The mass spectrum of compound Tesla showed strong mt peak at 71.
TRANSMITTANCE
LOD
Relative Intensity
100
MS-NW-1539
40
20
80
T
44
55
10
15
20
25
30
35
40
45
50
55
60
65
70
75
m/z
D
4000
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2000
1500
1000
500
HAVENUMBERI-11
Chapter 4 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 4 - Prob. 1ECh. 4 - Prob. 2ECh. 4 - Prob. 3ECh. 4 - Prob. 4ECh. 4 - Prob. 5ECh. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - Prob. 8ECh. 4 - Prob. 9ECh. 4 - Prob. 10E
Ch. 4 - Prob. 11ECh. 4 - The density of liquid oxygen is about 1.4 g/cm3....Ch. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - Prob. 15ECh. 4 - Prob. 16ECh. 4 - Prob. 17ECh. 4 - Prob. 18ECh. 4 - Prob. 19ECh. 4 - Prob. 20ECh. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - Prob. 27ECh. 4 - Many common liquids have boiling points that are...Ch. 4 - Hydrogen cyanide is the deadly gas used in some...Ch. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - Prob. 33ECh. 4 - Prob. 34ECh. 4 - Prob. 35ECh. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - A sample of carbon dioxide gas at a pressure of...Ch. 4 - Prob. 39ECh. 4 - A sample of krypton gas at a pressure of 905 torr...Ch. 4 - Prob. 41ECh. 4 - A sample of krypton gas occupies a volume of 6.68...Ch. 4 - Prob. 43ECh. 4 - Prob. 44ECh. 4 - Prob. 45ECh. 4 - Prob. 46ECh. 4 - If 1 cubic foot-28.3 L-of air at common room...Ch. 4 - Prob. 48ECh. 4 - Prob. 49ECh. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - A container with a volume of 56.2 L holds helium...Ch. 4 - At STP, a sample of neon fills a 4.47-L container....Ch. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - Prob. 61ECh. 4 - Air in a steel cylinder is heated from 19 0C to 42...Ch. 4 - A gas storage tank is designed to hold a fixed...Ch. 4 - Prob. 64ECh. 4 - If 1.62 m3 of air at 120C and 738 torr is...Ch. 4 - Prob. 66ECh. 4 - The compression ratio in an automobile engine is...Ch. 4 - Target check For each of the macroscopic...Ch. 4 - Prob. 4.2TCCh. 4 - Prob. 4.3TCCh. 4 - Prob. 4.4TCCh. 4 - Prob. 1CLECh. 4 - Prob. 2CLECh. 4 - Prob. 3CLECh. 4 - Prob. 4CLECh. 4 - Prob. 5CLECh. 4 - Prob. 1PECh. 4 - Prob. 2PECh. 4 - Prob. 3PECh. 4 - Prob. 4PECh. 4 - Prob. 5PECh. 4 - Prob. 6PE
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- Technetium is the first element in the periodic chart that does not have any stable isotopes. Technetium-99m is an especially interesting and valuable isotope as it emits a gamma ray with a half life ideally suited for medical tests. It would seem that the decay of technetium should fit the treatment above with the result In(c/c) = -kt. The table below includes data from the two sites: http://dailymed.nlm.nih.gov/dailymed/druginfo.cfm?id=7130 http://wiki.medpedia.com/Clinical: Neutrospec_(Technetium_(99m Tc)_fanolesomab). a. b. C. Graph the fraction (c/c.) on the vertical axis versus the time on the horizontal axis. Also graph In(c/c.) on the vertical axis versus time on the horizontal axis. When half of the original amount of starting material has hours fraction remaining disappeared, c/c = ½ and the equation In(c/c.) = -kt becomes In(0.5) = -kt1/2 where t₁₂ is the half life (the time for half of the material to decay away). Determine the slope of your In(c/c.) vs t graph and…arrow_forwardPlease correct answer and don't use hand ratingarrow_forward1. a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in these orbitals. (4 points) b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules that were discussed in lecture. (3 points)arrow_forward
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