Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition) - Standalone book
Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition) - Standalone book
12th Edition
ISBN: 9780321908445
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 4, Problem 4.72UTC
Interpretation Introduction

To determine:

Description related to the subatomic particles i.e. protons, neutrons and electrons.

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The complex anion in Ba₂[Cr(CN)6] is a tetragonally distorted octahedral complex (Dan). Baz[Cr(CN)6] is paramagnetic at room temperature with S = 1. Assume that the complex is a low-spin complex. a) Identify if the [Cr(CN)6] anionic complex has 4 long and 2 short bonds (left side of figure) or if the complex has 4 short and 2 long bonds (right side of figure) with respect to Oh symmetry. Use crystal field theory to answer this question. Explain/rationalize your decision. Can the provided information decide on the order of orbital energies? Dah Tetragonal Distortion ய Dab z-compression z-elongation x and y elongation O symmetry x and y compression E eg d² dx²-y² t2g dxy dxz dyz Question 4 a) continued: Provide your explanations in the space below. b) At low temperatures Ba₂[Cr(CN)6] is ferromagnetically ordered with a phase transition to a paramagnetic phase at Tc = 150K. Sketch the magnetic susceptibility vs. temperature in the diagram below. Indicate Tc as well as the paramagnetic and…
a) Draw the octahedral mer-[FeCl3(CN)3] complex and determine its point group. Use proper wedges and dashes in order to illustrate 3 dimensional details. Use the point group to determine if the complex has a resulting net dipole moment and describe its allowed direction with respect to its symmetry elements (if applicable). ード M 4- b) Substitute one chlorido ligand in mer-[FeCl3(CN)3] 4 with one fluorido ligand. Determine all possible isomers and their corresponding point groups. Use the point groups to determine if the complexes have resulting net dipole moments and describe their allowed direction with respect to its symmetry elements (if applicable). The number of complex sketches below is not necessarily indicative of the number of isomers. 4- 4- ☐☐☐ c) Substitute two chlorido ligands in mer-[FeCl3 (CN)3] 4 with two fluorido ligands. Determine all possible isomers and their corresponding point groups.. Use the point groups to determine if the complexes have resulting net dipole…
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Chapter 4 Solutions

Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition) - Standalone book

Ch. 4.2 - Prob. 4.11QAPCh. 4.2 - 4.10 Give the symbol of the element described by...Ch. 4.2 - Prob. 4.13QAPCh. 4.2 - Identify each of the following elements as a...Ch. 4.3 - Identify each of the following as describing...Ch. 4.3 - 4.18 Identify each of the following as describing...Ch. 4.3 - What did Rutherford determine about the structure...Ch. 4.3 - 4.20 How did Thomson determine that the electrons...Ch. 4.3 - Prob. 4.19QAPCh. 4.3 - Is each of the following statements true or false?...Ch. 4.3 - Prob. 4.21QAPCh. 4.3 - 4.24 Sometimes clothes cling together when...Ch. 4.4 - 4.25 Would you use the atomic number, mass...Ch. 4.4 - 4.26 Identify the type of subatomic particles...Ch. 4.4 - Prob. 4.25QAPCh. 4.4 - Prob. 4.26QAPCh. 4.4 - Prob. 4.27QAPCh. 4.4 - Prob. 4.28QAPCh. 4.4 - Prob. 4.29QAPCh. 4.4 - Prob. 4.30QAPCh. 4.5 - What are the number of protons, neutrons, and...Ch. 4.5 - 4.34 What are the number of protons, neutrons, and...Ch. 4.5 - Write the atomic symbol for the isotope with each...Ch. 4.5 - Prob. 4.34QAPCh. 4.5 - Argon has three naturally occurring isotopes, with...Ch. 4.5 - Strontium has four naturally occurring isotopes,...Ch. 4.5 - Prob. 4.37QAPCh. 4.5 - Prob. 4.38QAPCh. 4.6 - Electrons can move to higher energy levels when...Ch. 4.6 - Prob. 4.40QAPCh. 4.6 - Prob. 4.41QAPCh. 4.6 - Prob. 4.42QAPCh. 4.6 - Prob. 4.43QAPCh. 4.6 - 4.50 Write the electron arrangement for each of...Ch. 4.6 - Prob. 4.45QAPCh. 4.6 - Prob. 4.46QAPCh. 4.7 - What is the group number and number of valence...Ch. 4.7 - 4.54 What is the group number and number of...Ch. 4.7 - Prob. 4.49QAPCh. 4.7 - Write the group number and draw the Lewis symbol...Ch. 4.7 - Prob. 4.51QAPCh. 4.7 - Prob. 4.52QAPCh. 4.7 - Prob. 4.53QAPCh. 4.7 - Prob. 4.54QAPCh. 4.7 - Prob. 4.55QAPCh. 4.7 - 4.62 Select the element in each pair with the...Ch. 4.7 - Prob. 4.57QAPCh. 4.7 - Prob. 4.58QAPCh. 4.7 - Prob. 4.59QAPCh. 4.7 - Prob. 4.60QAPCh. 4.7 - Prob. 4.61QAPCh. 4.7 - Prob. 4.62QAPCh. 4.7 - Prob. 4.63QAPCh. 4.7 - 4.70 Fill in the following blanks using higher or...Ch. 4.7 - Prob. 4.65QAPCh. 4.7 - Prob. 4.66QAPCh. 4.7 - Prob. 4.67QAPCh. 4.7 - 4.74 Which statements completed with a to e will...Ch. 4 - Prob. 4.69UTCCh. 4 - Use Rutherford’s gold-foil experiment to answer...Ch. 4 - Prob. 4.71UTCCh. 4 - Prob. 4.72UTCCh. 4 - Prob. 4.73UTCCh. 4 - Prob. 4.74UTCCh. 4 - Prob. 4.75UTCCh. 4 - Prob. 4.76UTCCh. 4 - Prob. 4.77UTCCh. 4 - Prob. 4.78UTCCh. 4 - Match the spheres A through D with atoms of Li,...Ch. 4 - Prob. 4.80UTCCh. 4 - Prob. 4.81UTCCh. 4 - Of the elements Sn, Xe, Te, Sr, I, and Rb,...Ch. 4 - Prob. 4.83AQAPCh. 4 - Prob. 4.84AQAPCh. 4 - Prob. 4.85AQAPCh. 4 - Prob. 4.86AQAPCh. 4 - Prob. 4.87AQAPCh. 4 - Prob. 4.88AQAPCh. 4 - Prob. 4.89AQAPCh. 4 - Write the name and symbol of the element with the...Ch. 4 - Prob. 4.91AQAPCh. 4 - Prob. 4.92AQAPCh. 4 - Prob. 4.93AQAPCh. 4 - Prob. 4.94AQAPCh. 4 - Prob. 4.95AQAPCh. 4 - Prob. 4.96AQAPCh. 4 - Prob. 4.97AQAPCh. 4 - Prob. 4.98AQAPCh. 4 - Prob. 4.99AQAPCh. 4 - Prob. 4.100AQAPCh. 4 - Why is the ionization energy of Ca higher than K,...Ch. 4 - Prob. 4.102AQAPCh. 4 - Prob. 4.103AQAPCh. 4 - Of the elements F, Br, Cl, and I, which (4.7) a....Ch. 4 - Prob. 4.105CQCh. 4 - Prob. 4.106CQCh. 4 - Prob. 4.107CQCh. 4 - Prob. 4.108CQCh. 4 - Prob. 4.109CQCh. 4 - Prob. 4.110CQCh. 4 - Prob. 4.111CQCh. 4 - Prob. 4.112CQ
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