Chemistry In Focus
6th Edition
ISBN: 9781305084476
Author: Tro, Nivaldo J., Neu, Don.
Publisher: Cengage Learning
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Textbook Question
Chapter 4, Problem 4.6YT
Using the Molar Mass to Find the Number of Molecules in a Sample of a Compound
Calculate the number of carbon tetrachloride
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
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Print Last Name, First Name Initial
Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
4th total
• 6H total
래
• 4H total
21 total
ZH
2H
Statistical
H < 3° C-H weakest
-
product
abstraction here
bund
leads to thermo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Product
6
Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
Waterfox
10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation →
depicted below
Use proper curved arrow notation that explicitly illustrates all bonds being broken, and
all bonds formed in the transformation.
Also, be sure to include all lone pairs and formal charges on all atoms involved in the
flow of electrons.
CH3O
II
HA
H
CH3O-H
H
①
Chapter 4 Solutions
Chemistry In Focus
Ch. 4 - Interpreting Chemical Formulas Determine the...Ch. 4 - Prob. 4.2YTCh. 4 - Prob. 4.3YTCh. 4 - Prob. 4.4YTCh. 4 - Calculating Formula Mass Calculate the formula...Ch. 4 - Using the Molar Mass to Find the Number of...Ch. 4 - Prob. 4.7YTCh. 4 - Chemical Formulas as Conversion Factors (Mass to...Ch. 4 - Prob. 4.9YTCh. 4 - Prob. 4.10YT
Ch. 4 - Using Chemical Equation Coefficients as Conversion...Ch. 4 - Classify each compound as ionic or molecular. LiBr...Ch. 4 - Prob. 2SCCh. 4 - What is wrong with the following compound names?...Ch. 4 - Prob. 4SCCh. 4 - The coefficients in the chemical reaction 2A+3B...Ch. 4 - Prob. 6SCCh. 4 - In Chapter 3, we learned that all matter is...Ch. 4 - Name some common everyday compounds.Ch. 4 - Prob. 3ECh. 4 - Prob. 4ECh. 4 - Prob. 5ECh. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - What is the difference between a common name for a...Ch. 4 - Prob. 9ECh. 4 - Prob. 10ECh. 4 - Prob. 11ECh. 4 - Prob. 12ECh. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - Why must chemical equations be balanced?Ch. 4 - Explain the numerical relationships inherent in a...Ch. 4 - Chemical Formulas Determine the number of each...Ch. 4 - Determine the number of each type of atom in each...Ch. 4 - Classify each compound as ionic or molecular:...Ch. 4 - Classify each compound as ionic or molecular:...Ch. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - Give a chemical formula for each compound: a....Ch. 4 - Give a chemical formula for each compound: a....Ch. 4 - Prob. 29ECh. 4 - Calculate the formula mass for each compound:...Ch. 4 - The formula mass of an unknown compound containing...Ch. 4 - The formula mass of an unknown compound containing...Ch. 4 - Mole Conversions How many moles of CO2 are...Ch. 4 - What is the mass of 2.55 moles of water?Ch. 4 - The active ingredient in aspirin is...Ch. 4 - The active ingredient in Tylenol is acetaminophen...Ch. 4 - Calculate the number of water molecules (H2O) in...Ch. 4 - Acetone (C3H6O) is used as nail polish remover. If...Ch. 4 - Determine the number of sugar molecules in 7.5 g...Ch. 4 - One drop of water from a medicine dropper has a...Ch. 4 - How many chlorine atoms are in each of the...Ch. 4 - How many hydrogen atoms are in each of the...Ch. 4 - Prob. 43ECh. 4 - Find the number of moles of nitrogen in each of...Ch. 4 - The U.S. Food and Drug Administration recommends...Ch. 4 - The scientific consensus indicates that adults...Ch. 4 - Determine the mass of iron (in kilograms)...Ch. 4 - Determine the mass of carbon (in kilograms)...Ch. 4 - Balancing Chemical Equations Balance each chemical...Ch. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Water can be synthesized according to the...Ch. 4 - Billions of pounds of urea, CO(NH2)2, are produced...Ch. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 61ECh. 4 - For each space-filling molecular model, write a...Ch. 4 - For each chemical reaction, draw in the missing...
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